Sperm oil

Sperm oil is a waxy liquid obtained from sperm whales. It is a clear, yellowish liquid with a very faint odor. Sperm oil has a different composition from common whale oil. Although it is traditionally called an "oil", it is technically a liquid wax. It is composed of wax esters with a small proportion of triglycerides, an ester of an unsaturated fatty acid and a branched-chain fatty alcohol.[1] It is a natural antioxidant and heat-transfer agent.[1] Through catalytic reaction, it carries phosphorus and sulfur derivatives providing anti-wear and friction modification.[1] In the late 18th and early 19th centuries, sperm oil was prized as an illuminant for its bright, odorless flame and as a lubricant for its low viscosity and stability. It was supplanted in the late 19th century by less expensive alternatives such as kerosene and petroleum-based lubricants. With the 1987 international ban on whaling, sperm oil is no longer legally sold.[2]

The oil from bottlenose whales was sometimes called "Arctic sperm oil". It was cheaper and inferior to true sperm oil.[3][4]

Processing

Sperm oil is extracted from the spermaceti organ and the junk of the sperm whale.

After killing a sperm whale, the whalers would pull the carcass alongside the ship, cut off the head and haul it on deck, whereupon they would cut a hole in it and bail out the matter inside with a bucket. The primary source of sperm oil was the spermaceti organ and the junk (or "melon"), the organs that serve to focus and modulate the animal's vocalizations. A sperm whale's spermaceti organ may contain as much as 1,900 litres of substance.[5] The matter from these organs was stored in casks to be processed on land; sometimes it was boiled first to prevent it going rancid. The blubber also contained smaller proportions of spermaceti, which was obtained by boiling the blubber on the ship itself. On land, the casks of head-matter were allowed to chill during the winter, causing it to congeal into a spongy and viscous mass. The congealed matter was then loaded into wool sacks and placed in a press to squeeze out its liquid. This liquid was bottled and sold as "winter-strained sperm oil". This was the most valuable product: an oil that remained liquid in freezing winter temperatures. When spring came and the leftover solid matter melted a bit, the liquid was strained off and sold as "spring-strained sperm oil". In summer, the matter melted some more and the liquid was strained off to leave a fully solid wax. This wax, brown in color, was then bleached and sold as "spermaceti wax".[6][7]

Chemistry

Physical properties of sperm oil
specific gravity 0.884 at 15.6 °C[8]
flash point 260-266 °C[9]
saponification value 120-150.3[10]
unsaponifiable matter 17.5-44.0%[10]
refractive index 1.4649 at 15.6 °C[11][12]
iodine number (Wijs) 70.4-96.4[10]
viscosity 21-23 cSt at 37.5 °C[13]
viscosity index 180[14]

Sperm oil has a fairly low viscosity (roughly equal to coconut oil).[13] It retains its viscosity in high temperatures better than most oils. It does not tend to become rancid, dry out, or corrode metals. Sperm oil cannot be hydrogenated, and thus could not be used to make soap or margarine.[15][16] It is fairly resistant to oxidization.[17]

Spermaceti is a liquid wax, composed mostly of wax esters (chiefly cetyl palmitate) and a smaller proportion of triglycerides,[18] with oleic acid being the most common fatty acid. The proportion of wax esters in the spermaceti organ increases with the age of the whale: 38-51% in calves, 58-87% in adult females, and 71-94% in adult males. The blubber oil of the whale is about 66% wax.[19] When cooled to below 30 °C, the waxes in spermaceti begin to crystallize.[20]

Winter-strained sperm oil is roughly two-thirds wax esters and one third triglycerides.[21][22] Most of the carbon chains are unsaturated, with 18:1 being the most common.[23] Unlike other toothed whales save the Amazon river dolphin, most of the carbon chains in the wax esters are relatively long (C10-C22).[19]

Applications

US consumption of sperm oil peaked in the mid-19th century, then saw a precipitous decline.

Sperm oil was particularly prized as an illuminant in oil lamps, as it burned more brightly and cleanly than any other available oil and gave off no foul odor.[7] It was replaced in the late 19th century by cheaper, more efficient kerosene.[24]

In the US, whale oil was used in cars as an additive to automatic transmission fluid until it was banned by the Endangered Species Act.[25] Prior to 1972, over 30 million pounds of Sperm Whale oil was used annually in lubricants because of its exceptional lubricity and heat stability.[26] In 1972, the Sperm Whale was listed as an Endangered Species and the following year, the US Congress amended the Endangered Species Act, outlawing the killing of whales and the use of their oil.[26] The loss of whale oil had a profound impact in the automotive industry, where for example, transmission failures rose from under 1 million in 1972 to over 8 million by 1975.[26]

Sperm oil was a popular lubricant. It worked well for fine, light machinery such as sewing machines and watches because it is thin, doesn't congeal or dry out and doesn't corrode metals. It was also used in heavy machinery such as locomotives and steam-powered looms because it can withstand high temperatures.[27] In the late 20th century, Jojoba oil was discovered to be a better substitute for high-friction applications because it is even more stable at high temperatures. This caused sperm oil's price to collapse to a tenth of its previous value.[28]

Because of its very low freezing point, sperm oil saw widespread use in the aerospace industry.[29]

Sperm oil was used to protect metals from rust. A coat of sperm oil provided a temporary protection for the metal components in firearms, because it did not dry out or gum up.[30][31] It was the basis of the original (but not current) Rust-Oleum.

