Copper(II) chloride

Copper(II) chloride

Anhydrous

Anhydrous

Dihydrate
Names
Other names
Cupric chloride
Identifiers
7447-39-4 YesY
10125-13-0 (dihydrate) N
ChEBI CHEBI:49553 YesY
ChEMBL ChEMBL1200553 N
ChemSpider 148374 YesY
Jmol interactive 3D Image
Image
PubChem 24014
RTECS number GL7000000
UNII P484053J2Y YesY
Properties
CuCl2
Molar mass 134.45 g/mol (anhydrous)
170.48 g/mol (dihydrate)
Appearance yellow-brown solid (anhydrous)
blue-green solid (dihydrate)
Odor odorless
Density 3.386 g/cm3 (anhydrous)
2.51 g/cm3 (dihydrate)
Melting point 498 °C (928 °F; 771 K) (anhydrous)
100 °C (dehydration of dihydrate)
Boiling point 993 °C (1,819 °F; 1,266 K) (anhydrous, decomposes)
70.6 g/100 mL (0 °C)
75.7 g/100 mL (25 °C)
107.9 g/100 mL (100 °C)
Solubility methanol:
68 g/100 mL (15 °C)


ethanol:
53 g/100 mL (15 °C)
soluble in acetone

Structure
distorted CdI2 structure
Octahedral
Hazards
Safety data sheet Fischer Scientific
Not listed
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g., chloroform Reactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g., calcium Special hazards (white): no codeNFPA 704 four-colored diamond
0
2
1
Flash point Non-flammable
US health exposure limits (NIOSH):
TWA 1 mg/m3 (as Cu)[1]
TWA 1 mg/m3 (as Cu)[1]
TWA 100 mg/m3 (as Cu)[1]
Related compounds
Other anions
 Copper(II) fluoride
Copper(II) bromide
Other cations
 Copper(I) chloride
Silver chloride
Gold(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Copper(II) chloride is the chemical compound with the chemical formula CuCl2. This is a light brown solid, which slowly absorbs moisture to form a blue-green dihydrate. The copper(II) chlorides are some of the most common copper(II) compounds, after copper sulfate.

Structure

Anhydrous CuCl2 adopts a distorted cadmium iodide structure. In this motif, the copper centers are octahedral. Most copper(II) compounds exhibit distortions from idealized octahedral geometry due to the Jahn-Teller effect, which in this case describes the localization of one d-electron into a molecular orbital that is strongly antibonding with respect to a pair of chloride ligands. In CuCl2·2H2O, the copper again adopts a highly distorted octahedral geometry, the Cu(II) centers being surrounded by two water ligands and four chloride ligands, which bridge asymmetrically to other Cu centers.[2]

Copper(II) chloride is paramagnetic. Of historical interest, CuCl2·2H2O was used in the first electron paramagnetic resonance measurements by Yevgeny Zavoisky in 1944.[3][4]

Properties and reactions

Aqueous solutions of "copper(II) chloride". Greenish when high in [Cl−], more blue when lower in [Cl−].

Aqueous solution prepared from copper(II) chloride contain a range of copper(II) complexes depending on concentration, temperature, and the presence of additional chloride ions. These species include blue color of [Cu(H2O)6]2+ and yellow or red color of the halide complexes of the formula [CuCl2+x]x−.[5]

Hydrolysis

Copper(II) hydroxide precipitates upon treating copper(II) chloride solutions with base:

CuCl2 + 2 NaOH → Cu(OH)2 + 2 NaCl
Copper(II) chloride dihydrate crystal

Partial hydrolysis gives copper oxychloride, Cu2Cl(OH)3, a popular fungicide.

Redox

CuCl2 is a mild oxidant. It decomposes to CuCl and Cl2 at 1000 °C:

2 CuCl2 → 2 CuCl + Cl2

CuCl2 reacts with several metals to produce copper metal or copper(I) chloride with oxidation of the other metal. To convert copper(II) chloride to copper(I) derivatives, it can be convenient to reduce an aqueous solution with sulfur dioxide as the reductant:

2 CuCl2 + SO2 + 2 H2O → 2 CuCl + 2 HCl + H2SO4

Coordination complexes

CuCl2 reacts with HCl or other chloride sources to form complex ions: the red CuCl3− (it is a dimer in reality, Cu2Cl62−, a couple of tetrahedrons that share an edge), and the green or yellow CuCl42−.[6]

CuCl
2 + Cl−
 is in equilibrium with CuCl−
3
CuCl
2 + 2 Cl−
 is in equilibrium with CuCl2−
4

Some of these complexes can be crystallized from aqueous solution, and they adopt a wide variety of structures.

