Gasoline

A Shell gasoline station in Hiroshima, Japan

Gasoline (American English) or petrol (British English), is a transparent, petroleum-derived liquid that is used primarily as a fuel in internal combustion engines. It consists mostly of organic compounds obtained by the fractional distillation of petroleum, enhanced with a variety of additives. On average, a 42-gallon barrel of crude oil (159 L) yields about 19 US gallons (72 L) of gasoline when processed in an oil refinery, though this varies based on the crude oil source's assay.

The characteristic of a particular gasoline blend to resist igniting too early (which causes knocking and reduces efficiency in reciprocating engines) is measured by its octane rating. Gasoline is produced in several grades of octane rating. Tetraethyllead and other lead compounds are no longer used in most areas to regulate and increase octane-rating, but many other additives are put into gasoline to improve its chemical stability, control corrosiveness and provide fuel system 'cleaning,' and determine performance characteristics under intended use. Sometimes, gasoline also contains ethanol as an alternative fuel, for economic or environmental reasons.

Gasoline, as used worldwide in the vast number of internal combustion engines used in transport and industry, has a significant impact on the environment, both in local effects (e.g., smog) and in global effects (e.g., effect on the climate). Gasoline may also enter the environment uncombusted, as liquid and as vapors, from leakage and handling during production, transport and delivery, from storage tanks, from spills, etc. As an example of efforts to control such leakage, many (underground) storage tanks are required to have extensive measures in place to detect and prevent such leaks. Gasoline contains benzene and other known carcinogens.[1][2][3]

History

The first automotive combustion engines, so-called Otto engines, were developed in the last quarter of the 19th century in Germany. The fuel was a relatively volatile hydrocarbon obtained from coal gas. With a boiling point near 85 °C (octanes boil about 40 °C higher), it was well suited for early carburetors (evaporators). The development of a "spray nozzle" carburetor enabled the use of less volatile fuels. Further improvements in engine efficiency were attempted at higher compression ratios, but early attempts were blocked by knocking (premature explosion of fuel). In the 1920s, antiknock compounds were introduced by Thomas Midgley Jr. and Boyd, specifically tetraethyllead (TEL). This innovation started a cycle of improvements in fuel efficiency that coincided with the large-scale development of oil refining to provide more products in the boiling range of gasoline. In the 1950s oil refineries started to focus on high octane fuels, and then detergents were added to gasoline to clean the jets in carburetors. The 1970s witnessed greater attention to the environmental consequences of burning gasoline. These considerations led to the phasing out of TEL and its replacement by other antiknock compounds. Subsequently, low-sulfur gasoline was introduced, in part to preserve the catalysts in modern exhaust systems.[4]

Etymology and terminology

"Gasoline" is the term that is used in North America to refer to the most popular automobile fuel. The Oxford English Dictionary dates the first use to 1863, when it was spelled "gasolene". On 27 November 1862, publisher, coffee merchant, and social campaigner John Cassell placed an advertisement in The Times:

The Patent Cazeline Oil, safe, economical, and brilliant … possesses all the requisites which have so long been desired as a means of powerful artificial light.[5]

This is the earliest occurrence of the word to have been found. Cassell discovered that a shopkeeper in Dublin named Samuel Boyd was selling counterfeit cazeline and wrote to him to ask him to stop. Boyd did not reply and changed every ‘C’ into a ‘G’, thus coining the word "gazeline".[6]. The word may also derive from older trademarks. Variant spellings of "gasoline" had been used to refer to raw petroleum since the 16th century.[7]

"Petrol" is the preferred term in most Commonwealth countries. "Petrol" was first used as the name of a refined petroleum product around 1870 by British wholesaler Carless, Capel & Leonard, who marketed it as a solvent.[8] When the product later found a new use as a motor fuel, Frederick Simms, an associate of Gottlieb Daimler, suggested to Carless that they register the trade mark "petrol",[9] but by this time the word was already in general use, possibly inspired by the French pétrole,[7] and the registration was not allowed. Carless registered a number of alternative names for the product, but "petrol" became the common term for the fuel in the British Commonwealth.[10][11]

British refiners originally used "motor spirit" as a generic name for the automotive fuel and "aviation spirit" for aviation gasoline. When Carless was denied a trademark on "petrol" in the 1930s, its competitors switched to the more popular name "petrol". However, "motor spirit" had already made its way into laws and regulations, so the term remains in use as a formal name for petrol.[12][13] The term is used most widely in Nigeria, where the largest petroleum companies call their product "premium motor spirit".[14] Although "petrol" has made inroads into Nigerian English, "premium motor spirit" remains the formal name that is used in scientific publications, government reports, and newspapers.[15]

The use of the word gasoline instead of petrol outside North America can often be confusing. Shortening gasoline to gas, which happens often, causes confusion with various forms of gas used as car fuel (compressed natural gas (CNG), liquefied natural gas (LNG) and liquefied petroleum gas (LPG)). In many countries, gasoline has a colloquial name derived from that of the chemical benzene (e.g., German Benzin, Czech benzín, Dutch benzine, Italian benzina, Russian бензин benzin, Polish benzyna, Chilean Spanish bencina, Thai เบนซิน bensin, Greek βενζίνη venzini, Romanian benzină, Swedish bensin, Arabic بنزين binzīn). Argentina, Uruguay and Paraguay use the colloquial name nafta derived from that of the chemical naphtha.[16]

Octane rating

Spark ignition engines are designed to burn gasoline in a controlled process called deflagration. However, the unburned mixture may autoignite by detonating from pressure and heat alone, rather than ignite from the spark plug at exactly the right time. This causes a rapid pressure rise which can damage the engine. This is often referred to as engine knocking or end-gas knock. Knocking can be reduced by increasing the gasoline's resistance to autoignition, which is expressed by its octane rating.

