Dichloro(cycloocta-1,5-diene)platinum(II)
Identifiers | |
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3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.031.937 |
PubChem CID |
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Properties | |
C8H12Cl2Pt | |
Molar mass | 374.17 g·mol−1 |
Melting point | 285 °C (545 °F; 558 K) |
Hazards | |
EU classification (DSD) (outdated) |
Xi |
R-phrases (outdated) | R36/37/38 |
S-phrases (outdated) | S26-S37/39 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is prepared from potassium tetrachloroplatinate and the diene:[1]
- K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl
References
- ↑ E. Costa; P. G. Pringle; M. Ravetz (1997). "[(1,2,5,6-N)-1,5-Cyclooctadiene]Dimethyl-Platinum(II)". Inorg. Synth. Inorganic Syntheses. 31: 284–286. ISBN 978-0-470-13262-3. doi:10.1002/9780470132623.ch49.
Further reading
- Ashfaquzzaman Syed; Edwin D. Stevens; Sandra G. Cruz (1984). "Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum". Inorg. Chem. 23 (22): 3673–3674. doi:10.1021/ic00190a053.
- J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, “The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II),” Acta Crystallogr. C. 2004, m353-m354.
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