Even and odd atomic nuclei

Nuclear physics
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In nuclear physics, properties of a nucleus depend on evenness or oddness of its atomic number Z, neutron number N and, consequently, of their sum, the mass number A. Most notably, oddness of both Z and N tends to lower the nuclear binding energy, making odd nuclei, generally, less stable. This effect is not only experimentally observed, but is included to the semi-empirical mass formula and explained by some other nuclear models, such as nuclear shell model. This remarkable difference of nuclear binding energy between neighbouring nuclei, especially of odd-A isobars, has important consequences for beta decay.

Also, the nuclear spin is integer for all even-A nuclei and non-integer (half-integer) for all odd-A nuclei.

The neutron–proton ratio is not the only factor affecting nuclear stability. Adding neutrons to isotopes can vary their nuclear spins and nuclear shapes, causing differences in neutron capture cross-sections and gamma spectroscopy and nuclear magnetic resonance properties. If too many or too few neutrons are present with regard to the nuclear binding energy optimum, the nucleus becomes unstable and subject to certain types of nuclear decay. Unstable nuclides with a nonoptimal number of neutrons or protons decay by beta decay (including positron decay), electron capture or other exotic means, such as spontaneous fission and cluster decay.

Even mass number

Even-mass-number nuclides, which comprise 153/254 = ~ 60% of all stable nuclides, are bosons, i.e. they have integer spin. Almost all (148 of the 153) are even-proton, even-neutron (EE) nuclides, which necessarily have spin 0 because of pairing. The remainder of the stable bosonic nuclides are 5 odd-proton, odd-neutron stable nuclides (see below, these are: 2
1H, 6
3Li, 10
5B, 14
7N and 180m
73Ta, all having a non-zero integer spin.

Pairing effects

Beta decay of an even–even nucleus produces an odd–odd nucleus, and vice versa. An even number of protons or of neutrons are more stable (higher binding energy) because of pairing effects, so even–even nuclei are much more stable than odd–odd. One effect is that there are few stable odd–odd nuclides, but another effect is to prevent beta decay of many even–even nuclei into another even–even nucleus of the same mass number but lower energy, because decay proceeding one step at a time would have to pass through an odd–odd nucleus of higher energy. Double beta decay directly from even–even to even–even skipping over an odd–odd nuclide is only occasionally possible, and even then with a half-life greater than a billion times the age of the universe. For example, the double beta emitter 116Cd has a half-life of 7019290000000000000♠2.9×10¹⁹ years. This makes for a larger number of stable even–even nuclides, up to three for some mass numbers, and up to seven for some atomic (proton) numbers.

For example, the extreme stability of helium-4 due to a double pairing of 2 protons and 2 neutrons prevents any nuclides containing five or eight nucleons from existing for long enough to serve as platforms for the buildup of heavier elements via nuclear fusion in stars (see triple alpha process).

Even proton, even neutron

There are 148 stable even–even nuclides, forming ~58% of the 254 stable nuclides. There are also 22 primordial long-lived even–even nuclides. As a result, many of the 41 even-numbered elements from 2 to 82 have many primordial isotopes. Half of these even-numbered elements have six or more stable isotopes.

All even–even nuclides have spin 0 in their ground state.

Odd proton, odd neutron

Only five stable nuclides contain both an odd number of protons and an odd number of neutrons. The first four "odd–odd" nuclides occur in low mass nuclides, for which changing a proton to a neutron or vice versa would lead to a very lopsided proton–neutron ratio (2
1H, 6
3Li, 10
5B, and 14
7N; spins 1, 1, 3, 1). The only other observationally "stable" odd–odd nuclide is 180m
73Ta (spin 9), the only primordial nuclear isomer, which has not yet been observed to decay despite experimental attempts.^[1] Also, four long-lived radioactive odd–odd nuclides (40
19K, 50
23V,138
57La,176
71Lu; spins 4, 6, 5, 7) occur naturally. As in the case of 180m
73Ta decay of high spin nuclides by beta decay (including electron capture), gamma decay, or internal conversion is greatly inhibited if the only decay possible between isobar nuclides (or in the case of 180m
73Ta between nuclear isomers of the same nuclide) involves high multiples of a change in spin of 1 unit, the "preferred" change of spin that is associated with rapid decay. This high-spin inhibition of decay is the cause of the five heavy stable or long-lived odd-proton, odd-neutron nuclides discussed above. For an example of this effect where the spin effect is subtracted, tantalum-180, the odd–odd low-spin (theoretical) decay product of primordial tantalum-180m, itself has a half life of only about 8 hours.

Many odd–odd radionuclides (like tantalum-180) with comparatively short half lives are known. Almost invariably, these decay by positive or negative beta decay, in order to produce stable even–even isotopes which have paired protons and paired neutrons. In some odd–odd radionuclides where the ratio of neither protons or neutrons is "excessive" (i.e., falls too far from the ratio of maximal stability), this decay can proceed in either direction, turning a proton into a neutron, or vice versa. An example is 64
29Cu, which can decay either by positron emission to 64
28Ni, or by electron emission to 64
30Zn.