Octane rating is measured relative to a mixture of 2,2,4-trimethylpentane (an isomer of octane) and n-heptane. There are different conventions for expressing octane ratings, so the same physical fuel may have several different octane ratings based on the measure used. One of the best known is the research octane number (RON).

The octane rating of typical commercially available gasoline varies by country. In Finland, Sweden, and Norway, 95 RON is the standard for regular unleaded gasoline and 98 RON is also available as a more expensive option. In the UK, ordinary regular unleaded gasoline is 95 RON (commonly available), premium unleaded gasoline is always 97 RON, and super unleaded is usually 97–98 RON. However, both Shell and BP produce fuel at 102 RON for cars with high-performance engines and in 2006 the supermarket chain Tesco began to sell super unleaded gasoline rated at 99 RON. In the US, octane ratings in unleaded fuels can vary between 85[17] and 87 AKI (91–92 RON) for regular, through 89–90 AKI (94–95 RON) for mid-grade (equivalent to European regular), up to 90–94 AKI (95–99 RON) for premium (European premium).

South Africa's largest city, Johannesburg, is located on the Highveld at 1,753 metres (5,751 ft) above sea level. So the South African AA recommends 95 octane gasoline (petrol) at low altitude and 93 octane for use in Johannesburg because "The higher the altitude the lower the air pressure, and the lower the need for a high octane fuel as there is no real performance gain".[18]

The octane rating became important as the military sought higher output for aircraft engines in the late 1930s and the 1940s. A higher octane rating allows a higher compression ratio or supercharger boost, and thus higher temperatures and pressures, which translate to higher power output. Some scientists even predicted that a nation with a good supply of high octane gasoline would have the advantage in air power. In 1943, the Rolls-Royce Merlin aero engine produced 1,320 horsepower (984 kW) using 100 RON fuel from a modest 27 liter displacement. By the time of Operation Overlord during World War II both the RAF and USAAF were conducting some operations in Europe using 150 RON fuel (100/150 avgas), obtained by adding 2.5% aniline to 100 octane avgas.[19] By this time the Rolls-Royce Merlin 66 was developing 2,000 hp using this fuel.

Stability

Quality gasoline should be stable for six months if stored properly but gasoline will break down slowly over time due to the separation of the components. Gasoline stored for a year will most likely be able to be burned in an internal combustion engine without too much trouble but the effects of long term storage will become more noticeable with each passing month until a time comes when the gasoline should be diluted with ever-increasing amounts of freshly made fuel so that the older gasoline may be used up. If left undiluted, improper operation will occur and this may include engine damage from misfiring and/or the lack of proper action of the fuel within a fuel injection system and from an onboard computer attempting to compensate (if applicable to the vehicle). Storage should be in an airtight container (to prevent oxidation or water vapors mixing in with the gas) that can withstand the vapor pressure of the gasoline without venting (to prevent the loss of the more volatile fractions) at a stable cool temperature (to reduce the excess pressure from liquid expansion, and to reduce the rate of any decomposition reactions). When gasoline is not stored correctly, gums and solids may be created, which can corrode system components and accumulate on wetted surfaces, resulting in a condition called "stale fuel". Gasoline containing ethanol is especially subject to absorbing atmospheric moisture, then forming gums, solids, or two phases (a hydrocarbon phase floating on top of a water-alcohol phase).

The presence of these degradation products in the fuel tank, fuel lines plus a carburetor or fuel injection components makes it harder to start the engine or causes reduced engine performance. On resumption of regular engine use, the buildup may or may not be eventually cleaned out by the flow of fresh gasoline. The addition of a fuel stabilizer to gasoline can extend the life of fuel that is not or cannot be stored properly though removal of all fuel from a fuel system is the only real solution to the problem of long term storage of an engine or a machine or vehicle. Some typical fuel stabilizers are proprietary mixtures containing mineral spirits, isopropyl alcohol, 1,2,4-trimethylbenzene, or other additives. Fuel stabilizer is commonly used for small engines, such as lawnmower and tractor engines, especially when their use is seasonal (low to no use for one or more seasons of the year). Users have been advised to keep gasoline containers more than half full and properly capped to reduce air exposure, to avoid storage at high temperatures, to run an engine for ten minutes to circulate the stabilizer through all components prior to storage, and to run the engine at intervals to purge stale fuel from the carburetor.[4]

Gasoline stability requirements are set in standard ASTM D4814-14b. The standard describes the various characteristics and requirements of automotive fuels for use over a wide range of operating conditions in ground vehicles equipped with spark-ignition engines.

