Isotopes of silver
Naturally occurring silver (Ag) is composed of the two stable isotopes 107Ag and 109Ag with 107Ag being the more abundant (51.839% natural abundance). Twenty-eight radioisotopes have been characterized with the most stable being 105Ag with a half-life of 41.29 days, 111Ag with a half-life of 7.45 days, and 112Ag with a half-life of 3.13 hours.
All of the remaining radioactive isotopes have half-lives that are less than an hour and the majority of these have half-lives that are less than 3 minutes. This element has numerous meta states with the most stable being 108mAg (t* 418 years), 110mAg (t* 249.79 days) and 106mAg (t* 8.28 days).
Isotopes of silver range in atomic weight from 92.950 u (93Ag) to 129.950 u (130Ag). The primary decay mode before the most abundant stable isotope, 107Ag, is electron capture and the primary mode after is beta decay. The primary decay products before 107Ag are palladium (element 46) isotopes and the primary products after are cadmium (element 48) isotopes.
The palladium isotope 107Pd decays by beta emission to 107Ag with a half-life of 6.5 million years. Iron meteorites are the only objects with a high enough palladium/silver ratio to yield measurable variations in 107Ag abundance. Radiogenic 107Ag was first discovered in the Santa Clara meteorite in 1978.
The discoverers suggest that the coalescence and differentiation of iron-cored small planets may have occurred 10 million years after a nucleosynthetic event. 107Pd versus 107Ag correlations observed in bodies, which have clearly been melted since the accretion of the solar system, must reflect the presence of live short-lived nuclides in the early solar system.
Relative atomic mass: 107.8682(2)
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[1][n 1] |
daughter isotope(s)[n 2] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
93Ag | 47 | 46 | 92.94978(64)# | 5# ms [>1.5 µs] |
9/2+# | ||||
94Ag | 47 | 47 | 93.94278(54)# | 37(18) ms [26(+26−9) ms] |
β+ | 94Pd | 0+# | ||
94m1Ag | 1350(400)# keV | 422(16) ms | β+ (>99.9%) | 94Pd | (7+) | ||||
β+, p (<.1%) | 93Rh | ||||||||
94m2Ag | 6500(2000)# keV | 300(200) ms | (21+) | ||||||
95Ag | 47 | 48 | 94.93548(43)# | 1.74(13) s | β+ (>99.9%) | 95Pd | (9/2+) | ||
β+, p (<.1%) | 94Rh | ||||||||
95m1Ag | 344.2(3) keV | <0.5 s | (1/2−) | ||||||
95m2Ag | 2531(1) keV | <16 ms | (23/2+) | ||||||
95m3Ag | 4859(1) keV | <40 ms | (37/2+) | ||||||
96Ag | 47 | 49 | 95.93068(43)# | 4.45(4) s | β+ (96.3%) | 96Pd | (8+) | ||
β+, p (3.7%) | 95Rh | ||||||||
96m1Ag | 0(50)# keV | 6.9(6) s | (2+) | ||||||
96m2Ag | 700(200) ns | ||||||||
97Ag | 47 | 50 | 96.92397(35) | 25.3(3) s | β+ | 97Pd | (9/2+) | ||
97mAg | 2343(49) keV | 5 ns | (21/2+) | ||||||
98Ag | 47 | 51 | 97.92157(7) | 47.5(3) s | β+ (99.99%) | 98Pd | (5+) | ||
β+, p (.0012%) | 97Rh | ||||||||
