Isotopes of hafnium
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Standard atomic weight (Ar) |
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Natural hafnium (72Hf) consists of five stable isotopes (176Hf, 177Hf, 178Hf, 179Hf, and 180Hf) and one very long-lived radioisotope, 174Hf, with a half-life of 2×1015 years. In addition, there are 30 other known radionuclides, the most stable of which is 182Hf with a half-life of 8.9×106 years. No other radioisotope has a half-life over 1.87 days. Most isotopes have half-lives under 1 minute. There are also 26 known nuclear isomers, the most stable of which is 178m2Hf with a half-life of 31 years.
List of isotopes
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life[n 1] | decay mode(s)[2][n 2] |
daughter isotope(s)[n 3] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
153Hf | 72 | 81 | 152.97069(54)# | 400# ms [>200 ns] | 1/2+# | ||||
153mHf | 750(100)# keV | 500# ms | 11/2−# | ||||||
154Hf | 72 | 82 | 153.96486(54)# | 2(1) s | β+ | 154Lu | 0+ | ||
α (rare) | 150Yb | ||||||||
155Hf | 72 | 83 | 154.96339(43)# | 890(120) ms | β+ | 155Lu | 7/2−# | ||
α (rare) | 151Yb | ||||||||
156Hf | 72 | 84 | 155.95936(22) | 23(1) ms | α (97%) | 152Yb | 0+ | ||
β+ (3%) | 156Lu | ||||||||
156mHf | 1959.0(10) keV | 480(40) µs | 8+ | ||||||
157Hf | 72 | 85 | 156.95840(21)# | 115(1) ms | α (86%) | 153Yb | 7/2− | ||
β+ (14%) | 157Lu | ||||||||
158Hf | 72 | 86 | 157.954799(19) | 2.84(7) s | β+ (55%) | 158Lu | 0+ | ||
α (45%) | 154Yb | ||||||||
159Hf | 72 | 87 | 158.953995(18) | 5.20(10) s | β+ (59%) | 159Lu | 7/2−# | ||
α (41%) | 155Yb | ||||||||
160Hf | 72 | 88 | 159.950684(12) | 13.6(2) s | β+ (99.3%) | 160Lu | 0+ | ||
α (.7%) | 156Yb | ||||||||
161Hf | 72 | 89 | 160.950275(24) | 18.2(5) s | β+ (99.7%) | 161Lu | 3/2−# | ||
α (.3%) | 157Yb | ||||||||
162Hf | 72 | 90 | 161.94721(1) | 39.4(9) s | β+ (99.99%) | 162Lu | 0+ | ||
α (.008%) | 158Yb | ||||||||
163Hf | 72 | 91 | 162.94709(3) | 40.0(6) s | β+ | 163Lu | 3/2−# | ||
α (10−4%) | 159Yb | ||||||||
164Hf | 72 | 92 | 163.944367(22) | 111(8) s | β+ | 164Lu | 0+ | ||
165Hf | 72 | 93 | 164.94457(3) | 76(4) s | β+ | 165Lu | (5/2−) | ||
166Hf | 72 | 94 | 165.94218(3) | 6.77(30) min | β+ | 166Lu | 0+ | ||
167Hf | 72 | 95 | 166.94260(3) | 2.05(5) min | β+ | 167Lu | (5/2)− | ||
168Hf | 72 | 96 | 167.94057(3) | 25.95(20) min | β+ | 168Lu | 0+ | ||
169Hf | 72 | 97 | 168.94126(3) | 3.24(4) min | β+ | 169Lu | (5/2)− | ||
170Hf | 72 | 98 | 169.93961(3) | 16.01(13) h | EC | 170Lu | 0+ | ||
171Hf | 72 | 99 | 170.94049(3) | 12.1(4) h | β+ | 171Lu | 7/2(+) | ||
171mHf | 21.93(9) keV | 29.5(9) s | IT | 171Hf | 1/2(−) | ||||
172Hf | 72 | 100 | 171.939448(26) | 1.87(3) y | EC | 172Lu | 0+ | ||
172mHf | 2005.58(11) keV | 163(3) ns | (8−) | ||||||
173Hf | 72 | 101 | 172.94051(3) | 23.6(1) h | β+ | 173Lu | 1/2− | ||
174Hf[n 4] | 72 | 102 | 173.940046(3) | 2.0(4)×1015 y | α | 170Yb | 0+ | 0.0016(1) | 0.001619–0.001621 |
174m1Hf | 1549.3 keV | 138(4) ns | (6+) | ||||||
174m2Hf | 1797.5(20) keV | 2.39(4) µs | (8−) | ||||||
174m3Hf | 3311.7 keV | 3.7(2) µs | (14+) | ||||||
175Hf | 72 | 103 | 174.941509(3) | 70(2) d | β+ | 175Lu | 5/2− | ||