Energy content

Energy is obtained from the combustion of gasoline by the conversion of a hydrocarbon to carbon dioxide and water. The combustion of octane follows this reaction:

2 C8H18 + 25 O2 → 16 CO2 + 18 H2O

Gasoline contains about 46.7 MJ/kg (127 MJ/US gal, 35.3 kWh/US gal, 13.0 kWh/kg, 120,405 BTU/US gal), quoting the lower heating value.[20] Gasoline blends differ, and therefore actual energy content varies according to the season and producer by up to 1.75% more or less than the average.[21] On average, about 74 L of gasoline (19.5 US gal, 16.3 imp gal) are available from a barrel of crude oil (about 46% by volume), varying due to quality of crude and grade of gasoline. The remainder are products ranging from tar to naphtha.[22]

A high-octane-rated fuel, such as liquefied petroleum gas (LPG) has an overall lower power output at the typical 10:1 compression ratio of a gasoline engine. However, with an engine tuned to the use of LPG (i.e. via higher compression ratios, such as 12:1 instead of 10:1), the power output can be improved. This is because higher-octane fuels allow for a higher compression ratio without knocking, resulting in a higher cylinder temperature, which improves efficiency. Also, increased mechanical efficiency is created by a higher compression ratio through the concomitant higher expansion ratio on the power stroke, which is by far the greater effect. The higher expansion ratio extracts more work from the high-pressure gas created by the combustion process. An Atkinson cycle engine uses the timing of the valve events to produce the benefits of a high expansion ratio without the disadvantages, chiefly detonation, of a high compression ratio. A high expansion ratio is also one of the two key reasons for the efficiency of diesel engines, along with the elimination of pumping losses due to throttling of the intake air flow.

The lower energy content (per liter) of LPG in comparison to gasoline is due mainly to its lower density. Energy content per kilogram is higher than for gasoline (higher hydrogen to carbon ratio, for an example see Standard enthalpy of formation).

Molecular weights of the above reagents are C8H18 114, O2 32, CO2 44, H2O 18; therefore 1 kg of fuel reacts with 3.51 kg of oxygen to produce 3.09 kg of carbon dioxide and 1.42 kg of water.

Density

The density of gasoline ranges from 0.71–0.77 kg/L (719.7 kg/m3 ; 0.026 lb/in3; 6.073 lb/US gal; 7.29 lb/imp gal), higher densities having a greater volume of aromatics.[23] Since gasoline floats on water, water cannot generally be used to extinguish a gasoline fire unless used in a fine mist. Finished marketable gasoline is traded with a standard reference of 0.755 kg/L, and its price is escalated/de-escalated according to its actual density.

Chemical analysis and production

Some of the main components of gasoline: isooctane, butane, 3-ethyltoluene, and the octane enhancer MTBE.
A pumpjack in the United States
An oil rig in the Gulf of Mexico

Gasoline is produced in oil refineries. Roughly 19 US gallons (72 L) of gasoline is derived from a 42-gallon (159 L) barrel of crude oil.[24] Material separated from crude oil via distillation, called virgin or straight-run gasoline, does not meet specifications for modern engines (particularly the octane rating, see below), but can be pooled to the gasoline blend.

The bulk of a typical gasoline consists of hydrocarbons with between 4 and 12 carbon atoms per molecule (commonly referred to as C4-C12).[4] It is a mixture of paraffins (alkanes), cycloalkanes (naphthenes), and olefins (alkenes), where the usage of the terms paraffin and olefin is particular to the oil industry. The actual ratio depends on:

The various refinery streams blended to make gasoline have different characteristics. Some important streams are:

The terms above are the jargon used in the oil industry and terminology varies.

Currently, many countries set limits on gasoline aromatics in general, benzene in particular, and olefin (alkene) content. Such regulations led to increasing preference for high octane pure paraffin (alkane) components, such as alkylate, and is forcing refineries to add processing units to reduce benzene content. In the EU the benzene limit is set at 1% volume for all grade of automotive gasoline.

Gasoline can also contain other organic compounds, such as organic ethers (deliberately added), plus small levels of contaminants, in particular organosulfur compounds, but these are usually removed at the refinery.

Additives

Antiknock additives

A plastic container for storing gasoline used in Germany

Almost all countries in the world have phased out automotive leaded fuel. In 2011 six countries[25] were still using leaded gasoline: Afghanistan, Myanmar, North Korea, Algeria, Iraq and Yemen. It was expected that by the end of 2013 those countries would ban leaded gasoline,[26] but it has not occurred. Algeria will replace leaded with unleaded automotive fuel only in 2015. Different additives have replaced the lead compounds. The most popular additives include aromatic hydrocarbons, ethers and alcohol (usually ethanol or methanol). For technical reasons the use of leaded additives is still permitted worldwide for the formulation of some grades of aviation gasoline such as 100LL, because the required octane rating would be technically infeasible to reach without the use of leaded additives.

A gas can

Tetraethyllead

Gasoline, when used in high-compression internal combustion engines, tends to autoignite (detonate) causing damaging "engine knocking" (also called "pinging" or "pinking"). To address this problem, tetraethyllead (TEL) was widely adopted as an additive for gasoline in the 1920s. With the discovery of the extent of environmental and health damage caused by the lead, however, and the incompatibility of lead with catalytic converters, leaded gasoline was phased out in the USA beginning in 1973. By 1995, leaded fuel accounted for only 0.6% of total gasoline sales and under 2000 short tons (1814 t) of lead per year in the USA. From 1 January 1996, the U.S. Clean Air Act banned the sale of leaded fuel for use in on-road vehicles in the USA. The use of TEL also necessitated other additives, such as dibromoethane. First European countries started replacing lead by the end of the 1980s and by the end of the 1990s leaded gasoline was banned within the entire European Union. Reduction in the average blood lead level is believed to have been a major cause for falling violent crime rates in the United States[27] and South Africa.[28] A statistically significant correlation has been found between the usage rate of leaded gasoline and violent crime: taking into account a 22-year time lag, the violent crime curve virtually tracks the lead exposure curve.[29][30]

Lead Replacement Petrol

Lead Replacement Petrol (LRP) was developed for vehicles designed to run on leaded fuel and incompatible with unleaded. Rather than tetraethyl lead it contains other metal such as potassium compounds or methylcyclopentadienyl manganese tricarbonyl (MMT); these are purported to buffer soft exhaust valves and seats so that they do not suffer recession due to the use of unleaded fuel.

