Allen–Cahn equation
The Allen–Cahn equation (after John W. Cahn and Sam Allen) is a reaction-diffusion equation of mathematical physics which describes the process of phase separation in multi-component alloy systems, including order-disorder transitions.
The equation describes the time evolution of a scalar-valued state variable on a domain during a time interval , and is given by:[1][2]
where is the mobility, is the free energy density, is the control on the state variable at the portion of the boundary , is the source control at , is the initial condition, and is the outward normal to .
It is the L2 gradient flow of the Ginzburg–Landau–Wilson Free Energy Functional. It is closely related to the Cahn–Hilliard equation. In one space-dimension, a very detailed account is given by a paper by Xinfu Chen.[3]
References
- ↑ S. M. Allen and J. W. Cahn, "Ground State Structures in Ordered Binary Alloys with Second Neighbor Interactions," Acta Met. 20, 423 (1972).
- ↑ S. M. Allen and J. W. Cahn, "A Correction to the Ground State of FCC Binary Ordered Alloys with First and Second Neighbor Pairwise Interactions," Scripta Met. 7, 1261 (1973).
- ↑ X. Chen, "Generation, propagation, and annihilation of metastable patterns", J. Differential Equations 206, 399–437 (2004).
- http://www.ctcms.nist.gov/~wcraig/variational/node10.html
- S. M. Allen and J. W. Cahn, "Coherent and Incoherent Equilibria in Iron-Rich Iron-Aluminum Alloys," Acta Met. 23, 1017 (1975).
- S. M. Allen and J. W. Cahn, "On Tricritical Points Resulting from the Intersection of Lines of Higher-Order Transitions with Spinodals," Scripta Met. 10, 451–454 (1976).
- S. M. Allen and J. W. Cahn, "Mechanisms of Phase Transformation Within the Miscibility Gap of Fe-Rich Fe-Al Alloys," Acta Met. 24, 425–437 (1976).
- J. W. Cahn and S. M. Allen, "A Microscopic Theory of Domain Wall Motion and Its Experimental Verification in Fe-Al Alloy Domain Growth Kinetics," J. de Physique 38, C7-51 (1977).
- S. M. Allen and J. W. Cahn, "A Microscopic Theory for Antiphase Boundary Motion and Its Application to Antiphase Domain Coarsening," Acta Met.27, 1085–1095 (1979).
- L. Bronsard & F. Reitich, On three-phase boundary motion and the singular limit of a vector valued Ginzburg–Landau equation, Arch. Rat. Mech. Anal. 124, 355–379 (1993).