Isotopes of gold
Gold (Au) has one stable isotope, 197Au, and 18 radioisotopes, with 195Au being the most stable with a half-life of 186 days.
Gold is currently considered the heaviest monoisotopic element (bismuth formerly held that distinction, but bismuth-209 has been found to be slightly radioactive).
Relative atomic mass: 196.966569(5).[1]
Radioactive particle tracking
Inside coker units at oil refineries, gold-198 is used to study the hydrodynamic behavior of solids in fluidized beds and can also be used to quantify the degree of fouling of bed internals.[2]
Nuclear medicine
Gold-198 is a beta emitter with range in tissue of about 11 mm and half life 2.7 days. It is used in some cancer treatments and for treating other diseases.[3][4] Gold-198 nanoparticles are being investigated as an injectable treatment for prostate cancer.[5]
Nuclear weapons
Gold has been proposed as a material for creating a salted nuclear weapon (cobalt is another, better-known salting material). A jacket of natural 197Au, irradiated by the intense high-energy neutron flux from an exploding thermonuclear weapon, would transmute into the radioactive isotope 198Au with a half-life of 2.697 days and produce approximately .411 MeV of gamma radiation, significantly increasing the radioactivity of the weapon's fallout for several days. Such a weapon is not known to have ever been built, tested, or used.[6] Gold has been used in thermonuclear weapons as radiation mirrors within the secondary assembly. Ivy Mike used a thin layer of gold on the secondary casing walls to enhance the blackbody effect, trapping more energy in the foam to enhance the implosion.[7]
The highest amount of 198Au detected in any United States nuclear test was in shot "Sedan" detonated at Nevada Test Site on July 6, 1962.[8]
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[9][n 1] |
daughter isotope(s)[n 2] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
169Au | 79 | 90 | 168.99808(32)# | 150# µs | 1/2+# | ||||
170Au | 79 | 91 | 169.99612(22)# | 310(50) µs [286(+50−40) µs] |
(2−) | ||||
170mAu | 275(14) keV | 630(60) µs [0.62(+6−5) ms] |
(9+) | ||||||
171Au | 79 | 92 | 170.991879(28) | 30(5) µs | p | 170Pt | (1/2+) | ||
α (rare) | 167Ir | ||||||||
171mAu | 250(16) keV | 1.014(19) ms | α (54%) | 167Ir | 11/2− | ||||
p (46%) | 170Pt | ||||||||
172Au | 79 | 93 | 171.99004(17)# | 4.7(11) ms | α (98%) | 168Ir | high | ||
p (2%) | 171Pt | ||||||||
173Au | 79 | 94 | 172.986237(28) | 25(1) ms | α | 169Ir | (1/2+) | ||
β+ (rare) | 173Pt | ||||||||
173mAu | 214(23) keV | 14.0(9) ms | α (96%) | 169Ir | (11/2−) | ||||
β+ (4%) | 173Pt | ||||||||
174Au | 79 | 95 | 173.98476(11)# | 139(3) ms | α | 170Ir | low | ||
β+ (rare) | 174Pt | ||||||||
174mAu | 360(70)# keV | 171(29) ms | high | ||||||
175Au | 79 | 96 | 174.98127(5) | 100# ms | α (82%) | 171Ir | 1/2+# | ||
β+ (18%) | 175Pt | ||||||||
175mAu | 200(30)# keV | 156(3) ms | α | 171Ir | 11/2−# | ||||
β+ | 175Pt | ||||||||
176Au | 79 | 97 | 175.98010(11)# | 1.08(17) s [0.84(+17−14) s] |
α (60%) | 172Ir | (5−) | ||
β+ (40%) | 176Pt | ||||||||