176Hf[n 5] | 72 | 104 | 175.9414086(24) | Observationally Stable[n 6] | 0+ | 0.0526(7) | 0.05206–0.05271 | ||
177Hf | 72 | 105 | 176.9432207(23) | Observationally Stable[n 7] | 7/2− | 0.1860(9) | 0.18593–0.18606 | ||
177m1Hf | 1315.4504(8) keV | 1.09(5) s | 23/2+ | ||||||
177m2Hf | 1342.38(20) keV | 55.9(12) µs | (19/2−) | ||||||
177m3Hf | 2740.02(15) keV | 51.4(5) min | 37/2− | ||||||
178Hf | 72 | 106 | 177.9436988(23) | Observationally Stable[n 8] | 0+ | 0.2728(7) | 0.27278–0.27297 | ||
178m1Hf | 1147.423(5) keV | 4.0(2) s | 8− | ||||||
178m2Hf | 2445.69(11) keV | 31(1) y | 16+ | ||||||
178m3Hf | 2573.5(5) keV | 68(2) µs | (14−) | ||||||
179Hf | 72 | 107 | 178.9458161(23) | Observationally Stable[n 9] | 9/2+ | 0.1362(2) | 0.13619–0.1363 | ||
179m1Hf | 375.0367(25) keV | 18.67(4) s | 1/2− | ||||||
179m2Hf | 1105.84(19) keV | 25.05(25) d | 25/2− | ||||||
180Hf | 72 | 108 | 179.9465500(23) | Observationally Stable[n 10] | 0+ | 0.3508(16) | 0.35076–0.351 | ||
180m1Hf | 1141.48(4) keV | 5.47(4) h | 8− | ||||||
180m2Hf | 1374.15(4) keV | 0.57(2) µs | (4−) | ||||||
180m3Hf | 2425.8(10) keV | 15(5) µs | (10+) | ||||||
180m4Hf | 2486.3(9) keV | 10(1) µs | 12+ | ||||||
180m5Hf | 2538.3(12) keV | >10 µs | (14+) | ||||||
180m6Hf | 3599.3(18) keV | 90(10) µs | (18−) | ||||||
181Hf | 72 | 109 | 180.9491012(23) | 42.39(6) d | β− | 181Ta | 1/2− | ||
181m1Hf | 595(3) keV | 80(5) µs | (9/2+) | ||||||
181m2Hf | 1040(10) keV | ~100 µs | (17/2+) | ||||||
181m3Hf | 1738(10) keV | 1.5(5) ms | (27/2−) | ||||||
182Hf | 72 | 110 | 181.950554(7) | 8.90(9)×106 y | β− | 182Ta | 0+ | ||
182mHf | 1172.88(18) keV | 61.5(15) min | β− (58%) | 182Ta | 8− | ||||
IT (42%) | 182Hf | ||||||||
183Hf | 72 | 111 | 182.95353(3) | 1.067(17) h | β− | 183Ta | (3/2−) | ||
184Hf | 72 | 112 | 183.95545(4) | 4.12(5) h | β− | 184Ta | 0+ | ||
184mHf | 1272.4(4) keV | 48(10) s | β− | 184Ta | 8− | ||||
185Hf | 72 | 113 | 184.95882(21)# | 3.5(6) min | β− | 185Ta | 3/2−# | ||
186Hf | 72 | 114 | 185.96089(32)# | 2.6(12) min | β− | 186Ta | 0+ | ||
187Hf | 72 | 115 | 186.96459(43)# | 30# s [>300 ns] | |||||
188Hf | 72 | 116 | 187.96685(54)# | 20# s [>300 ns] | 0+ |
- ↑ Bold for isotopes with half-lives longer than the age of the universe (nearly stable)
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes
- ↑ primordial radionuclide
- ↑ Used in Lutetium-Hafnium dating
- ↑ Believed to undergo α decay to 172Yb
- ↑ Believed to undergo α decay to 173Yb
- ↑ Believed to undergo α decay to 174Yb
- ↑ Believed to undergo α decay to 175Yb
- ↑ Believed to undergo α decay to 176Yb
Notes
- Evaluated isotopic composition is for most but not all commercial samples.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ↑ Meija, J.; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure Appl. Chem. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- ↑ "Universal Nuclide Chart". nucleonica. (Registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005. Check date values in:
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(help) - N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
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