Criticality accident

A criticality accident is an uncontrolled nuclear fission chain reaction. It is sometimes referred to as a critical excursion or a critical power excursion or a divergent chain reaction.

Any such event involves the unintended accumulation or arrangement of a critical mass of fissile material, for example enriched uranium or plutonium. Criticality accidents can release potentially fatal radiation doses, if they occur in an unprotected environment.

Under normal circumstances, a critical or supercritical fission reaction (one that is self-sustaining in power or increasing in power) should only occur inside a safely shielded location, such as a reactor cores or a suitable test environment. A criticality accident occurs if the same reaction is achieved unintentionally, for example in an unsafe environment or during reactor maintenance.

Though dangerous and frequently lethal to humans within the immediate area, the critical mass formed would not be capable of producing a massive nuclear detonation of the type that fission bombs are designed to produce. This is because all the design features needed to make a nuclear warhead cannot arise by chance.

In some cases, the heat released by the chain reaction will cause the fissile (and other nearby) materials to expand. In such cases, the chain reaction can either settle into a low power steady state or may even become either temporarily or permanently shut down (subcritical).

In the history of atomic power development, at least 60 criticality accidents have occurred, including 22 in process environments, outside of nuclear reactor cores or experimental assemblies, and 38 in small experimental reactors and other test assemblies.

Although process accidents occurring outside of reactors are characterized by large releases of radiation, the releases are localized. Nonetheless, fatal radiation exposures have occurred to persons close to these events, resulting in 14 fatalities. In a few cases, the energy released has caused significant mechanical damage or even small explosions.[1]

Physical basis

Criticality occurs when sufficient fissile material (a "critical mass") is in one place such that each fission of an atom of the material, on average, produces a neutron that in turn strikes another atom causing another fission; this causes the chain reaction to become self-sustaining within the mass of material.

Criticality can be achieved by using metallic uranium or plutonium or by mixing compounds or liquid solutions of these elements. The chain reaction is influenced by range of parameters noted by the acronyms MAGIC MERV - for Mass, Absorption, Geometry, Interaction, Concentration, Moderation, Enrichment, Reflection and Volume and MERMAIDS - for Mass, Enrichment, Reflection, Moderation, Absorption, Interaction, Density and Shape. Temperature can also be a key factor.

Complex calculations can be performed to predict the conditions needed to arrange materials into a critical state. Where fissile materials are handled in civil and military installations, specially trained personnel are employed to carry out such calculations, and to ensure that all reasonably practicable measures are used to prevent criticality accidents, during both planned normal operations and any potential process upset conditions that cannot be dismissed on the basis of negligible likelihoods.

The assembly of a critical mass establishes a nuclear chain reaction, resulting in an exponential rate of change in the neutron population over space and time leading to neutron radiation and a neutron flux. This radiation contains both a neutron and gamma ray component and is extremely dangerous to any unprotected nearby life-form. The rate of change of neutron population depends on the neutron generation time, which is characteristic of the neutron population, the state of "criticality", and the fissile medium.

A nuclear fission creates approximately 2.5 neutrons per fission event on average.[2] Hence, to maintain a stable, exactly critical chain reaction, 1.5 neutrons per fission event must either leak from the system or be absorbed without causing further fissions.

For every 1000 neutrons released by fission, a small number, typically no more than about 7, are delayed neutrons which are emitted from the fission product precursors, called delayed neutron emitters. This delayed neutron fraction, on the order of 0.007 for uranium, is crucial for the control of the neutron chain reaction in reactors. It is called one dollar of reactivity. The lifetime of delayed neutrons ranges from fractions of seconds to almost 100 seconds after fission. The neutrons are usually classified in 6 delayed neutron groups.[2] The average neutron lifetime considering delayed neutrons is approximately 0.1 sec, which makes the chain reaction relatively easy to control over time. The remaining 993 prompt neutrons are released very quickly, approximately 1 μs after the fission event.

In steady state operation, nuclear reactors operate at exact criticality. When at least one dollar of reactivity is added above the exact critical point (where the neutron production rate balances the rate of neutron losses, from both absorption and leakage) then the chain reaction does not rely on delayed neutrons. In such cases, the neutron population can rapidly increase exponentially, with a very small time constant, known as the prompt neutron lifetime. Thus there is a very large increase in neutron population over a very short time frame. Since each fission event contributes approximately 200 MeV per fission, this results in a very large energy burst as a "prompt critical spike". This spike can be easily detected by radiation dosimetry instrumentation and "criticality accident alarm system" detectors that are properly deployed.