LRP was marketed during and after the phaseout of leaded motor fuels in the United Kingdom, Australia, South Africa and some other countries. Consumer confusion led to widespread mistaken preference for LRP rather than unleaded,[31] and LRP was phased out 8 to 10 years after the introduction of unleaded.[32]

Leaded petrol was withdrawn from sale in Britain after 31 December 1999, seven years after EEC regulations signalled the end of production for cars using leaded petrol in member states. At this stage, a large percentage of cars from the 1980s and early 1990s which ran on leaded petrol were still in use, along with cars which could run on unleaded fuel. However, the declining number of such cars on British roads saw many petrol stations withdrawing LRP from sale by 2003.[33]

MMT

Methylcyclopentadienyl manganese tricarbonyl (MMT) is used in Canada and in Australia to boost octane.[34] It also helps old cars designed for leaded fuel run on unleaded fuel without need for additives to prevent valve problems. Its use in the US has been restricted by regulations.[35] Its use in the EU is restricted by Article 8a of the Fuel Quality Directive[36] following its testing under the Protocol for the evaluation of effects of metallic fuel-additives on the emissions performance of vehicles.[37]

Fuel stabilizers (antioxidants and metal deactivators)

Substituted phenols and derivatives of phenylenediamine are common antioxidants used to inhibit gum formation in gasoline (gasoline).

Gummy, sticky resin deposits result from oxidative degradation of gasoline upon long term storage. These harmful deposits arise from the oxidation of alkenes and other minor components in gasoline (see drying oils). Improvements in refinery techniques have generally reduced the susceptibility of gasolines to these problems. Previously, catalytically or thermally cracked gasolines are most susceptible to oxidation. The formation of these gums is accelerated by copper salts, which can be neutralized by additives called metal deactivators.

This degradation can be prevented through the addition of 5–100 ppm of antioxidants, such as phenylenediamines and other amines.[4] Hydrocarbons with a bromine number of 10 or above can be protected with the combination of unhindered or partially hindered phenols and oil-soluble strong amine bases, such as hindered phenols. "Stale" gasoline can be detected by a colorimetric enzymatic test for organic peroxides produced by oxidation of the gasoline.[38]

Gasolines are also treated with metal deactivators, which are compounds that sequester (deactivate) metal salts that otherwise accelerate the formation of gummy residues. The metal impurities might arise from the engine itself or as contaminants in the fuel.

Detergents

Gasoline, as delivered at the pump, also contains additives to reduce internal engine carbon buildups, improve combustion, and to allow easier starting in cold climates. High levels of detergent can be found in Top Tier Detergent Gasolines. The specification for Top Tier Detergent gasolines was developed by four automakers: GM, Honda, Toyota and BMW. According to the bulletin, the minimal EPA requirement is not sufficient to keep engines clean.[39] Typical detergents include alkylamines and alkyl phosphates at the level of 50–100 ppm.[4]

Ethanol

European Union

In the EU, 5% ethanol can be added within the common gasoline spec (EN 228). Discussions are ongoing to allow 10% blending of ethanol (available in Finnish, French and German gas stations). In Finland most gasoline stations sell 95E10, which is 10% of ethanol; and 98E5, which is 5% ethanol. Most gasoline sold in Sweden has 5–15% ethanol added.

Brazil

In Brazil, the Brazilian National Agency of Petroleum, Natural Gas and Biofuels (ANP) requires gasoline for automobile use to have 27.5% of ethanol added to its composition.[40] Pure hydrated ethanol is also available as a fuel.

Australia

Legislation requires retailers to label fuels containing ethanol on the dispenser, and limits ethanol use to 10% of gasoline in Australia. Such gasoline is commonly called E10 by major brands, and it is cheaper than regular unleaded gasoline.

United States

The federal Renewable Fuel Standard (RFS) effectively requires refiners and blenders to blend renewable biofuels (mostly ethanol) with gasoline, sufficient to meet a growing annual target of total gallons blended. Although the mandate does not require a specific percentage of ethanol, annual increases in the target combined with declining gasoline consumption has caused the typical ethanol content in gasoline to approach 10%. Most fuel pumps display a sticker that states that the fuel may contain up to 10% ethanol, an intentional disparity that reflects the varying actual percentage. Until late 2010, fuels retailers were only authorized to sell fuel containing up to 10 percent ethanol (E10), and most vehicle warranties (except for flexible fuel vehicles) authorize fuels that contain no more than 10 percent ethanol. In parts of the United States, ethanol is sometimes added to gasoline without an indication that it is a component.

