Carbon dioxide equivalent

Carbon dioxide equivalent (CDE) and equivalent carbon dioxide (CO₂e and CO₂eq) are two related but distinct measures for describing how much global warming a given type and amount of greenhouse gas may cause, using the functionally equivalent amount or concentration of carbon dioxide (CO₂) as the reference.

Global warming potential

Carbon dioxide equivalency is a quantity that describes, for a given mixture and amount of greenhouse gas, the amount of CO₂ that would have the same global warming potential (GWP), when measured over a specified timescale (generally, 100 years). Carbon dioxide equivalency thus reflects the time-integrated radiative forcing of a quantity of emissions or rate of greenhouse gas emission—a flow into the atmosphere—rather than the instantaneous value of the radiative forcing of the stock (concentration) of greenhouse gases in the atmosphere described by CO₂e.

The carbon dioxide equivalency for a gas is obtained by multiplying the mass and the GWP of the gas. The following units are commonly used:

By the UN climate change panel IPCC: n×10¹² tonnes of CO₂ equivalent (GtCO₂eq).
In industry: million metric tonnes of carbon dioxide equivalents (MMTCDE).
For vehicles: g of carbon dioxide equivalents / km (gCDE/km).

For example, the GWP for methane over 100 years is 34^[1] and for nitrous oxide 298. This means that emissions of 1 million metric tonnes of methane and nitrous oxide respectively is equivalent to emissions of 34 and 298 million metric tonnes of carbon dioxide.^[2]

Equivalent carbon dioxide

Equivalent CO₂ (CO₂e) is the concentration of CO₂ that would cause the same level of radiative forcing as a given type and concentration of greenhouse gas. Examples of such greenhouse gases are methane, perfluorocarbons, and nitrous oxide. CO₂e is expressed as parts per million by volume, ppmv.

CO₂e calculation examples:

The radiative forcing for pure CO₂ is approximated by $RF=\alpha ln(C/C_{0})$ where C is the present concentration, $\alpha$ is a constant, 5.35, and $C_{0}$ is the pre-industrial concentration, 280 ppm. Hence the value of CO₂e for an arbitrary gas mixture with a known radiative forcing is given by $C_{0}exp(RF/\alpha )$ in ppmv.
To calculate the radiative forcing for a 1998 gas mixture, IPCC 2001 gives the radiative forcing (relative to 1750) of various gases as: CO₂=1.46 (corresponding to a concentration of 365 ppmv), CH₄=0.48, N₂O=0.15 and other minor gases =0.01 W/m2. The sum of these is 2.10 W/m2. Inserting this to the above formula, we obtain CO₂e = 412 ppmv.
To calculate the CO₂e of the additional radiative forcing calculated from April 2016's updated data:^[3] ∑ RF(GHGs) = 3.3793, thus CO₂e = 280 e^3.3793/5.35 ppmv = 526.6 ppmv.

References

↑ "Climate Change 2013: The Physical Science Basis". IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, Ch.8, p. 711-714, Table 8.7. 2013. Retrieved 2014-02-13.
↑ IPCC AR4 WG1, Table 2.14, p.212
↑ Blasing, T.J. (April 2016), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032

External links

The different meanings of CO₂e explained

Bibliography

Gohar and Shine, Equivalent CO₂ and its use in understanding the climate effects of increased greenhouse gas concentrations, Weather, Nov 2007, pp. 307–311.

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