Of the nine primordial odd–odd nuclides (five stable and four radioactive with long half lives), only 14
7N is the most common isotope of a common element. This is the case because it is a part of the CNO cycle. The nuclides 6
3Li and 10
5B are minority isotopes of elements that are themselves rare compared to other light elements, while the other six isotopes make up only a tiny percentage of the natural abundance of their elements. For example, 180m
73Ta is thought to be the rarest of the 254 stable nuclides.

None of the primordial (i.e., stable or nearly stable) odd–odd nuclides have spin 0 in the ground state. This is because the single unpaired neutron and unpaired proton have a larger nuclear force attraction to each other if their spins are aligned (producing a total spin of at least 1 unit), instead of anti-aligned. See deuterium for the simplest case of this nuclear behavior.

Odd mass number

For a given odd mass number, there are few beta-stable nuclides, since there is not a difference in binding energy between even–odd and odd–even comparable to that between even–even and odd–odd, leaving other nuclides of the same mass number (isobars) free to beta decay toward the lowest-mass nuclide. For mass numbers of 5, 147, 151, and 209+, the beta-stable isobar of that mass number can alpha decay. (In theory, mass number 143 to 155, 160 to 162, and 165+ can also alpha decay). This gives a total of 101 stable nuclides with odd mass numbers. There are another 9 radioactive primordial nuclides (which by definition all have relatively long half lives, greater than 80 million years) with odd mass numbers.

Odd-mass-number nuclides are fermions, i.e. have half-integer spin. Generally speaking, since odd-mass-number nuclides always have an even number of either neutrons or protons, the even-numbered particles usually form part of a "core" in the nucleus with a spin of zero. The nucleon with the odd number (whether protons or neutrons) then form a second core with nucleons paired off, with most of the nuclear spin due to the orbital angular momentum and spin angular momentum of the last remaining nucleon. In all, 29 of the 110 primordial odd-mass nuclides have spin 1/2, 30 have spin 3/2, 24 have spin 5/2, 17 have spin 7/2, and nine have spin 9/2.^[2]

The odd-mass number stable nuclides are divided (roughly evenly) into odd-proton–even-neutron, and odd-neutron–even-proton nuclides, which are more thoroughly discussed below.

Odd proton, even neutron

These 48 stable nuclides, stabilized by their even numbers of paired neutrons, form most of the stable isotopes of the odd-numbered elements; the very few odd–odd nuclides comprise the others. There are 41 odd-numbered elements with Z = 1 through 81, of which 30 (including hydrogen) have one stable odd-even isotope, the elements technetium (
43Tc) and promethium (
61Pm) have no stable isotopes, and nine elements: chlorine (
17Cl), potassium (
19K), copper (
29Cu), gallium (
31Ga), bromine (
35Br), silver (
47Ag), antimony (
51Sb), iridium (
77Ir), and thallium (
81Tl), have two odd–even stable isotopes each. This makes a total 30 + 2(9) = 48 stable odd–even isotopes. There are also five primordial long-lived radioactive odd–even isotopes, 87
37Rb, 115
49In, 187
75Re, 151
63Eu, and 209
83Bi. The last two were only recently found to decay, with half-lives greater than 10¹⁸ years.

Even proton, odd neutron

These 53 stable nuclides have an even number of protons and an odd number of neutrons. By definition, they are all isotopes of even-Z elements, where they are a minority in comparison to the even–even isotopes which are about 3 times as numerous. Among the 41 even-Z elements that have a stable nuclide, only three elements (argon, cerium, and lead) have no even–odd stable nuclides. One element (tin) has three. There are 24 elements that have one even–odd nuclide and 13 that have two odd–even nuclides.

Of 35 primordial radionuclides there exist four even–odd nuclides (see table at right), including the fissile 235
92U.

Because of their odd neutron numbers, the even–odd nuclides tend to have large neutron capture cross sections, due to the energy that results from neutron-pairing effects.

These stable even-proton odd-neutron nuclides tend to be uncommon by abundance in nature, generally because in order to form and be enter into primordial abundance, they must have escaped capturing neutrons to form yet other stable even–even isotopes, during both the s-process and r-process of neutron capture, during nucleosynthesis in stars. For this reason, only 195
78Pt and 9
4Be are the most naturally abundant isotopes of their element, the former only by a small margin, and the latter only because the expected beryllium-8 has lower binding energy than two alpha particles and therefore alpha decays.

Odd neutron number

Actinides with odd neutron number are generally fissile (with thermal neutrons), while those with even neutron number are generally not, though they are fissionable with fast neutrons. Only 195
78Pt, 9
4Be and 14
7N have odd neutron number and are the most naturally abundant isotope of their element.

References