India

The Government of India in October 2007 decided to make 5% ethanol blending (with petrol) mandatory. Currently, 10% Ethanol blended product (E10) is being sold in various parts of the country.[41][42]

Ethanol has been found in at least one study to damage catalytic converters.[43]

Dye

In Australia, the lowest grade of gasoline (RON 91) is dyed a light shade of red/orange and the medium grade (RON 95) is dyed yellow.[44]

In the United States, aviation gasoline (avgas) is dyed to identify its octane rating and to distinguish it from kerosene-based jet fuel, which is clear.[45]

In Canada the gasoline for marine and farm use is dyed red and is not subject to road tax.

Oxygenate blending

Oxygenate blending adds oxygen-bearing compounds such as MTBE, ETBE, ethanol, and biobutanol. The presence of these oxygenates reduces the amount of carbon monoxide and unburned fuel in the exhaust gas. In many areas throughout the US, oxygenate blending is mandated by EPA regulations to reduce smog and other airborne pollutants. For example, in Southern California, fuel must contain 2% oxygen by weight, resulting in a mixture of 5.6% ethanol in gasoline. The resulting fuel is often known as reformulated gasoline (RFG) or oxygenated gasoline, or in the case of California, California reformulated gasoline. The federal requirement that RFG contain oxygen was dropped on 6 May 2006 because the industry had developed VOC-controlled RFG that did not need additional oxygen.[46]

MTBE was phased out in the US due to ground water contamination and the resulting regulations and lawsuits. Ethanol and, to a lesser extent, the ethanol-derived ETBE are common replacements. A common ethanol-gasoline mix of 10% ethanol mixed with gasoline is called gasohol or E10, and an ethanol-gasoline mix of 85% ethanol mixed with gasoline is called E85. The most extensive use of ethanol takes place in Brazil, where the ethanol is derived from sugarcane. In 2004, over 3.4 billion US gallons (2.8 billion imp gal/13 million m³) of ethanol was produced in the United States for fuel use, mostly from corn, and E85 is slowly becoming available in much of the United States, though many of the relatively few stations vending E85 are not open to the general public.[47]

The use of bioethanol, either directly or indirectly by conversion of such ethanol to bio-ETBE, is encouraged by the European Union Directive on the Promotion of the use of biofuels and other renewable fuels for transport. Since producing bioethanol from fermented sugars and starches involves distillation, though, ordinary people in much of Europe cannot legally ferment and distill their own bioethanol at present (unlike in the US, where getting a BATF distillation permit has been easy since the 1973 oil crisis).

Safety

HAZMAT class 3 gasoline

Environmental considerations

Combustion of 1 U.S. gallon (3.8 L) of gasoline produces 8.74 kilograms (19.3 lb) of carbon dioxide (2.3 kg/l), a greenhouse gas.[48][49]

The main concern with gasoline on the environment, aside from the complications of its extraction and refining, is the potential effect on the climate through the production of carbon dioxide. Unburnt gasoline and evaporation from the tank, when in the atmosphere, reacts in sunlight to produce photochemical smog. Vapor pressure initially rises with some addition of ethanol to gasoline, but the increase is greatest at 10% by volume. At higher concentrations of ethanol above 10%, the vapor pressure of the blend starts to decrease. At a 10% ethanol by volume, the rise in vapor pressure may potentially increase the problem of photochemical smog. This rise in vapor pressure could be mitigated by increasing or decreasing the percentage of ethanol in the gasoline mixture.

The chief risks of such leaks come not from vehicles, but from gasoline delivery truck accidents and leaks from storage tanks. Because of this risk, most (underground) storage tanks now have extensive measures in place to detect and prevent any such leaks, such as monitoring systems (Veeder-Root, Franklin Fueling).

Production of gasoline consumes 0.63 gallon of water per mile driven.[50]

Toxicity

The safety data sheet for unleaded gasoline shows at least 15 hazardous chemicals occurring in various amounts, including benzene (up to 5% by volume), toluene (up to 35% by volume), naphthalene (up to 1% by volume), trimethylbenzene (up to 7% by volume), methyl tert-butyl ether (MTBE) (up to 18% by volume, in some states) and about ten others.[51] Hydrocarbons in gasoline generally exhibit low acute toxicities, with LD50 of 700–2700 mg/kg for simple aromatic compounds.[52] Benzene and many antiknocking additives are carcinogenic.

People can be exposed to gasoline in the workplace by swallowing it, breathing in vapors, skin contact, and eye contact. The National Institute for Occupational Safety and Health (NIOSH) has designated gasoline as a carcinogen.[53]

Inhalation for intoxication

Inhaled (huffed) gasoline vapor is a common intoxicant. Users concentrate and inhale gasoline vapour in a manner not intended by the manufacturer to produce euphoria and intoxication. Gasoline inhalation has become epidemic in some poorer communities and indigenous groups in Australia, Canada, New Zealand, and some Pacific Islands.[54] The practice is thought to cause severe organ damage, including mental retardation.[55][56][57]

In Canada, Native children in the isolated Northern Labrador community of Davis Inlet were the focus of national concern in 1993, when many were found to be sniffing gasoline. The Canadian and provincial Newfoundland and Labrador governments intervened on a number of occasions, sending many children away for treatment. Despite being moved to the new community of Natuashish in 2002, serious inhalant abuse problems have continued. Similar problems were reported in Sheshatshiu in 2000 and also in Pikangikum First Nation.[58] In 2012, the issue once again made the news media in Canada.[59]

Australia has long faced a petrol (gasoline) sniffing problem in isolated and impoverished aboriginal communities. Although some sources argue that sniffing was introduced by United States servicemen stationed in the nation's Top End during World War II[60] or through experimentation by 1940s-era Cobourg Peninsula sawmill workers,[61] other sources claim that inhalant abuse (such as glue inhalation) emerged in Australia in the late 1960s. Chronic, heavy petrol sniffing appears to occur among remote, impoverished indigenous communities, where the ready accessibility of petrol has helped to make it a common substance for abuse.