Accident types

Criticality accidents are divided into one of two categories:

Excursion types can be classified into four categories depicting the nature of the evolution over time:

  1. Prompt criticality excursion
  2. Transient criticality excursion
  3. Exponential excursion
  4. Steady state excursion

The prompt critical excursion is characterized by a power history with an initial prompt critical spike as previously noted, that either self terminates or continues for an extended period as a tail region that decreases over time. The transient critical excursion is characterized by a continuing or repeating spike pattern (sometimes known as "chugging") after the initial prompt critical excursion. The longest of the 22 process accidents occurred at Hanford Works in 1962 and lasted for 37.5 hours. The 1999 Tokaimura nuclear accident remained critical for about 20 hours, until it was shut down by active intervention. The exponential excursion is characterized by a reactivity of less than one dollar added, where the neutron population rises as an exponential over time, until either feedback effects or intervention reduce the reactivity. The exponential excursion can reach a peak power level, then decrease over time, or reach a steady state power level, where the critical state is exactly achieved for a "steady state" excursion.

The steady state excursion is also a state which the heat generated by fission is balanced by the heat losses to the ambient environment. This excursion has been characterized by the Oklo natural reactor that was naturally produced within uranium deposits in Gabon, Africa about 1.7 billion years ago.

Recorded incidents

At least sixty criticality accidents have been recorded since 1945. These have caused at least twenty-one deaths: seven in the United States, ten in the Soviet Union, two in Japan, one in Argentina, and one in Yugoslavia. Nine have been due to process accidents, and the others from research reactor accidents.[1]

Criticality accidents have occurred both in the context of nuclear weapons and nuclear reactors.