98mAg | 167.83(15) keV | 220(20) ns | (3+) | ||||||
99Ag | 47 | 52 | 98.91760(16) | 124(3) s | β+ | 99Pd | (9/2)+ | ||
99mAg | 506.1(4) keV | 10.5(5) s | IT | 99Ag | (1/2−) | ||||
100Ag | 47 | 53 | 99.91610(8) | 2.01(9) min | β+ | 100Pd | (5)+ | ||
100mAg | 15.52(16) keV | 2.24(13) min | IT | 100Ag | (2)+ | ||||
β+ | 100Pd | ||||||||
101Ag | 47 | 54 | 100.91280(11) | 11.1(3) min | β+ | 101Pd | 9/2+ | ||
101mAg | 274.1(3) keV | 3.10(10) s | IT | 101Ag | 1/2− | ||||
102Ag | 47 | 55 | 101.91169(3) | 12.9(3) min | β+ | 102Pd | 5+ | ||
102mAg | 9.3(4) keV | 7.7(5) min | β+ (51%) | 102Pd | 2+ | ||||
IT (49%) | 102Ag | ||||||||
103Ag | 47 | 56 | 102.908973(18) | 65.7(7) min | β+ | 103Pd | 7/2+ | ||
103mAg | 134.45(4) keV | 5.7(3) s | IT | 103Ag | 1/2− | ||||
104Ag | 47 | 57 | 103.908629(6) | 69.2(10) min | β+ | 104Pd | 5+ | ||
104mAg | 6.9(4) keV | 33.5(20) min | β+ (99.93%) | 104Pd | 2+ | ||||
IT (.07%) | 104Ag | ||||||||
105Ag | 47 | 58 | 104.906529(12) | 41.29(7) d | β+ | 105Pd | 1/2− | ||
105mAg | 25.465(12) keV | 7.23(16) min | IT (99.66%) | 105Ag | 7/2+ | ||||
β+ (.34%) | 105Pd | ||||||||
106Ag | 47 | 59 | 105.906669(5) | 23.96(4) min | β+ (99.5%) | 106Pd | 1+ | ||
β− (0.5%) | 106Cd | ||||||||
106mAg | 89.66(7) keV | 8.28(2) d | β+ | 106Pd | 6+ | ||||
IT (4.16×10−6%) | 106Ag | ||||||||
107Ag[n 3] | 47 | 60 | 106.905097(5) | Stable[n 4] | 1/2− | 0.51839(8) | |||
107mAg | 93.125(19) keV | 44.3(2) s | IT | 107Ag | 7/2+ | ||||
108Ag | 47 | 61 | 107.905956(5) | 2.37(1) min | β− (97.15%) | 108Cd | 1+ | ||
β+ (2.85%) | 108Pd | ||||||||
108mAg | 109.440(7) keV | 418(21) y | β+ (91.3%) | 108Pd | 6+ | ||||
IT (8.96%) | 108Ag | ||||||||
109Ag[n 5] | 47 | 62 | 108.904752(3) | Stable[n 4] | 1/2− | 0.48161(8) | |||
109mAg | 88.0341(11) keV | 39.6(2) s | IT | 109Ag | 7/2+ | ||||
110Ag | 47 | 63 | 109.906107(3) | 24.6(2) s | β− (99.7%) | 110Cd | 1+ | ||
EC (.3%) | 110Pd | ||||||||
110m1Ag | 1.113 keV | 660(40) ns | 2− | ||||||
110m2Ag | 117.59(5) keV | 249.950(24) d | β− (98.64%) | 110Cd | 6+ | ||||
IT (1.36%) | 110Ag | ||||||||
111Ag[n 5] | 47 | 64 | 110.905291(3) | 7.45(1) d | β− | 111Cd | 1/2− | ||
111mAg | 59.82(4) keV | 64.8(8) s | IT (99.3%) | 111Ag | 7/2+ | ||||
β− (.7%) | 111Cd | ||||||||
112Ag | 47 | 65 | 111.907005(18) | 3.130(9) h | β− | 112Cd | 2(−) | ||
113Ag | 47 | 66 | 112.906567(18) | 5.37(5) h | β− | 113mCd | 1/2− | ||
113mAg | 43.50(10) keV | 68.7(16) s | IT (64%) | 113Ag | 7/2+ | ||||
β− (36%) | 113Cd | ||||||||
114Ag | 47 | 67 | 113.908804(27) | 4.6(1) s | β− | 114Cd | 1+ | ||
114mAg | 199(5) keV | 1.50(5) ms | IT | 114Ag | (<7+) | ||||
115Ag | 47 | 68 | 114.90876(4) | 20.0(5) min | β− | 115mCd | 1/2− | ||
115mAg | 41.16(10) keV | 18.0(7) s | β− (79%) | 115Cd | 7/2+ | ||||
IT (21%) | 115Ag | ||||||||
116Ag | 47 | 69 | 115.91136(5) | 2.68(10) min | β− | 116Cd | (2)− | ||
