Isotopes of scandium
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Standard atomic weight (Ar) |
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Naturally occurring scandium (21Sc) is composed of one stable isotope 45Sc. Twenty-three radioisotopes have been characterized with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and Sc-44 with a half-life of 3.97 hours. All of the remaining radioactive isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being 39Sc with a half-life shorter than 300 nanoseconds. The half-lives for isotopes with mass numbers less than 39 is unknown. This element also has 10 meta states with the most stable being 44m2Sc (t1/2 58.6 h).
The isotopes of scandium range in atomic weight from 36 u (36Sc) to 60 u (60Sc). The primary decay mode at masses lower than the only stable isotope, 45Sc, is Beta-plus or electron capture, and the primary mode at masses above it is beta-minus. The primary decay products at atomic weights below 45Sc are calcium isotopes and the primary products from higher atomic weights are titanium isotopes.
List of isotopes
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[2] |
daughter isotope(s)[n 1] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
37Sc | 21 | 16 | 37.00305(32)# | p | 36Ca | 7/2−# | |||
38Sc | 21 | 17 | 37.99470(32)# | <300 ns | p | 37Ca | (2−)# | ||
38mSc | p | 37Ca | |||||||
39Sc | 21 | 18 | 38.984790(26) | <300 ns | p | 38Ca | (7/2−)# | ||
40Sc | 21 | 19 | 39.977967(3) | 182.3(7) ms | β+ (99.54%) | 40Ca | 4- | ||
β+, p (.44%) | 39K | ||||||||
β+, α (.017%) | 36Ar | ||||||||
41Sc | 21 | 20 | 40.96925113(24) | 596.3(17) ms | β+ | 41Ca | 7/2− | ||
42Sc | 21 | 21 | 41.96551643(29) | 681.3(7) ms | β+ | 42Ca | 0+ | ||
42mSc | 616.28(6) keV | 61.7(4) s | β+ | 42Ca | (7,5,6)+ | ||||
43Sc | 21 | 22 | 42.9611507(20) | 3.891(12) h | β+ | 43Ca | 7/2− | ||
43m1Sc | 151.4(2) keV | 438(7) µs | 3/2+ | ||||||
43m2Sc | 3123.2(3) keV | 470(4) ns | (19/2)− | ||||||
44Sc | 21 | 23 | 43.9594028(19) | 3.97(4) h | β+ | 44Ca | 2+ | ||
44m1Sc | 67.8680(14) keV | 154.2(8) ns | 1− | ||||||
44m2Sc | 270.95(20) keV | 58.61(10) h | IT (98.8%) | 44Sc | 6+ | ||||
β+ (1.2%) | 44Ca | ||||||||
44m3Sc | 146.224(22) keV | 50.4(7) µs | 0- | ||||||
45Sc | 21 | 24 | 44.9559119(9) | Stable | 7/2− | 1.0000 | |||
45mSc | 12.40(5) keV | 318(7) ms | IT | 45Sc | 3/2+ | ||||
46Sc | 21 | 25 | 45.9551719(9) | 83.79(4) d | β− | 46Ti | 4+ | ||
46m1Sc | 52.011(1) keV | 9.4(8) µs | 6+ | ||||||
46m2Sc | 142.528(7) keV | 18.75(4) s | IT | 46Sc | 1− | ||||
47Sc | 21 | 26 | 46.9524075(22) | 3.3492(6) d | β− | 47Ti | 7/2− | ||
47mSc | 766.83(9) keV | 272(8) ns | (3/2)+ | ||||||
48Sc | 21 | 27 | 47.952231(6) | 43.67(9) h | β− | 48Ti | 6+ | ||
49Sc | 21 | 28 | 48.950024(4) | 57.2(2) min | β− | 49Ti | 7/2− | ||
50Sc | 21 | 29 | 49.952188(17) | 102.5(5) s | β− | 50Ti | 5+ | ||
50mSc | 256.895(10) keV | 350(40) ms | IT (97.5%) | 50Sc | 2+,3+ | ||||
β− (2.5%) | 50Ti | ||||||||
51Sc | 21 | 30 | 50.953603(22) | 12.4(1) s | β− | 51Ti | (7/2)− | ||
52Sc | 21 | 31 | 51.95668(21) | 8.2(2) s | β− | 52Ti | 3(+) | ||
53Sc | 21 | 32 | 52.95961(32)# | >3 s | β− (>99.9%) | 53Ti | (7/2−)# | ||
β−, n (<.1%) | 52Ti | ||||||||
54Sc | 21 | 33 | 53.96326(40) | 260(30) ms | β− (>99.9%) | 54Ti | 3+# | ||
β−, n (<.1%) | 53Ti | ||||||||
54mSc | 110(3) keV | 7(5) µs | (5+) | ||||||
55Sc | 21 | 34 | 54.96824(79) | 0.115(15) s | β− (>99.9%) | 55Ti | 7/2−# | ||
β−, n (<.1%) | 54Ti | ||||||||
56Sc | 21 | 35 | 55.97287(75)# | 35(5) ms | β− | 56Ti | (1+) | ||
57Sc | 21 | 36 | 56.97779(75)# | 13(4) ms | β− | 57Ti | 7/2−# | ||
58Sc | 21 | 37 | 57.98371(86)# | 12(5) ms | β− | 58Ti | (3+)# | ||
59Sc | 21 | 38 | 58.98922(97)# | 10# ms | β−, n | 58Ti | 7/2−# | ||
β− | 59Ti | ||||||||
60Sc | 21 | 39 | 59.99571(97)# | 3# ms | 3+# |
- ↑ Bold for stable isotopes, bold italic for nearly-stable isotopes (half-life longer than the age of the universe)
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
- Nuclide masses are given by IUPAP Commission on Symbols, Units, Nomenclature, Atomic Masses and Fundamental Constants (SUNAMCO)
- Isotope abundances are given by IUPAC Commission on Isotopic Abundances and Atomic Weights
References
- ↑ Meija, J.; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure Appl. Chem. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- ↑ "Universal Nuclide Chart". nucleonica. (Registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005. Check date values in:
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(help) - N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of calcium | Isotopes of scandium | Isotopes of titanium |
Table of nuclides |