Date Location Description Injuries Fatalities Refs
1944 Los Alamos Otto Frisch received a larger than intended dose of radiation when leaning over the original Lady Godiva device for a couple of seconds. He noticed that the red lamps (that normally would flicker intermittently when neutrons were being emitted) were 'glowing continuously'. Frisch's body had reflected some neutrons back to the device, increasing its neutron multiplication, and it was only by quickly leaning back and away from the device and removing a couple of the uranium blocks that Frisch escaped harm but, he said, "if I had hesitated for another two seconds before removing the material ... the dose would have been fatal". On 3 February 1954 and 12 February 1957, accidental criticality excursions occurred causing damage to the device, but fortunately only insignificant exposures to personnel. This original Godiva device was irreparable after the second accident and was replaced by the Godiva II. 0 0 [3][4]
4 June 1945 Los Alamos Scientist John Bistline was conducting an experiment to determine the effect of surrounding a sub-critical mass of enriched uranium with a water reflector. The experiment unexpectedly became critical when water leaked into the polyethylene box holding the metal. When that happened, the water began to function as a highly effective moderator rather than just a neutron reflector. Three people received non-fatal doses of radiation. 3 0 [5]
21 August 1945 Los Alamos Scientist Harry Daghlian suffered fatal radiation poisoning and died 25 days later after accidentally dropping a tungsten carbide brick onto a sphere of plutonium, which was later (see next entry) nicknamed the demon core. The brick acted as a neutron reflector, bringing the mass to criticality. This was the first known criticality accident causing a fatality. 0 1 [6][7]
21 May 1946 Los Alamos Scientist Louis Slotin accidentally irradiated himself during a similar incident (called the "Pajarito accident" at the time) using the same "demon core" sphere of plutonium responsible for the Daghlian accident. Slotin surrounded the plutonium sphere with two 9-inch diameter hemispherical cups of the neutron-reflecting material beryllium; one above and one below. He was using a screwdriver to keep the cups slightly apart, which kept the assembly subcritical. When the screwdriver accidentally slipped, the cups closed completely around the plutonium, sending the assembly supercritical. Slotin quickly disassembled the device, likely saving the lives of seven fellow scientists nearby. Slotin succumbed to radiation poisoning nine days later. The demon core was melted down and reused in other bomb tests in subsequent years.[8] 8 1 [9][10]
16 June 1958 Oak Ridge, Tennessee Y-12 incident The first recorded uranium-processing–related criticality occurred at the Y-12 Plant. During a routine leak test a fissile solution was unknowingly allowed to collect in a 55-gallon drum. The excursion lasted for approximately 20 minutes and resulted in eight workers receiving significant exposure. There were no fatalities, though five were hospitalized for forty-four days. All eight workers eventually returned to work but most subsequently developed cancer. 8 0 [11][12]
15 October 1958 Vinča Nuclear Institute A criticality excursion in the heavy water RB reactor at the Vinca Nuclear Institute in Vinča, Yugoslavia, killing one person and injuring five. The initial survivors received the first bone marrow transplant in Europe. 5 1 [13][14][15][16]
30 December 1958 Los Alamos Cecil Kelley, a chemical operator working on plutonium purification, switched on a stirrer on a large mixing tank, which created a vortex in the tank. The plutonium, dissolved in an organic solvent, flowed into the center of the vortex. Due to a procedural error, the mixture contained 3.27 kg of plutonium, which reached criticality for about 200 microseconds. Kelley received 3,900 to 4,900 rads according to later estimates. The other operators reported seeing a flash of light and found Kelley outside, saying "I'm burning up! I'm burning up!" He died 35 hours later. 0 1 [17]
3 January 1961 SL-1, 40 miles west of Idaho Falls SL-1, a United States Army experimental nuclear power reactor underwent a steam explosion and meltdown due to improper withdrawal of the central control rod, killing its three operators. 0 3 [18]
24 July 1964 Wood River Junction The facility in Richmond, Rhode Island was designed to recover uranium from scrap material left over from fuel element production. An operator, intending to add trichloroethene to a tank containing uranium-235 and sodium carbonate to remove organics, erroneously added uranium solution instead, producing a criticality excursion. The operator was exposed to a fatal radiation dose of 10,000 rad (100 Gy). Ninety minutes later a second excursion happened when a plant manager returned to the building and turned off the agitator, exposing himself and another administrator to doses of up to 100 rad (1 Gy) without ill effect. The operator involved in the initial exposure died 49 hours after the incident. 0 1 [19][20][21]
10 December 1968 Mayak The nuclear fuel processing center in central Russia was experimenting with plutonium purification techniques. Two operators were using an "unfavorable geometry vessel in an improvised and unapproved operation as a temporary vessel for storing plutonium organic solution"; in other words, the operators were decanting plutonium solutions into the wrong type -- more importantly, shape -- of container. After most of the solution had been poured out, there was a flash of light and heat. "Startled, the operator dropped the bottle, ran down the stairs, and from the room." After the complex had been evacuated, the shift supervisor and radiation control supervisor re-entered the building. The shift supervisor then deceived the radiation control supervisor and entered the room of the incident; this was followed by a large nuclear reaction that irradiated the shift supervisor with a fatal dose of radiation, possibly due to an attempt by the supervisor to pour the solution down a floor drain. 0 1 [22]
23 September 1983 Centro Atomico Constituyentes An operator at the RA-2 research reactor in Buenos Aires, Argentina received a fatal radiation dose of 3700 rad (37 Gy) while changing the fuel rod configuration with moderating water in the reactor. Two others were injured. 2 1 [23][24]
17 June 1997 Sarov Russian Federal Nuclear Center senior researcher Alexandr Zakharov received a fatal dose of 4850 rem in a criticality accident. 0 1 [25][26][27]
30 September 1999 Tōkai At the Japanese uranium reprocessing facility in Ibaraki Prefecture, workers put a mixture of uranyl nitrate solution into a precipitation tank which was not designed to dissolve this type of solution and caused an eventual critical mass to be formed, and resulted in the death of two workers from radiation poisoning. 0 2 [28][29][30]

There was speculation although not confirmed within criticality accident experts, that Fukushima 3 suffered a criticality accident. Based on incomplete information about the 2011 Fukushima I nuclear accidents, Dr. Ferenc Dalnoki-Veress speculates that transient criticalities may have occurred there.[33] Noting that limited, uncontrolled chain reactions might occur at Fukushima I, a spokesman for the International Atomic Energy Agency (IAEA) “emphasized that the nuclear reactors won’t explode.”[34] By March 23, 2011, neutron beams had already been observed 13 times at the crippled Fukushima nuclear power plant. While a criticality accident was not believed to account for these beams, the beams could indicate nuclear fission is occurring.[35] On April 15, TEPCO reported that nuclear fuel had melted and fallen to the lower containment sections of three of the Fukushima I reactors, including reactor three. The melted material was not expected to breach one of the lower containers, which could cause a massive radioactivity release. Instead, the melted fuel is thought to have dispersed uniformly across the lower portions of the containers of reactors No. 1, No. 2 and No. 3, making the resumption of the fission process, known as a "recriticality", most unlikely.[36]

Observed effects

Image of a 60-inch cyclotron, circa 1939, showing an external beam of accelerated ions (perhaps protons or deuterons) ionizing the surrounding air and causing an ionized-air glow. Due to the similar mechanism of production, the blue glow is thought to resemble the "blue flash" seen by Harry Daghlian and other witnesses of criticality accidents.