References

  1. 1 2 3 [Transmission Digest, Volume 26, No. 2, October 2006, "The Science of Synthetic Sperm Whale Oil"]
  2. ↑ http://www.publicaffairs.noaa.gov/releases2004/jun04/noaa04-r150.html
  3. ↑ Julius Lewkowitsch (1904). Chemical technology and analysis of oils, fats, and waxes. pg 870
  4. ↑ http://www.swatch.com/zz_en/mobile/swatch-watches.html
  5. ↑ https://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/19720017437.pdf
  6. ↑ http://www.nha.org/history/hn/HNWhalingmus.htm
  7. 1 2 Wilson Heflin (2004). Herman Melville's Whaling Years. pg 232
  8. ↑ Emil F. Dieterichs (1916). A Practical Treatise On Friction, Lubrication, Fats And Oils. pg 22
  9. ↑ Richard P. Pohanish (2005). HazMat Data: For First Response, Transportation, Storage, and Security. pg 865
  10. 1 2 3 Moninder Mohan Chakrabarty (2009). Chemistry And Technology Of Oils And Fats. pg 183
  11. ↑ Abraham G. Blakeley , Edmund A. Reilly (1917). Some Data on Sperm Oils Used for Burning Purposes. The Journal of Industrial and Engineering Chemistry, Dec 1917. pg 1099
  12. ↑ J. N. Goldsmith (1921). Table of Refractive Indices. pg 239
  13. 1 2 http://www.engineeringtoolbox.com/kinematic-viscosity-d_397.html
  14. ↑ William Gordon Forbes (1943). Lubricants and cutting oils for machine tools. pg 69
  15. ↑ Joh. N. Tønnessen, Arne Odd Johnsen (1984). The History of Modern Whaling, pg 228.
  16. ↑ Robert Lloyd Webb (1988). On the Northwest: Commercial Whaling in the Pacific Northwest, 1790-1967. pg 144
  17. ↑ Czesław Kajdas, S. S. K. Harvey, E. Wilusz (1990). Encyclopedia of Tribology, Volume 15. pg 308.
  18. ↑ "Archived copy" (PDF). Archived from the original (PDF) on 2013-06-01. Retrieved 2012-10-29.
  19. 1 2 William F. Perrin, Bernd Würsig, J. G. M. Thewissen (2002). Encyclopedia of Marine Mammals. pg 1164
  20. ↑ Malcolm R. Clarke (1978). Physical Properties of Spermaceti Oil in the Sperm Whale. Journal of the Marine Biological Association of the United Kingdom Archived 2008-12-17 at the Wayback Machine.
  21. ↑ G. F. Spencer, W. H. Tallent (1973). Sperm whale oil analysis by gas chromatography and mass spectrometry. Journal of the American Oil Chemists Society
  22. ↑ J.W. Hagemann and J.A. Rothfus (1978). Oxidative Stability of Wax Esters by Thermogravimetric Analysis. JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, Vol .56, No.6. Pages: 629-631
  23. ↑ Gayland F. Spencer (1978). Alkoxy-Acyl Combinations in the Wax Esters from Winterized Sperm Whale Oil by Gas Chromatography-Mass Spectrometry
  24. ↑ http://www.thefreemanonline.org/columns/how-capitalism-saved-the-whales/
  25. ↑ New Scientist 1 May 1975 pg 262
  26. 1 2 3 [Landis, Phil. Gears for the Transmission Rebuilding Industry. Oxnard: Automatic Transmission Rebuilders Association, 2010. Print.]
  27. ↑ Scientists and Swindlers: Paul Lucier (2008). Consulting on Coal and Oil in America. pg 152
  28. ↑ James R. McGuigan, R. Charles Moyer, Frederick H. deB Harris (2010). Managerial Economics. pg 29
  29. ↑ [New Bedford Whaling Museum. American Whaling. Modified August 22, 2014: http://www.whalingmuseum.org/learn/research-topics/overview-of-north-american-whaling/american-whaling]
  30. ↑ Roy F. Dunlap (1963). Gunsmithing: The complete sourcebook of firearms design, construction, alteration, and restoration for amateur and professional gunsmiths. pgg= 84
  31. ↑ William S. Brophy (1985). The Springfield 1903 Rifles. pg 71
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.