176mAu | 150(100)# keV | 860(160) ms | (7+) | ||||||
177Au | 79 | 98 | 176.976865(14) | 1.462(32) s | β+ (60%) | 177Pt | (1/2+,3/2+) | ||
α (40%) | 173Ir | ||||||||
177mAu | 216(26) keV | 1.180(12) s | 11/2− | ||||||
178Au | 79 | 99 | 177.97603(6) | 2.6(5) s | β+ (60%) | 178Pt | |||
α (40%) | 174Ir | ||||||||
179Au | 79 | 100 | 178.973213(18) | 7.1(3) s | β+ (78%) | 179Pt | 5/2−# | ||
α (22%) | 175Ir | ||||||||
179mAu | 99(16) keV | (11/2−) | |||||||
180Au | 79 | 101 | 179.972521(23) | 8.1(3) s | β+ (98.2%) | 180Pt | |||
α (1.8%) | 176Ir | ||||||||
181Au | 79 | 102 | 180.970079(21) | 13.7(14) s | β+ (97.3%) | 181Pt | (3/2−) | ||
α (2.7%) | 177Ir | ||||||||
182Au | 79 | 103 | 181.969618(22) | 15.5(4) s | β+ (99.87%) | 182Pt | (2+) | ||
α (.13%) | 178Ir | ||||||||
183Au | 79 | 104 | 182.967593(11) | 42.8(10) s | β+ (99.2%) | 183Pt | (5/2)− | ||
α (.8%) | 179Ir | ||||||||
183m1Au | 73.3(4) keV | >1 µs | (1/2)+ | ||||||
183m2Au | 230.6(6) keV | <1 µs | (11/2)− | ||||||
184Au | 79 | 105 | 183.967452(24) | 20.6(9) s | β+ | 184Pt | 5+ | ||
184mAu | 68.46(1) keV | 47.6(14) s | β+ (70%) | 184Pt | 2+ | ||||
IT (30%) | 184Au | ||||||||
α (.013%) | 180Ir | ||||||||
185Au | 79 | 106 | 184.965789(28) | 4.25(6) min | β+ (99.74%) | 185Pt | 5/2− | ||
α (.26%) | 181Ir | ||||||||
185mAu | 100(100)# keV | 6.8(3) min | 1/2+# | ||||||
186Au | 79 | 107 | 185.965953(23) | 10.7(5) min | β+ (99.9992%) | 186Pt | 3− | ||
α (8×10−4%) | 182Ir | ||||||||
186mAu | 227.77(7) keV | 110(10) ns | 2+ | ||||||
187Au | 79 | 108 | 186.964568(27) | 8.4(3) min | β+ (99.997%) | 187Pt | 1/2+ | ||
α (.003%) | 183Ir | ||||||||
187mAu | 120.51(16) keV | 2.3(1) s | IT | 187Au | 9/2− | ||||
188Au | 79 | 109 | 187.965324(22) | 8.84(6) min | β+ | 188Pt | 1(−) | ||
189Au | 79 | 110 | 188.963948(22) | 28.7(3) min | β+ (99.9997%) | 189Pt | 1/2+ | ||
α (3×10−4%) | 185Ir | ||||||||
189m1Au | 247.23(16) keV | 4.59(11) min | β+ | 189Pt | 11/2− | ||||
IT (rare) | 189Au | ||||||||
189m2Au | 325.11(16) keV | 190(15) ns | 9/2− | ||||||
189m3Au | 2554.7(12) keV | 242(10) ns | 31/2+ | ||||||
190Au | 79 | 111 | 189.964700(17) | 42.8(10) min | β+ | 190Pt | 1− | ||
α (10−6%) | 186Ir | ||||||||
190mAu | 200(150)# keV | 125(20) ms | IT | 190Au | 11−# | ||||
β+ (rare) | 190Pt | ||||||||
191Au | 79 | 112 | 190.96370(4) | 3.18(8) h | β+ | 191Pt | 3/2+ | ||
191m1Au | 266.2(5) keV | 920(110) ms | IT | 191Au | (11/2−) | ||||
191m2Au | 2490(1) keV | >400 ns | |||||||
192Au | 79 | 113 | 191.964813(17) | 4.94(9) h | β+ | 192Pt | 1− | ||
192m1Au | 135.41(25) keV | 29 ms | IT | 192Au | (5#)+ | ||||
192m2Au | 431.6(5) keV | 160(20) ms | (11−) | ||||||
193Au | 79 | 114 | 192.964150(11) | 17.65(15) h | β+ (100%) | 193Pt | 3/2+ | ||
α (10−5%) | 189Ir | ||||||||
193m1Au | 290.19(3) keV | 3.9(3) s | IT (99.97%) | 193Au | 11/2− | ||||
β+ (.03%) | 193Pt | ||||||||
193m2Au | 2486.5(6) keV | 150(50) ns | (31/2+) | ||||||
194Au | 79 | 115 | 193.965365(11) | 38.02(10) h | β+ | 194Pt | 1− | ||
194m1Au | 107.4(5) keV | 600(8) ms | IT | 194Au | (5+) | ||||
194m2Au | 475.8(6) keV | 420(10) ms | (11−) | ||||||
195Au | 79 | 116 | 194.9650346(14) | 186.098(47) d | EC | 195Pt | 3/2+ | ||