Blue glow

Many criticality accidents have been observed to emit a blue flash of light.

The blue glow of a criticality accident results from the fluorescence of the excited ions, atoms and molecules of air (mostly oxygen and nitrogen) falling back to unexcited states, which produces an abundance of blue light. This is also the reason electrical sparks in air, including lightning, appear electric blue. The smell of ozone was said to be a sign of high ambient radioactivity by Chernobyl liquidators.

This blue flash or "blue glow" is often incorrectly attributed to Cherenkov radiation. It is a coincidence that the color of Cherenkov light and light emitted by ionized air are a very similar blue; their methods of production are different. Cherenkov radiation does occur in air for high-energy particles (such as particle showers from cosmic rays)[37] but not for the lower energy charged particles emitted from nuclear decay. In a nuclear setting, Cherenkov radiation is instead seen in dense media such as water or in a solution such as uranyl nitrate in a reprocessing plant. Cherenkov radiation could also be responsible for the "blue flash" experienced in an excursion due to the intersection of particles with the vitreous humour within the eyeballs of those in the presence of the criticality. This would also explain the absence of any record of blue light in video surveillance of the more recent incidents.

Heat effects

Some people reported feeling a "heat wave" during a criticality event.[38][39] It is not known whether this may be a psychosomatic reaction to the terrifying realization of what has just occurred (i.e. the high probability of inevitable impending death from a fatal radiation dose), or if it is a physical effect of heating (or nonthermal stimulation of heat sensing nerves in the skin) due to energy emitted by the criticality event.

A review of all of the criticality accidents with eyewitness accounts indicates that the heat waves were only observed when the fluorescent blue glow (the non-Cherenkov light, see above) was also observed. This would suggest a possible relationship between the two, and indeed, one can be potentially identified. In dense air, over 30% of the emissions lines from nitrogen and oxygen are in the ultraviolet range, and about 45% are in the infrared range. Only about 25% are in the visible range. Since the skin feels light (visible or otherwise) through its heating of the skin surface, it is possible that this phenomenon can explain the heat wave perceptions.[40] However, this explanation has still not been confirmed and may be inconsistent with the intensity of light reported by witnesses compared to the intensity of heat perceived. Further research is hindered by the small amount of data available from the few instances where humans have witnessed these incidents and survived long enough to provide a detailed account of their experiences and observations.

