Tetraxenonogold(II)

Tetraxenonogold(II)

Identifiers
ChemSpider	21106483
Jmol interactive 3D	Image
InChI InChI=1S/Au.4Xe/q+2;;;; Key: FIAFJDZYGVZLAJ-UHFFFAOYSA-N InChI=1/Au.4Xe/q+2;;;;/rAuXe4/c2-1(3,4)5/q+2 Key: FIAFJDZYGVZLAJ-YSLMZIHEAX
SMILES [Xe][Au+2]([Xe])([Xe])[Xe]
Properties
Chemical formula	AuXe4
Molar mass	722.138
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tetraxenonogold(II), gold tetraxenide(II) or AuXe2+
4 is a cationic complex with a square planar configuration of atoms. It is found in the compound AuXe2+
4(Sb
2F−
11)
2, which exists in triclinic and tetragonal crystal modifications.^[1] The AuXe2+
4 ion is stabilised by interactions with the fluoride atoms of the counterion. The Au-Xe bond length is 274 pm.^[2][3]

Tetraxenonogold(II) is unusual in that it is a compound of the notoriously inert atoms xenon and gold. It is also unusual in that it uses xenon as a transition metal ligand, and in that it contains gold in the +2 oxidation state. It can be produced by reduction of AuF₃ in the presence of fluoroantimonic acid and xenon, and crystallised at low temperature.^[4] The xenon bonds with the gold(II) ion to make this complex.

References