Copper(II) triflate

Copper(II) triflate
Names

IUPAC name Copper(II) trifluoromethanesulfonate
Other names Copper(II) triflate
Identifiers
CAS Number	34946-82-2^Y
3D model (JSmol)	Interactive image
ChemSpider	2016731^Y
ECHA InfoCard	100.047.531
PubChem CID	2734996
InChI InChI=1S/2CHF3O3S.Cu/c22-1(3,4)8(5,6)7;/h2(H,5,6,7);/q;;+2/p-2^Y Key: SBTSVTLGWRLWOD-UHFFFAOYSA-L^Y InChI=1/2CHF3O3S.Cu/c22-1(3,4)8(5,6)7;/h2(H,5,6,7);/q;;+2/p-2 Key: SBTSVTLGWRLWOD-NUQVWONBAL
SMILES [Cu+2].FC(F)(F)S([O-])(=O)=O.FC(F)(F)S([O-])(=O)=O
Properties
Chemical formula	C₂CuF₆O₆S₂
Molar mass	361.67 g·mol⁻¹
Appearance	white to pale blue powder
Solubility in water	very soluble, hygroscopic
Hazards
US health exposure limits (NIOSH):
PEL (Permissible)	TWA 1 mg/m³ (as Cu)^[1]
REL (Recommended)	TWA 1 mg/m³ (as Cu)^[1]
IDLH (Immediate danger)	TWA 100 mg/m³ (as Cu)^[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is ^YN ?)
Infobox references

Copper (II) triflate is the copper(II) salt of trifluoromethanesulfonic acid (known simply as triflic acid) which has a chemical formula of Cu(OSO₂CF₃)₂. This substance, first reported in 1972,^[2] is a powerful Lewis acid. It is used as a catalyst in several organic reactions, such as the Diels-Alder reaction^[3] and cyclopropanation reactions^[4] (much like Rhodium(II) acetate).

References

1 2 3 "NIOSH Pocket Guide to Chemical Hazards #0150". National Institute for Occupational Safety and Health (NIOSH).
↑ Jenkins, C.L.; Kochi, J.K. (1972). "Solvolytic Routes via Alkylcopper Intermediates in the Electron-Transfer Oxidation of Alkyl Radicals". Journal of the American Chemical Society. 94 (3): 843–855. doi:10.1021/ja00758a024.
↑ Evans, D.A.; Miller, S.J.; Lectka, T.; von Matt, P. (1999). "Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels−Alder Reaction". Journal of the American Chemical Society. 121 (33): 7559–7573. doi:10.1021/ja991190k.
↑ Salomon, R.G.; Kochi, J.K (1973). "Copper(I) catalysis in cyclopropanations with diazo compounds. Role of olefin coordination". Journal of the American Chemical Society. 95 (10): 3300–3310. doi:10.1021/ja00791a038.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.