Isotopes of berkelium
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Berkelium (97Bk) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 243Bk in 1949. There are 20 known radioisotopes, from 235Bk to 254Bk, and 6 nuclear isomers. The longest-lived isotope is 247Bk with a half-life of 1,380 years.
Actinides vs fission products
Actinides and fission products by half-life | ||||||||
---|---|---|---|---|---|---|---|---|
Actinides[2] by decay chain | Half-life range (y) |
Fission products of 235U by yield[3] | ||||||
4n | 4n+1 | 4n+2 | 4n+3 | |||||
4.5–7% | 0.04–1.25% | <0.001% | ||||||
228Ra№ | 4–6 | † | 155Euþ | |||||
244Cmƒ | 241Puƒ | 250Cf | 227Ac№ | 10–29 | 90Sr | 85Kr | 113mCdþ | |
232Uƒ | 238Puƒ№ | 243Cmƒ | 29–97 | 137Cs | 151Smþ | 121mSn | ||
248Bk[4] | 249Cfƒ | 242mAmƒ | 141–351 |
No fission products | ||||
241Amƒ | 251Cfƒ[5] | 430–900 | ||||||
226Ra№ | 247Bk | 1.3 k – 1.6 k | ||||||
240Puƒ№ | 229Th№ | 246Cmƒ | 243Amƒ | 4.7 k – 7.4 k | ||||
245Cmƒ | 250Cm | 8.3 k – 8.5 k | ||||||
239Puƒ№ | 24.1 k | |||||||
230Th№ | 231Pa№ | 32 k – 76 k | ||||||
236Npƒ | 233Uƒ№ | 234U№ | 150 k – 250 k | ‡ | 99Tc₡ | 126Sn | ||
248Cm | 242Puƒ | 327 k – 375 k | 79Se₡ | |||||
1.53 M | 93Zr | |||||||
237Npƒ№ | 2.1 M – 6.5 M | 135Cs₡ | 107Pd | |||||
236U№ | 247Cmƒ | 15 M – 24 M | 129I₡ | |||||
244Pu№ | 80 M |
... nor beyond 15.7 M years[6] | ||||||
232Th№ | 238U№ | 235Uƒ№ | 0.7 G – 14.1 G | |||||
Legend for superscript symbols |
List of isotopes
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[7][n 1] |
daughter isotope(s) |
nuclear spin |
---|---|---|---|---|---|---|---|
excitation energy | |||||||
233Bk[8] | 97 | 136 | 21 s | α | 229Am | ||
235Bk | 97 | 138 | 235.05658(43)# | 20# s | α | 231Am | |
β+ | 235Cm | ||||||
236Bk | 97 | 139 | 236.05733(43)# | 22(+13-6) s[9] | α | 232Am | |
β+ | 236Cm | ||||||
237Bk | 97 | 140 | 237.05700(24)# | 1# min | α | 233Am | 7/2+# |
β+ (rare) | 237Cm | ||||||
238Bk | 97 | 141 | 238.05828(31)# | 2.40(8) min | α | 234Am | |
β+, SF (.048%) | (various) | ||||||
β+ (rare) | 238Cm | ||||||
239Bk | 97 | 142 | 239.05828(25)# | 3# min | α | 235Am | 7/2+# |
β+ | 239Cm | ||||||
240Bk | 97 | 143 | 240.05976(16)# | 4.8(8) min | β+ (90%) | 240Cm | |
α (10%) | 236Am | ||||||
β+, SF (.002%) | (various) | ||||||
241Bk | 97 | 144 | 241.06023(22)# | 4.6(4) min | α | 237Am | (7/2+) |
β+ (rare) | 241Cm | ||||||
242Bk | 97 | 145 | 242.06198(22)# | 7.0(13) min | β+ (99.99%) | 242Cm | 2−# |
β+, SF (3×10−4%) | (various) | ||||||
242mBk | 200(200)# keV | 600(100) ns | |||||
243Bk | 97 | 146 | 243.063008(5) | 4.5(2) h | β+ (99.85%) | 243Cm | (3/2−) |
α (.15%) | 239Am | ||||||
244Bk | 97 | 147 | 244.065181(16) | 4.35(15) h | β+ (99.99%) | 244Cm | (4−)# |
α (.006%) | 240Am | ||||||
245Bk | 97 | 148 | 245.0663616(25) | 4.94(3) d | EC (99.88%) | 245Cm | 3/2− |
α (.12%) | 241Am | ||||||
246Bk | 97 | 149 | 246.06867(6) | 1.80(2) d | β+ (99.8%) | 246Cm | 2(−) |
α (.2%) | 242Am | ||||||
247Bk | 97 | 150 | 247.070307(6) | 1.38(25)×103 y | α | 243Am | (3/2−) |
SF (rare) | (various) | ||||||
248Bk | 97 | 151 | 248.07309(8)# | >300 y[10] | α | 244Am | 6+# |
248mBk | 30(70)# keV | 23.7(2) h | 1(−) | ||||
249Bk[n 2] | 97 | 152 | 249.0749867(28) | 330(4) d | β− | 249Cf | 7/2+ |
α (.00145%) | 245Am | ||||||
SF (4.7×10−8%) | (various) | ||||||
249mBk | 8.80(10) keV | 300 µs | (3/2−) | ||||
250Bk | 97 | 153 | 250.078317(4) | 3.212(5) h | β− | 250Cf | 2− |
250m1Bk | 35.59(5) keV | 29(1) µs | (4+) | ||||
250m2Bk | 84.1(21) keV | 213(8) µs | (7+) | ||||
251Bk | 97 | 154 | 251.080760(12) | 55.6(11) min | β− | 251Cf | (3/2−)# |
α (10−5%) | 247Am | ||||||
251mBk | 35.5(13) keV | 58(4) µs | (7/2+)# | ||||
252Bk | 97 | 155 | 252.08431(22)# | 1.8(5) min | β− | 252Cf | |
α | 248Am | ||||||
253Bk | 97 | 156 | 253.08688(39)# | 10# min | β− | 253Cf | |
254Bk | 97 | 157 | 254.09060(32)# | 1# min | β− | 254Cf |
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition
SF: Spontaneous fission - ↑ Easiest isotope to synthesize
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
See also
References
- ↑ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. doi:10.1016/0029-5582(65)90719-4.
- ↑ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
- ↑ Specifically from thermal neutron fission of U-235, e.g. in a typical nuclear reactor.
- ↑ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. doi:10.1016/0029-5582(65)90719-4.
"The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 y. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 y. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 y." - ↑ This is the heaviest nuclide with a half-life of at least four years before the "Sea of Instability".
- ↑ Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is nearly eight quadrillion years.
- ↑ "Universal Nuclide Chart". nucleonica. (Registration required (help)).
- ↑ "Observation of new neutron-deficient isotopes with Z ≥ 92 in multinucleon transfer reactions" http://inspirehep.net/record/1383747/files/scoap3-fulltext.pdf
- ↑ Konki, J. et. al. (10 Jan 2017). "Towards saturation of the electron-capture delayed fission probability: The new isotopes 240Es and 236Bk". Physics Letters B. 764: 265–270. ISSN 0370-2693. Retrieved 6 Dec 2016.
- ↑ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. doi:10.1016/0029-5582(65)90719-4.
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005. Check date values in:
|access-date=
(help) - N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
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