In Australia, petrol sniffing now occurs widely throughout remote Aboriginal communities in the Northern Territory, Western Australia, northern parts of South Australia and Queensland. The number of people sniffing petrol goes up and down over time as young people experiment or sniff occasionally. "Boss", or chronic, sniffers may move in and out of communities; they are often responsible for encouraging young people to take it up.[62] In 2005, the Government of Australia and BP Australia began the usage of opal fuel in remote areas prone to petrol sniffing.[63] Opal is a non-sniffable fuel (which is much less likely to cause a high) and has made a difference in some indigenous communities.

Flammability

Uncontrolled burning of gasoline produces large quantities of soot and carbon monoxide.

Like other hydrocarbons, gasoline burns in a limited range of its vapor phase and, coupled with its volatility, this makes leaks highly dangerous when sources of ignition are present. Gasoline has a lower explosive limit of 1.4% by volume and an upper explosive limit of 7.6%. If the concentration is below 1.4%, the air-gasoline mixture is too lean and does not ignite. If the concentration is above 7.6%, the mixture is too rich and also does not ignite. However, gasoline vapor rapidly mixes and spreads with air, making unconstrained gasoline quickly flammable.

Use and pricing

The United States accounts for about 44% of the world’s gasoline consumption.[64] In 2003, the United States consumed 476 gigaliters (126 billion U.S. gallons; 105 billion imperial gallons),[65] which equates to 1.3 gigaliters (340 million U.S. gallons; 290 million imperial gallons) of gasoline each day. The United States used about 510 gigaliters (130 billion U.S. gallons; 110 billion imperial gallons) of gasoline in 2006, of which 5.6% was mid-grade and 9.5% was premium grade.[66]

Europe

Unlike the US, countries in Europe impose substantial taxes on fuels such as gasoline. The price of gasoline in Europe is typically about three times that in the US.

United States

From 1998 to 2004, the price of gasoline fluctuated between US$1 and US$2 per U.S. gallon.[67] After 2004, the price increased until the average gas price reached a high of $4.11 per U.S. gallon in mid-2008, but receded to approximately $2.60 per U.S. gallon by September 2009.[67] More recently, the U.S. experienced an upswing in gasoline prices through 2011,[68] and by 1 March 2012, the national average was $3.74 per gallon.

In the United States, most consumer goods bear pre-tax prices, but gasoline prices are posted with taxes included. Taxes are added by federal, state, and local governments. As of 2009, the federal tax is 18.4¢ per gallon for gasoline and 24.4¢ per gallon for diesel (excluding red diesel).[69] Among states, the highest gasoline tax rates, including the federal taxes as of 2005, are New York (62.9¢/gal), Hawaii (60.1¢/gal), and California (60¢/gal).[68]

About 9% of all gasoline sold in the US in May 2009 was premium grade, according to the Energy Information Administration. Consumer Reports magazine says, "If [your owner’s manual] says to use regular fuel, do so—there's no advantage to a higher grade."[70] The Associated Press said premium gas—which is a higher octane and costs more per gallon than regular unleaded—should be used only if the manufacturer says it is "required".[71] Cars with turbocharged engines and high compression ratios often specify premium gas because higher octane fuels reduce the incidence of "knock", or fuel pre-detonation.[72] The price of gas varies during the summer and winter months.[73]

CO2 production

About 19.64 pounds (8.91 kg) of carbon dioxide (CO2) are produced from burning a (US) gallon (3.78l) of gasoline that does not contain ethanol (2.36 kg/l). About 22.38 pounds (10.15 kg) of CO2 are produced from burning a (US) gallon (3.78l) of diesel fuel (2.69 kg/l).[49]

The US EIA estimates that U.S. motor gasoline and diesel (distillate) fuel consumption for transportation in 2015 resulted in the emission of about 1,105 million metric tons of CO2 and 440 million metric tons of CO2, respectively, for a total of 1,545 million metric tons of CO2.[49] This total was equivalent to 83% of total U.S. transportation sector CO2 emissions and equivalent to 29% of total U.S. energy-related CO2 emissions in 2015.[49]

Most of the retail gasoline now sold in the United States contains about 10% fuel ethanol (or E10) by volume.[49] Burning a gallon of E10 produces about 17.68 pounds of CO2 that is emitted from the fossil fuel content. If the CO2 emissions from ethanol combustion are considered, then about 18.95 pounds of CO2 are produced when a gallon of E10 is combusted.[49] About 12.73 pounds of CO2 are produced when a gallon of pure ethanol is combusted.[49]

Biodiesel fuel is sold with various amounts of biodiesel content. B20 is a commonly sold biodiesel fuel. B20 contains 20% biodiesel and 80% petroleum diesel fuel. Burning a gallon of B20 results in the emission of about 17.90 pounds of CO2 that is emitted from the fossil fuel content. If the emissions from burning the biodiesel in B20 are included, then about 22.06 pounds of CO2 are produced. About 20.77 pounds of CO2 are produced from burning a gallon of B100 (100% biodiesel).[49]

