Isotopes of gallium
Natural gallium (Ga) consists of a mixture of two stable isotopes: gallium-69 and gallium-71. The most commercially important radioisotopes are gallium-67 and gallium-68.
Gallium-67 (half-life 3.3 days) is a gamma-emitting isotope (the gamma emitted immediately after electron-capture) used in standard nuclear medical imaging, in procedures usually referred to as gallium scans. It is usually used as the free ion, Ga3+. It is the longest-lived radioisotope of gallium.
The shorter-lived gallium-68 (half-life 68 minutes) is a positron-emitting isotope generated from germanium-68 in gallium-68 generators, for use in a small minority of diagnostic PET scans. For this use, it is usually attached as a tracer to a carrier molecule, which gives the resulting radiopharmaceutical a different tissue-uptake specificity from the ionic Ga-67 radioisotope normally used in standard gallium scans.
Relative atomic mass: 69.723(1)
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[1][n 1] |
daughter isotope(s)[n 2] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
56Ga | 31 | 25 | 55.99491(28)# | p | 55Zn | 3+# | |||
57Ga | 31 | 26 | 56.98293(28)# | p | 56Zn | 1/2−# | |||
58Ga | 31 | 27 | 57.97425(23)# | p | 57Zn | 2+# | |||
59Ga | 31 | 28 | 58.96337(18)# | p | 58Zn | 3/2−# | |||
60Ga | 31 | 29 | 59.95706(12)# | 70(10) ms | β+ | 60Zn | (2+) | ||
61Ga | 31 | 30 | 60.94945(6) | 168(3) ms | β+ | 61Zn | 3/2− | ||
62Ga | 31 | 31 | 61.944175(30) | 116.18(4) ms | β+ | 62Zn | 0+ | ||
63Ga | 31 | 32 | 62.9392942(14) | 32.4(5) s | β+ | 63Zn | (3/2−) | ||
64Ga | 31 | 33 | 63.9368387(22) | 2.627(12) min | β+ | 64Zn | 0(+#) | ||
64mGa | 42.85(8) keV | 21.9(7) µs | 2+ | ||||||
65Ga | 31 | 34 | 64.9327348(9) | 15.2(2) min | β+ | 65Zn | 3/2− | ||
66Ga | 31 | 35 | 65.931589(3) | 9.49(7) h | β+ | 66Zn | 0+ | ||
67Ga[n 3] | 31 | 36 | 66.9282017(14) | 3.2612(6) d | EC | 67Zn | 3/2− | ||
68Ga[n 4] | 31 | 37 | 67.9279801(16) | 67.71(9) min | β+ | 68Zn | 1+ | ||
69Ga | 31 | 38 | 68.9255736(13) | Stable | 3/2− | 0.60108(9) | |||
70Ga | 31 | 39 | 69.9260220(13) | 21.14(3) min | β− (99.59) | 70Ge | 1+ | ||
EC (0.41%) | 70Zn | ||||||||
71Ga | 31 | 40 | 70.9247013(11) | Stable | 3/2− | 0.39892(9) | |||
72Ga | 31 | 41 | 71.9263663(11) | 14.095(3) h | β− | 72Ge | 3- | ||
72mGa | 119.66(5) keV | 39.68(13) ms | IT | 72Ga | (0+) | ||||
73Ga | 31 | 42 | 72.9251747(18) | 4.86(3) h | β− | 73Ge | 3/2− | ||
74Ga | 31 | 43 | 73.926946(4) | 8.12(12) min | β− | 74Ge | (3-) | ||
74mGa | 59.571(14) keV | 9.5(10) s | (0) | ||||||
75Ga | 31 | 44 | 74.9265002(26) | 126(2) s | β− | 75Ge | (3/2)− | ||
76Ga | 31 | 45 | 75.9288276(21) | 32.6(6) s | β− | 76Ge | (2+,3+) | ||
77Ga | 31 | 46 | 76.9291543(26) | 13.2(2) s | β− | 77Ge | (3/2−) | ||
78Ga | 31 | 47 | 77.9316082(26) | 5.09(5) s | β− | 78Ge | (3+) | ||
79Ga | 31 | 48 | 78.93289(11) | 2.847(3) s | β− (99.911%) | 79mGe | (3/2−)# | ||
β−, n (.089%) | 78Ge | ||||||||
80Ga | 31 | 49 | 79.93652(13) | 1.697(11) s | β− (99.11%) | 80Ge | (3) | ||
β−, n (.89%) | 79Ge | ||||||||
81Ga | 31 | 50 | 80.93775(21) | 1.217(5) s | β− (88.11%) | 81mGe | (5/2−) | ||
β−, n (11.89%) | 80Ge | ||||||||
82Ga | 31 | 51 | 81.94299(32)# | 0.599(2) s | β− (78.5%) | 82Ge | (1,2,3) | ||
β−, n (21.5%) | 81Ge | ||||||||
83Ga | 31 | 52 | 82.94698(32)# | 308(1) ms | β− (60%) | 83Ge | 3/2−# | ||
β−, n (40%) | 82Ge | ||||||||
84Ga | 31 | 53 | 83.95265(43)# | 0.085(10) s | β−, n (70%) | 83Ge | |||
β− (30%) | 84Ge | ||||||||
85Ga | 31 | 54 | 84.95700(54)# | 50# ms [>300 ns] | 3/2−# | ||||
86Ga | 31 | 55 | 85.96312(86)# | 30# ms [>300 ns] |
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes, bold italics for nearly stable isotopes (half-life longer than the age of the universe)
- ↑ Deexcitation gamma used in medical imaging
- ↑ Medically useful radioisotope
Notes
- Commercially available materials may have been subjected to an undisclosed or inadvertent isotopic fractionation. Substantial deviations from the given mass and composition can occur.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
- Nuclide masses are given by IUPAP Commission on Symbols, Units, Nomenclature, Atomic Masses and Fundamental Constants (SUNAMCO).
- Isotope abundances are given by IUPAC Commission on Isotopic Abundances and Atomic Weights.
References
- ↑ "Universal Nuclide Chart". nucleonica. (registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of zinc | Isotopes of gallium | Isotopes of germanium |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
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