Iridium tetrachloride
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3D model (JSmol) |
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ChemSpider | |
EC Number | 233-048-8 |
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Properties | |
Cl4Ir | |
Molar mass | 334.02 g·mol−1 |
Appearance | amorphous brown solid |
good | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Iridium tetrachloride is an inorganic compound with the approximate formula IrCl4(H2O)n. It is a water-soluble dark brown amorphous solid. A well defined derivative is ammonium hexachloroiridate ((NH4)2IrCl6).[1] It is used to prepare catalysts, such as the Henbest Catalyst for transfer hydrogenation of cyclohexanones.[2]
References
- ↑ Thomas R. B. Mitchell (2001). "Iridium(IV) Chloride". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.ri050.
- ↑ E. L. Eliel, T. W. Doyle, R. O. Hutchins, E. C. Gilbert (1970). "cis-4-tert-Butylecyclohexanol". Org. Synth. 50: 13. doi:10.15227/orgsyn.050.0013.
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