See also

Notes

  1. 1 2 3 McLaughlin, Thomas P.; et al. (2000). A Review of Criticality Accidents (PDF). Los Alamos: Los Alamos National Laboratory. LA-13638. Retrieved 5 November 2012.
  2. 1 2 Lewis, Elmer E. Fundamentals of Nuclear Reactor Physics. Elsevier, 2008, p. 123. ISBN 978-0-12-370631-7
  3. ↑ Diana Preston Before the Fall-Out - From Marie Curie to Hiroshima - Transworld - 2005 - ISBN 0-385-60438-6 p, 278
  4. ↑ McLaughlin et al. pages 78, 80-83
  5. ↑ McLaughlin et al. page 93, "In this excursion, three people received radiation doses in the amounts of 66, 66, and 7.4 rep.", LA Appendix A: "rep: An obsolete term for absorbed dose in human tissue, replaced by rad. Originally derived from roentgen equivalent, physical."
  6. ↑ Dion, Arnold S., Harry Daghlian: America's first peacetime atom bomb fatality, retrieved April 13, 2010
  7. ↑ McLaughlin et al. pages 74-76, "His dose was estimated as 510 rem"
  8. ↑ "The blue flash". Restricted Data: The Nuclear Secrecy Blog. Retrieved 2016-06-29.
  9. ↑ Declassified report See pg. 23 for dimensions of beryllium hand-controlled sphere.
  10. ↑ McLaughlin et al. pages 74-76, "The eight people in the room received doses of about 2100, 360, 250, 160, 110, 65, 47, and 37 rem."
  11. ↑ Y-12’s 1958 nuclear criticality accident and increased safety
  12. ↑ Criticality accident at the Y-12 plant. Diagnosis and treatment of acute radiation injury, 1961, Geneva, World Health Organization, pp. 27-48.
  13. ↑ McLaughlin et al. page 96, "Radiation doses were intense, being estimated at 205, 320, 410, 415, 422, and 433 rem. Of the six persons present, one died shortly afterward, and the other five recovered after severe cases of radiation sickness."
  14. ↑ "1958-01-01". Retrieved 2011-01-02.
  15. ↑ Vinca reactor accident, 1958, compiled by Wm. Robert Johnston
  16. ↑ Nuove esplosioni a Fukushima: danni al nocciolo. Ue: “In Giappone l’apocalisse”, 14 marzo 2011
  17. ↑ The Cecil Kelley Criticality Accident
  18. ↑ Stacy, Susan M. (2000). "Chapter 15: The SL-1 Incident" (PDF). Proving the Principle: A History of The Idaho National Engineering and Environmental Laboratory, 1949-1999 (PDF). U.S. Department of Energy, Idaho Operations Office. pp. 138–149. ISBN 0-16-059185-6.
  19. ↑ McLaughlin et al. pages 33-34
  20. ↑ Johnstone
  21. ↑ "Wood River criticality accident, 1964". Retrieved 7 December 2016.
  22. ↑ McLaughlin et al. pages 40-43
  23. ↑ McLaughlin et al. page 103
  24. ↑ "NRC: Information Notice No. 83-66, Supplement 1: Fatality at Argentine Critical Facility". Retrieved 7 December 2016.
  25. ↑ Johnston, Wm. Robert. "Arzamas-16 criticality accident, 19". Retrieved July 8, 2013.
  26. ↑ Kudrik, Igor (June 23, 1997). "Arzamas-16 researcher died on June 20". Retrieved July 8, 2013.
  27. ↑ The criticality accident in Sarov, IAEA, 2001.
  28. ↑ McLaughlin et al. pages 53-56
  29. ↑ https://www.nrc.gov/reading-rm/doc-collections/commission/secys/2000/secy2000-0085/2000-0085scy.pdf
  30. ↑ https://www.nrc.gov/reading-rm/doc-collections/commission/secys/2000/secy2000-0085/attachment3.pdf
  31. ↑ McLaughlin et al. pages 74-75
  32. 1 2 McLaughlin et al. pages 81-82
  33. ↑ "Has Fukushima’s Reactor No. 1 Gone Critical?". Ecocentric - TIME.com. 2011-03-30. Retrieved 2011-04-01.
  34. ↑ Jonathan Tirone, Sachiko Sakamaki and Yuriy Humber (March 31, 2011). "Fukushima Workers Threatened by Heat Bursts; Sea Radiation Rises".
  35. ↑ Neutron beam observed 13 times at crippled Fukushima nuke plant. These "neutron beams" as explained in the popular media, do not explain or prove a criticality excursion, as the requisite signature (combined neutron/gamma ratio of approximately 1:3 was not confirmed). A more credible explanation is the presence of neutrons from continued fissions from the decay process. It is highly unlikely that a recriticality occurred in Fukushima 3 since workers near the reactor were not exposed to a high neutron dose in a very short time (milliseconds), and plant radiation instruments would have captured any "repeating spikes" that are characteristic of a continuing moderated criticality accident. TOKYO, March 23, Kyodo News http://web.archive.org/web/20110323214235/http://english.kyodonews.jp/news/2011/03/80539.html
  36. ↑ Japan Plant Fuel Melted Partway Through Reactors: Report Because there was no large radiation release in the proximity of the reactor, and available dosimetry did not indicate an abnormal neutron dose or neutron/gamma dose ratio, there is no evidence of a criticality accident at Fukushima. Friday, April 15, 2011 "Archived copy". Archived from the original on 2 December 2011. Retrieved 24 April 2011.
  37. ↑ "Science". Retrieved 7 December 2016.
  38. ↑ McLaughlin et al. page 42, "the operator saw a flash of light and felt a pulse of heat."
  39. ↑ McLaughlin et al. page 88, "There was a flash, a shock, a stream of heat in our faces."
  40. ↑ Minnema, "Criticality Accidents and the Blue Glow," American Nuclear Society Winter Meeting, 2007.

References

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