116mAg | 81.90(20) keV | 8.6(3) s | β− (94%) | 116Cd | (5+) | ||||
IT (6%) | 116Ag | ||||||||
117Ag | 47 | 70 | 116.91168(5) | 73.6(14) s [72.8(+20−7) s] |
β− | 117mCd | 1/2−# | ||
117mAg | 28.6(2) keV | 5.34(5) s | β− (94%) | 117mCd | (7/2+) | ||||
IT (6%) | 117Ag | ||||||||
118Ag | 47 | 71 | 117.91458(7) | 3.76(15) s | β− | 118Cd | 1- | ||
118m1Ag | 45.79(9) keV | ~0.1 µs | 0(−) to 2(−) | ||||||
118m2Ag | 127.49(5) keV | 2.0(2) s | β− (59%) | 118Cd | 4(+) | ||||
IT (41%) | 118Ag | ||||||||
118m3Ag | 279.37(20) keV | ~0.1 µs | (2+,3+) | ||||||
119Ag | 47 | 72 | 118.91567(10) | 6.0(5) s | β− | 119mCd | 1/2−# | ||
119mAg | 20(20)# keV | 2.1(1) s | β− | 119Cd | 7/2+# | ||||
120Ag | 47 | 73 | 119.91879(8) | 1.23(4) s | β− (99.99%) | 120Cd | 3(+#) | ||
β−, n (.003%) | 119Cd | ||||||||
120mAg | 203.0(10) keV | 371(24) ms | β− (63%) | 120Cd | 6(−) | ||||
IT (37%) | 120Ag | ||||||||
121Ag | 47 | 74 | 120.91985(16) | 0.79(2) s | β− (99.92%) | 121Cd | (7/2+)# | ||
β−, n (.076%) | 120Cd | ||||||||
122Ag | 47 | 75 | 121.92353(22)# | 0.529(13) s | β− (>99.9%) | 122Cd | (3+) | ||
β−, n (<.1%) | 121Cd | ||||||||
122mAg | 80(50)# keV | 1.5(5) s | β− (>99.9%) | 122Cd | 8-# | ||||
β−, n (<.1%) | 121Cd | ||||||||
123Ag | 47 | 76 | 122.92490(22)# | 0.300(5) s | β− (99.45%) | 123Cd | (7/2+) | ||
β−, n (.549%) | 122Cd | ||||||||
124Ag | 47 | 77 | 123.92864(21)# | 172(5) ms | β− (99.9%) | 124Cd | 3+# | ||
β−, n (.1%) | 123Cd | ||||||||
124mAg | 0(100)# keV | 200# ms | β− | 124Cd | 8-# | ||||
IT | 124Ag | ||||||||
125Ag | 47 | 78 | 124.93043(32)# | 166(7) ms | β− (>99.9%) | 125Cd | (7/2+)# | ||
β−, n (<.1%) | 124Cd | ||||||||
126Ag | 47 | 79 | 125.93450(32)# | 107(12) ms | β− (>99.9%) | 126Cd | 3+# | ||
β−, n (<.1%) | 125Cd | ||||||||
127Ag | 47 | 80 | 126.93677(32)# | 79(3) ms | β− (>99.9%) | 127Cd | 7/2+# | ||
β−, n (<.1%) | 126Cd | ||||||||
128Ag | 47 | 81 | 127.94117(32)# | 58(5) ms | |||||
129Ag | 47 | 82 | 128.94369(43)# | 44(7) ms [46(+5−9) ms] |
7/2+# | ||||
129mAg | 0(200)# keV | ~160 ms | 1/2−# | ||||||
130Ag | 47 | 83 | 129.95045(36)# | ~50 ms | 0+ |
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes, bold italics for nearly-stable isotopes (half-life longer than the age of the universe)
- ↑ Used to date certain events in the early history of the Solar System
- 1 2 Theoretically capable of spontaneous fission
- 1 2 Fission product
Notes
- The precision of the isotope abundances and atomic mass is limited through variations. The given ranges should be applicable to any normal terrestrial material.
- Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ↑ "Universal Nuclide Chart". nucleonica. (registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of palladium | Isotopes of silver | Isotopes of cadmium |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
|