Comparison with other fuels

Volumetric and mass energy density of some fuels compared with gasoline (in the rows with gross and net, they are from[74]):

Fuel type Gross MJ/L      MJ/kg Gross BTU/gal
(imp)		 Gross BTU/gal
(U.S.)		 Net BTU/gal (U.S.)     RON
Conventional gasoline 34.8 44.4[75] 150,100 125,000 115,400 91–92
Autogas (LPG) (Consisting mostly of C3 and C4 hydrocarbons) 26.8 46 95,640 108
Ethanol 21.2[75] 26.8[75] 101,600 84,600 75,700 108.7[76]
Methanol 17.9 19.9[75] 77,600 64,600 56,600 123
Butanol 29.2 36.6 6,087 7,311 91–99
Gasohol 31.2 145,200 120,900 112,400 93/94
Diesel(*) 38.6 45.4 166,600 138,700 128,700 25
Biodiesel 33.3–35.7[77] 126,200 117,100
Avgas (high octane gasoline) 33.5 46.8 144,400 120,200 112,000
Jet fuel (kerosene based) 35.1 43.8 151,242 125,935
Jet fuel (naphtha) 127,500 118,700
Liquefied natural gas 25.3 ~55 109,000 90,800
Liquefied petroleum gas 46.1 91,300 83,500
Hydrogen 10.1 (at 20 kelvin) 142 130[78]

(*) Diesel fuel is not used in a gasoline engine, so its low octane rating is not an issue; the relevant metric for diesel engines is the cetane number

