Melamine resin

Melamine resin

Melamine resin or melamine formaldehyde (also shortened to melamine) is a hard, thermosetting plastic material made from melamine and formaldehyde by polymerization. In its butylated form, it is dissolved in n-butanol and xylene. It is then used to cross-link with alkyd, epoxy, acrylic, and polyester resins, used in surface coatings. There are many types, varying from very slow to very fast curing. It was initially discovered by William F. Talbot .[1]

Applications

Construction material

The principal use of melamine resin is the main constituent of high-pressure laminates, such as Formica and Arborite, and of laminate flooring. Melamine-resin tile wall panels can also be used as whiteboards.[2] Melamine formaldehyde is used in plastic laminate and overlay materials. Formaldehyde is more tightly bound in MF than it is in urea-formaldehyde, reducing emissions.

Other

In the kitchen

A melamine-resin plate
A melamine-resin ladle

Melamine resin is often used in kitchen utensils and plates (such as Melmac). Melamine resin utensils and bowls are not microwave safe.[3]

During the late 1950s and 1960s melamine tableware became highly fashionable. Aided crucially by the stylish modern designs of A. H. Woodfull and the Product Design Unit of British Industrial Plastics, it was thought to threaten the dominant position of ceramics in the market. The tendency of melamine cups and plates to stain and scratch led sales to decline in the late 1960s, however, and eventually the material became largely restricted to the camping and nursery market.[4]

Cabinet and furniture making

Melamine resin is often used to saturate decorative paper that is laminated under heat and pressure and then pasted onto particle board; the resulting panel is often called melamine and commonly used in ready-to-assemble furniture and kitchen cabinets.

Melamine is available in different sizes and thicknesses, as well as a large number of colors and patterns. The sheets are heavy; the resin is prone to chipping when being cut with conventional table saws.[5]

Production and structure

Melamine-formaldehyde resin forms via the condensation of formaldehyde with melamine to give, under idealized conditions, the hexa-hydroxymethyl derivative. Upon heating in the presence of acid, this or similar hydroxymethylated species undergoes further condensation and crosslinking. Linkages between the heterocycles include mono-, di-, and polyethers. The microstructure of the material can be analyzed by NMR spectroscopy.[6]

Idealized chemical reactions leading to melamine-formaldehyde resin.

See also

References

  1. ↑ Gibson, Weldon B (1980). SRI: The Founding Years. Stanford Research Institute. ISBN 0-913232-80-7.
  2. ↑ H. Deim, G. Matthias, R. A. Wagner "Amino Resins" in Ullmann's Encyclopedia of Industrial Chemistry,2012, Wiley-VCH, Weinheim. doi:10.1002/14356007.a02_115.pub2
  3. ↑ Anne Field (2003-06-24). "Melamine Plastic". Home Maintenance and Repair. Michigan State University Extension.
  4. ↑ "The Rise and Fall of Melamine Tableware". plastiquarian (Plastics Historical Society) (32): 10. Summer 2004. Archived from the original on 2008-06-25. Retrieved 2008-12-12.
  5. ↑ "Melamine". Pro Woodworking Tips.com.
  6. ↑ David R. Bauer “Melamine/formaldehyde crosslinkers: characterization, network formation and crosslink degradation” Progress in Organic Coatings 1986, Volume 14, pp. 193–218. doi:10.1016/0033-0655(86)80001-2


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