195mAu | 318.58(4) keV | 30.5(2) s | IT | 195Au | 11/2− | ||||
196Au | 79 | 117 | 195.966570(3) | 6.1669(6) d | β+ (93.05%) | 196Pt | 2− | ||
β− (6.95%) | 196Hg | ||||||||
196m1Au | 84.660(20) keV | 8.1(2) s | IT | 196Au | 5+ | ||||
196m2Au | 595.66(4) keV | 9.6(1) h | 12− | ||||||
197Au[n 3] | 79 | 118 | 196.9665687(6) | Observationally Stable[n 4] | 3/2+ | 1.0000 | |||
197mAu | 409.15(8) keV | 7.73(6) s | IT | 197Au | 11/2− | ||||
198Au | 79 | 119 | 197.9682423(6) | 2.69517(21) d | β− | 198Hg | 2− | ||
198m1Au | 312.2200(20) keV | 124(4) ns | 5+ | ||||||
198m2Au | 811.7(15) keV | 2.27(2) d | IT | 198Au | (12−) | ||||
199Au | 79 | 120 | 198.9687652(6) | 3.139(7) d | β− | 199Hg | 3/2+ | ||
199mAu | 548.9368(21) keV | 440(30) µs | (11/2)− | ||||||
200Au | 79 | 121 | 199.97073(5) | 48.4(3) min | β− | 200Hg | 1(−) | ||
200mAu | 970(70) keV | 18.7(5) h | β− (82%) | 200Hg | 12− | ||||
IT (18%) | 200Au | ||||||||
201Au | 79 | 122 | 200.971657(3) | 26(1) min | β− | 201Hg | 3/2+ | ||
202Au | 79 | 123 | 201.97381(18) | 28.8(19) s | β− | 202Hg | (1−) | ||
203Au | 79 | 124 | 202.975155(3) | 53(2) s | β− | 203Hg | 3/2+ | ||
204Au | 79 | 125 | 203.97772(22)# | 39.8(9) s | β− | 204Hg | (2−) | ||
205Au | 79 | 126 | 204.97987(32)# | 31(2) s | β− | 205Hg | 3/2+ |
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes, bold italics for nearly-stable isotopes (half-life longer than the age of the universe)
- ↑ Potential material for salted bombs
- ↑ Believed to undergo α decay to 193Ir
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ↑ Table of Standard Atomic Weights 2013 – CIAAW
- ↑ Sanchez, Francisco J.; Granovskiy, Mikhail (2012). "Application of radioactive particle tracking to indicate shed fouling in the stripper section of a fluid coker". Canadian Journal of Chemical Engineering. doi:10.1002/cjce.21740.
- ↑ "Nanoscience and Nanotechnology in Nanomedicine: Hybrid Nanoparticles In Imaging and Therapy of Prostate Cancer". Radiopharmaceutical Sciences Institute, University of Missouri-Columbia.
- ↑ Hainfeld, James F.; Dilmanian, F. Avraham; Slatkin, Daniel N.; Smilowitz, Henry M. (2008). "Radiotherapy enhancement with gold nanoparticles". Journal of Pharmacy and Pharmacology 60 (8): 977–85. doi:10.1211/jpp.60.8.0005. PMID 18644191.
- ↑ "Green Tea and Gold Nanoparticles Destroy Prostate Tumors". 2012.
- ↑ D. T. Win; M. Al Masum (2003). "Weapons of Mass Destruction" (PDF). Assumption University Journal of Technology 6 (4): 199–219.
- ↑ Rhodes, Richard (1995). Dark sun: The making of the hydrogen bomb. New York: Simon & Schuster. ISBN 0-684-80400-X.
- ↑ R. L. Miller (2002). U.S. Atlas of Nuclear Fallout, 1951–1970 1 (Abridged General Reader ed.). Two Sixty Press. p. 340. ISBN 1-881043-13-4.
- ↑ "Universal Nuclide Chart". nucleonica. (registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729 (1): 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729 (1): 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of platinum | Isotopes of gold | Isotopes of mercury |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
|