Stable isotope ratio

The term stable isotope has a similar meaning to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundance of such stable isotopes can be measured experimentally (isotope analysis), yielding an isotope ratio that can be used as a research tool. Theoretically, such stable isotopes could include the radiogenic daughter products of radioactive decay, used in radiometric dating. However, the expression stable isotope ratio is preferably used to refer to isotopes whose relative abundances are affected by isotope fractionation in nature. This field is termed stable isotope geochemistry.

Stable isotope ratios

Measurement of the ratios of naturally occurring stable isotopes (isotope analysis) plays an important role in isotope geochemistry, but stable isotopes (mostly carbon, nitrogen, oxygen and sulfur) are also finding uses in ecological and biological studies. Other workers have used oxygen isotope ratios to reconstruct historical atmospheric temperatures, making them important tools for paleoclimatology.

These isotope systems for lighter elements that exhibit more than one primordial isotope for each element, have been under investigation for many years in order to study processes of isotope fractionation in natural systems. The long history of study of these elements is in part because the proportions of stable isotopes in these light and volatile elements is relatively easy to measure. However, recent advances in isotope ratio mass spectrometry (i.e. multiple-collector inductively coupled plasma mass spectrometry) now enable the measurement of isotope ratios in heavier stable elements, such as iron, copper, zinc, molybdenum, etc.

Applications

The variations in oxygen and hydrogen isotope ratios have applications in hydrology since most samples will lie between two extremes, ocean water and Arctic/Antarctic snow.[1] Given a sample of water from an aquifer, and a sufficiently sensitive tool to measure the variation in the isotopic ratio of hydrogen in the sample, it is possible to infer the source, be it ocean water seeping into the aquifer or precipitation seeping into the aquifer, and even to estimate the proportions from each source.[2] Stable isotopes of water are also used in partitioning water sources for plant transpiration and groundwater recharge.[3][4]

Another application is in paleotemperature measurement for paleoclimatology. For example, one technique is based on the variation in isotopic fractionation of oxygen by biological systems with temperature.[5] Species of Foraminifera incorporate oxygen as calcium carbonate in their shells. The ratio of the oxygen isotopes oxygen-16 and oxygen-18 incorporated into the calcium carbonate varies with temperature and the oxygen isotopic composition of the water. This oxygen remains "fixed" in the calcium carbonate when the forminifera dies, falls to the sea bed, and its shell becomes part of the sediment. It is possible to select standard species of forminifera from sections through the sediment column, and by mapping the variation in oxygen isotopic ratio, deduce the temperature that the Forminifera encountered during life if changes in the oxygen isotopic composition of the water can be constrained.[6]

In forensic science, research suggests that the variation in certain isotope ratios in drugs derived from plant sources (cannabis, cocaine) can be used to determine the drug's continent of origin.[7]

It also has applications in "doping control", to distinguish between endogenous and exogenous (synthetic) sources of hormones.[8][9]

Chondrite meteorites are classified using the oxygen isotope ratios. In addition, an unusual signature of carbon-13 confirms the non-terrestrial origin for organic compounds found in carbonaceous chondrites, as in the Murchison meteorite.

In ecology, carbon and nitrogen isotope ratios are widely used to determine the broad diet of seabirds, and to identify the geographical areas where individuals spend the breeding and non-breeding season. [10]

See also

Bibliography

References

  1. ↑ Han LF, Gröning M, Aggarwal P, Helliker BR (2006). "Reliable determination of oxygen and hydrogen isotope ratios in atmospheric water vapour adsorbed on 3A molecular sieve". Rapid Commun. Mass Spectrom. 20 (23): 3612–8. PMID 17091470. doi:10.1002/rcm.2772.
  2. ↑ Weldeab S, Lea DW, Schneider RR, Andersen N (2007). "155,000 years of West African monsoon and ocean thermal evolution". Science. 316 (5829): 1303–7. Bibcode:2007Sci...316.1303W. PMID 17540896. doi:10.1126/science.1140461.
  3. ↑ Good, Stephen P.; Noone, David; Bowen, Gabriel (2015-07-10). "Hydrologic connectivity constrains partitioning of global terrestrial water fluxes". Science. 349 (6244): 175–177. ISSN 0036-8075. PMID 26160944. doi:10.1126/science.aaa5931.
  4. ↑ Evaristo, Jaivime; Jasechko, Scott; McDonnell, Jeffrey J. "Global separation of plant transpiration from groundwater and streamflow". Nature. 525 (7567): 91–94. PMID 26333467. doi:10.1038/nature14983.
  5. ↑ Tolosa I, Lopez JF, Bentaleb I, Fontugne M, Grimalt JO (1999). "Carbon isotope ratio monitoring-gas chromatography mass spectrometric measurements in the marine environment: biomarker sources and paleoclimate applications". Sci. Total Environ. 237–238: 473–81. PMID 10568296. doi:10.1016/S0048-9697(99)00159-X.
  6. ↑ Shen JJ, You CF (2003). "A 10-fold improvement in the precision of boron isotopic analysis by negative thermal ionization mass spectrometry". Anal. Chem. 75 (9): 1972–7. PMID 12720329. doi:10.1021/ac020589f.
  7. ↑ Casale J, Casale E, Collins M, Morello D, Cathapermal S, Panicker S (2006). "Stable isotope analyses of heroin seized from the merchant vessel Pong Su". J. Forensic Sci. 51 (3): 603–6. PMID 16696708. doi:10.1111/j.1556-4029.2006.00123.x.
  8. ↑ Author, A. "Stable isotope ratio analysis in sports anti-doping". Drug Testing and Analysis. 4 (12): 893–896. doi:10.1002/dta.1399.
  9. ↑ Cawley, Adam T.; Kazlauskas, Rymantas; Trout, Graham J.; Rogerson, Jill H.; George, Adrian V. "Isotopic Fractionation of Endogenous Anabolic Androgenic Steroids and Its Relationship to Doping Control in Sports" (PDF). Journal of Chromatographic Science. 43: 32–38. doi:10.1093/chromsci/43.1.32.
  10. ↑ Graña Grilli, M.; Cherel, Y. (2017). "Skuas (Stercorarius spp.) moult body feathers during both the breeding and inter-breeding periods: implications for stable isotope investigations in seabirds". Ibis. 159 (2): 266–271. doi:10.1111/ibi.12441.
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