Copper(II) chloride also forms a variety of coordination complexes with ligands such as pyridine and triphenylphosphine oxide:

CuCl2 + 2 C5H5N → [CuCl2(C5H5N)2] (tetragonal)
CuCl2 + 2 (C6H5)3P=O → [CuCl2((C6H5)3P=O)2] (tetrahedral)

However "soft" ligands such as phosphines (e.g., triphenylphosphine), iodide, and cyanide as well as some tertiary amines induce reduction to give copper(I) complexes.

Preparation

Copper(II) chloride is prepared commercially by the action of chlorination of copper:

Cu + Cl2 + 2 H2O → CuCl2(H2O)2

Copper metal itself cannot be oxidised by hydrochloric acid, but copper-containing bases such as the hydroxide, oxide, or copper(II) carbonate can be reacted with hydrochloric acid.

Once prepared, a solution of CuCl2 may be purified by crystallization. A standard method takes the solution mixed in hot dilute hydrochloric acid, and causes the crystals to form by cooling in a CaCl2-ice bath.[7][8]

There are indirect and rarely used means of using copper ions in solution to form copper(II) chloride. Electrolysis of aqueous sodium chloride with copper electrodes produces (among other things) a blue-green foam that can be collected and converted to the hydrate. While this is not usually done due to the emission of toxic chlorine gas, and the prevalence of the more general chloralkali process, the electrolysis will convert the copper metal to copper ions in solution forming the compound. Indeed any solution of copper ions can be mixed with hydrochloric acid and made into copper chloride by removing any other ions.

Natural occurrence

Copper(II) chloride occurs naturally as the very rare mineral tolbachite and the dihydrate eriochalcite. Both are found near fumaroles. More common are mixed oxyhydroxide-chlorides like atacamite Cu2(OH)3Cl, arising among Cu ore beds oxidation zones in arid climate (also known from some altered slags).

Uses

Cu-catalyst in Wacker process

A major industrial application for copper(II) chloride is as a co-catalyst with palladium(II) chloride in the Wacker process. In this process, ethene (ethylene) is converted to ethanal (acetaldehyde) using water and air. During the reaction, PdCl2 is reduced to Pd, and the CuCl2 serves to re-oxidize this back to PdCl2. Air can then oxidize the resultant CuCl back to CuCl2, completing the cycle.

  1. C2H4 + PdCl2 + H2O → CH3CHO + Pd + 2 HCl
  2. Pd + 2 CuCl2 → 2 CuCl + PdCl2
  3. 4 CuCl + 4 HCl + O2 → 4 CuCl2 + 2 H2O

The overall process is:

2 C2H4 + O2 → 2 CH3CHO

Catalyst in production of chlorine

Copper(II) chloride is used as a catalyst in a variety of processes that produce chlorine by oxychlorination. The Deacon process takes place at about 400 to 450 °C in the presence of a copper chloride:

4 HCl + O2 → 2 Cl2 + 2 H2O

Copper(II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloroethane.[9]

Copper(II) chloride is used in the Copper–chlorine cycle in which it splits steam into a copper oxygen compound and hydrogen chloride, and is later recovered in the cycle from the electrolysis of copper(I) chloride.

Other organic synthetic applications

Copper(II) chloride has some highly specialized applications in the synthesis of organic compounds.[7] It effects chlorination of aromatic hydrocarbons- this is often performed in the presence of aluminium oxide. It is able to chlorinate the alpha position of carbonyl compounds:[10]

This reaction is performed in a polar solvent such as dimethylformamide (DMF), often in the presence of lithium chloride, which accelerates the reaction.

CuCl2, in the presence of oxygen, can also oxidize phenols. The major product can be directed to give either a quinone or a coupled product from oxidative dimerization. The latter process provides a high-yield route to 1,1-binaphthol:[11]

Such compounds are intermediates in the synthesis of BINAP and its derivatives

Copper(II) chloride dihydrate promotes the hydrolysis of acetonides, i.e., for deprotection to regenerate diols[12] or aminoalcohols, as in this example (where TBDPS = tert-butyldiphenylsilyl):[13]

CuCl2 also catalyses the free radical addition of sulfonyl chlorides to alkenes; the alpha-chlorosulfone may then undergo elimination with base to give a vinyl sulfone product.