See also

References

Notes

  1. ↑ "Evaluation of the Carcinogenicity of Unleaded Gasoline". epa.gov.
  2. ↑ Mehlman, MA (1990). "Dangerous properties of petroleum-refining products: carcinogenicity of motor fuels (gasoline).". Teratogenesis, carcinogenesis, and mutagenesis. 10 (5): 399–408. PMID 1981951.
  3. ↑ Baumbach, JI; Sielemann, S; Xie, Z; Schmidt, H (15 March 2003). "Detection of the gasoline components methyl tert-butyl ether, benzene, toluene, and m-xylene using ion mobility spectrometers with a radioactive and UV ionization source.". Analytical chemistry. 75 (6): 1483–90. PMID 12659213.
  4. 1 2 3 4 5 Werner Dabelstein, Arno Reglitzky, Andrea Schütze and Klaus Reders "Automotive Fuels" in Ullmann's Encyclopedia of Industrial Chemistry 2007, Wiley-VCH, Weinheim. doi:10.1002/14356007.a16_719.pub2
  5. ↑ "The etymology of gasoline". Oxford English Dictionary. Retrieved 30 July 2017.
  6. ↑ "The etymology of gasoline". Oxford English Dictionary. Retrieved 30 July 2017.
  7. 1 2 gasoline, n., and gasoline, n., Oxford English Dictionary online edition
  8. ↑ "Carless, Capel & Leonard", vintagegarage.co.uk, accessed 5 August 2012
  9. ↑ "Carless, Capel and Leonard Ltd Records: Administrative History", The National Archives, accessed 5 August 2012
  10. ↑ "Online Etymology Dictionary". etymonline.com.
  11. ↑ Ron Hincks (2004). "Our Motoring Heritage: gasoline & Oil". Chrysler Collector (154): 16–20.
  12. ↑ Kemp, John (18 March 2017). "India's thirst for gasoline helps spur global oil demand: Kemp". Reuters. India's drivers used 500,000 barrels per day of motor spirit in the 12 months ending in February 2016, according to the Petroleum Planning and Analysis Cell of the Ministry of Petroleum.
  13. ↑ National Energy Advisory Committee (Australia). Motor Spirit: Vehicle Emissions, Octane Ratings and Lead Additives: Further Examination, March 1981. Australian Government Publishing Service. p. 11. ISBN 9780642066725. Based on estimated provided by the oil refining industry, the Department of National Development and Energy has estimated that the decision to reduce the RON of premium motor spirit from 98 to 97 has resulted in an annual saving equivalent to about 1.6 million barrels of crude oil.
  14. ↑ "Premium Motor Spirit". Oando PLC. Archived from the original on 17 February 2017.
  15. ↑ Udonwa, N. E.; Uko, E. K.; Ikpeme, B. M.; Ibanga, I. A.; Okon, B. O. (2009). "Exposure of Petrol Station Attendants and Auto Mechanics to Premium Motor Sprit Fumes in Calabar, Nigeria". Journal of Environmental and Public Health. 2009. doi:10.1155/2009/281876.
  16. ↑ "Nafta in English – Spanish to English Translation". SpanishDict.
  17. ↑ Ryan Lengerich Journal staff. "85-octane warning labels not posted at many gas stations". Rapid City Journal.
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  19. ↑ Hearst Magazines (April 1936). Popular Mechanics. Hearst Magazines. pp. 524–. ISSN 0032-4558.
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  25. ↑ "List of countries using leaded petrol in 2011".
  26. ↑ "UN: Leaded fuel to be gone by 2013".
  27. ↑ Matthews, Dylan (22 April 2013). "Lead abatement, alcohol taxes and 10 other ways to reduce the crime rate without annoying the NRA". Washington Post. Retrieved 23 May 2013.
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  31. ↑ Seggie, Eleanor (5 August 2011). "More than 20% of SA cars still using lead-replacement petrol but only 1% need it". Engineering News. South Africa. Retrieved 30 March 2017.
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  34. ↑ Hollrah, Don P.; Burns, Allen M. "MMT INCREASES OCTANE WHILE REDUCING EMISSIONS". www.ogj.com.
  35. ↑ EPA,OAR,OTAQ, US. "EPA Comments on the Gasoline Additive MMT". www.epa.gov.
  36. ↑ http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2009:140:0088:0113:EN:PDF
  37. ↑ "Archived copy" (PDF). Archived from the original (PDF) on 8 October 2016. Retrieved 30 August 2016.
  38. ↑ A1 AU 2000/72399 A1 Gasoline test kit
  39. ↑ "Top Tier Detergent Gasoline (Deposits, Fuel Economy, No Start, Power, Performance, Stall Concerns)", GM Bulletin, 04-06-04-047, 06-Engine/Propulsion System, June 2004
  40. ↑ "MEDIDA PROVISÓRIA nº 532, de 2011". senado.gov.br.
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  43. ↑ http://european-biogas.eu/wp-content/uploads/2014/02/022013_Fuel-impact-on-the-aging-of-TWC%E2%80%99s-under-real-driving-conditions_Winkler-et-al.pdf
  44. ↑ http://www.aip.com.au/topics/mr_pdf/AIP_media_release_280912.pdf
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  46. ↑ "Removal of Reformulated Gasoline Oxygen Content Requirement (national) and Revision of Commingling Prohibition to Address Non-0xygenated Reformulated Gasoline (national)". U.S. Environmental Protection Agency. 22 February 2006.
  47. ↑ "Alternative Fueling Station Locator". U.S. Department of Energy.
  48. ↑ "How Gasoline Becomes CO2". Slate Magazine. 1 November 2006.
  49. 1 2 3 4 5 6 7 8 "How much carbon dioxide is produced by burning gasoline and diesel fuel?". U.S. Energy Information Administration (EIA).  This article incorporates text from this source, which is in the public domain.
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  51. ↑ Material safety data sheet Tesoro petroleum Companies, Inc., U.S., 8 February 2003
  52. ↑ Karl Griesbaum et al. "Hydrocarbons" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a13_227
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  54. ↑ gasoline Sniffing Fact File Sheree Cairney, www.abc.net.au, Published 24 November 2005. Retrieved 13 October 2007, a modified version of the original article Archived 15 June 2007 at the Wayback Machine., now archived
  55. ↑ "Low IQ and Gasoline Huffing: The Perpetuation Cycle".
  56. ↑ "Rising Trend: Sniffing Gasoline - Huffing & Inhalants". 16 May 2013.
  57. ↑ "Petrol Sniffing / Gasoline Sniffing".
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  59. ↑ "Labrador Innu kids sniffing gas again to fight boredom". CBC.ca. Retrieved 18 June 2012.
  60. ↑ Wortley, R. P. (29 August 2006). "Anangu Pitjantjatjara Yankunytjatjara Land Rights (Regulated Substances) Amendment Bill". Legislative Council (South Australia). Hansard. Archived from the original (– Scholar search) on 29 September 2007. Retrieved 27 December 2006.
  61. ↑ Brady, Maggie (27 April 2006). "Community Affairs Reference Committee Reference: Petrol sniffing in remote Aboriginal communities" (PDF). Official Committee Hansard (Senate). Hansard: 11. Archived from the original (PDF) on 12 September 2006. Retrieved 20 March 2006.
  62. ↑ Williams, Jonas (March 2004). "Responding to petrol sniffing on the Anangu Pitjantjatjara Lands: A case study". Social Justice Report 2003. Human Rights and Equal Opportunity Commission. Retrieved 27 December 2006.
  63. ↑ Submission to the Senate Community Affairs References Committee by BP Australia Pty Ltd Archived 14 June 2007 at the Wayback Machine. Parliament of Australia Web Site. Retrieved 8 June 2007.
  64. ↑ http://www.worldwatch.org/node/5579 , http://www.eia.doe.gov/emeu/international/oilconsumption.html
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  66. ↑ "U.S. Prime Supplier Sales Volumes of petroleum Products". United States Energy Information Administration. Retrieved 24 October 2007.
  67. 1 2 "Gas Prices: Frequently Asked Questions". fueleconomy.gov.
  68. 1 2 "Archived copy". Archived from the original on 6 July 2009. Retrieved 12 June 2009.
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  70. ↑ "New & Used Car Reviews & Ratings". Consumer Reports.
  71. ↑ "Gassing up with premium probably a waste". philly.com. 19 August 2009. Archived from the original on 21 August 2009.
  72. ↑ Biello, David. "Fact or Fiction?: Premium Gasoline Delivers Premium Benefits to Your Car". Scientific American.
  73. ↑ "Why is summer fuel more expensive than winter fuel?". HowStuffWorks.
  74. ↑ "Appendix B – Transportation Energy Data Book". ornl.gov.
  75. 1 2 3 4 Thomas, George: "Overview of Storage Development DOE Hydrogen Program" (PDF). Archived from the original (PDF) on 21 February 2007. (99.6 KB). Livermore, CA. Sandia National Laboratories. 2000.
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  77. ↑ "Extension Forestry - North Carolina Cooperative Extension" (PDF). Archived from the original (PDF) on 22 November 2012.
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