Allylpalladium chloride dimer
Names | |
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IUPAC name
Allylpalladium(II) chloride dimer | |
Other names
Allylpalladium chloride dimer bis(allyl)di-μ-chloro-dipalladium(II) APC | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.031.423 |
PubChem CID |
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Properties | |
C6H10Cl2Pd2 | |
Molar mass | 365.85 g/mol |
Appearance | Pale yellow, crystalline solid |
Density | Solid |
Melting point | decomp at 155-156 °C |
Insoluble | |
Solubility in other solvents | Chloroform benzene acetone methanol |
Hazards | |
Safety data sheet | http://www.colonialmetals.com/pdf/5048.pdf |
R-phrases (outdated) | 36/37/38 |
S-phrases (outdated) | 26-36 |
Related compounds | |
Related compounds |
(η3-allyl)(η5 – cyclopentadienyl)palladium(II) di-μ-chlorobis(crotyl)dipalladium |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
Allylpalladium(II) chloride dimer (APC) is a chemical compound with the formula [(η3-C3H5)PdCl]2. This yellow air-stable compound is an important catalyst used in organic synthesis.[1] It is one of the most widely used transition metal allyl complexes.
Synthesis and reactions
The compound is prepared by purging carbon monoxide through a methanolic aqueous solution of sodium tetrachloropalladate (prepared from palladium(II) chloride and sodium chloride), and allyl chloride.[1]
- 2 Na2PdCl4 + 2 CH2=CHCH2Cl + 2 CO + 2 H2O → [(η3-C3H5)PdCl]2 + 4 NaCl + 2 CO2 + 4 HCl
APC reacts with sources of cyclopentadienyl anion to give the corresponding 18e complex cyclopentadienyl allyl palladium:
- [(η3-C3H5)PdCl]2 + 2 NaC5H5 → 2 [(η5-C5H5)Pd(η3-C3H5)] + 2 NaCl
References
- 1 2 Tatsuno, Y.; Yoshida, T.; Otsuka, S. "(η3-allyl)palladium(II) Complexes" Inorganic Syntheses, 1990, volume 28, pages 342-345. ISBN 0-471-52619-3
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