Niche uses

Copper(II) chloride is also used in pyrotechnics as a blue/green coloring agent. In a flame test, copper chlorides, like all copper compounds, emit green-blue.

In humidity indicator cards (HICs), cobalt-free brown to azure (copper(II) chloride base) HICs can be found on the market. In 1998, the European Community (EC) classified items containing cobalt(II) chloride of 0.01 to 1% w/w as T (Toxic), with the corresponding R phrase of R49 (may cause cancer if inhaled). As a consequence, new cobalt-free humidity indicator cards have been developed that contain copper.

Safety

Copper(II) chloride can be toxic. Only concentrations below 5 ppm are allowed in drinking water by the US Environmental Protection Agency.

References

  1. 1 2 3 "NIOSH Pocket Guide to Chemical Hazards #0150". National Institute for Occupational Safety and Health (NIOSH).
  2. ↑ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.
  3. ↑ Peter Baláž (2008). Mechanochemistry in Nanoscience and Minerals Engineering. Springer. p. 167. ISBN 3-540-74854-7.
  4. ↑ Marina Brustolon (2009). Electron paramagnetic resonance: a practitioner's toolkit. John Wiley and Sons. p. 3. ISBN 0-470-25882-9.
  5. ↑ Greenwood, N. N. and Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.
  6. ↑ Naida S. Gill; et al. (1967). "Inorganic Syntheses". Inorg. Synth. Inorganic Syntheses 9: 136–142. doi:10.1002/9780470132401.ch37. ISBN 978-0-470-13240-1. |chapter= ignored (help)
  7. 1 2 S. H. Bertz, E. H. Fairchild, in Handbook of Reagents for Organic Synthesis, Volume 1: Reagents, Auxiliaries and Catalysts for C-C Bond Formation, (R. M. Coates, S. E. Denmark, eds.), pp. 220-3, Wiley, New York, 1999.
  8. ↑ W. L. F. Armarego, Christina Li Lin Chai (2009-05-22). Purification of Laboratory Chemicals (Google Books excerpt) (6th ed.). Butterworth-Heinemann. p. 461. ISBN 1-85617-567-7.
  9. ↑ H.Wayne Richardson, "Copper Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim, doi:10.1002/14356007.a07_567
  10. ↑ C. E. Castro, E. J. Gaughan, D. C. Owsley (1965). "Cupric Halide Halogenations". Journal of Organic Chemistry 30 (2): 587. doi:10.1021/jo01013a069.
  11. ↑ J. Brussee, J. L. G. Groenendijk, J. M. Koppele, A. C. A. Jansen (1985). "On the mechanism of the formation of s(−)-(1, 1'-binaphthalene)-2,2'-diol via copper(II)amine complexes". Tetrahedron 41 (16): 3313. doi:10.1016/S0040-4020(01)96682-7.
  12. ↑ Chandrasekhar, M.; Kusum L. Chandra; Vinod K. Singh (2003). "Total Synthesis of (+)-Boronolide, (+)-Deacetylboronolide, and (+)-Dideacetylboronolide". Journal of Organic Chemistry 68 (10): 4039–4045. doi:10.1021/jo0269058. PMID 12737588.
  13. ↑ Krishna, Palakodety Radha; G. Dayaker (2007). "A stereoselective total synthesis of (−)-andrachcinidine via an olefin cross-metathesis protocol". Tetrahedron Letters (Elsevier) 48 (41): 7279–7282. doi:10.1016/j.tetlet.2007.08.053.

Further reading

  1. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9. 
  2. Lide, David R. (1990). CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data. Boca Raton: CRC Press. ISBN 0-8493-0471-7. 
  3. The Merck Index, 7th edition, Merck & Co, Rahway, New Jersey, USA, 1960.
  4. D. Nicholls, Complexes and First-Row Transition Elements, Macmillan Press, London, 1973.
  5. A. F. Wells, 'Structural Inorganic Chemistry, 5th ed., Oxford University Press, Oxford, UK, 1984.
  6. J. March, Advanced Organic Chemistry, 4th ed., p. 723, Wiley, New York, 1992.
  7. Fieser & Fieser Reagents for Organic Synthesis Volume 5, p158, Wiley, New York, 1975.
  8. D. W. Smith (1976). "Chlorocuprates(II)". Coordination Chemistry Reviews 21 (2–3): 93–158. doi:10.1016/S0010-8545(00)80445-2. 

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