Calcium silicate

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Calcium silicate
Names
Preferred IUPAC name
Calcium silicate
Systematic IUPAC name
Dicalcium silicate
Other names
Belite

Calcium monosilicate
Calcium hydrosilicate
Calcium metasilicate, Calcium orthosilicate
Grammite
Micro-cell
Silene

Silicic acid calcium salt
Identifiers
1344-95-2 YesY
111811-33-7 hydrate YesY
12168-85-3 calcium oxide YesY
ChemSpider 14235 N
23811 calcium oxide YesY
EC Number 235-336-9
Jmol interactive 3D Image
KEGG D03309 N
MeSH Calcium+silicate
PubChem 14941
44154858 hydrate
25523 calcium oxide
UNII S4255P4G5M YesY
Properties
Ca2O4Si
Molar mass 172.24 g·mol−1
Appearance White crystals
Density 0.29 g/cm3 (solid)[1]
Melting point 1,540 °C (2,800 °F; 1,810 K)
0.01% (20 °C)[1]
Thermochemistry
84 J·mol−1·K−1[2]
−1630 kJ·mol−1[2]
Pharmacology
ATC code A02AC02
Hazards
Main hazards Irritant
Safety data sheet [3]
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g., chloroform Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
0
2
0
Flash point Not applicable
US health exposure limits (NIOSH):
TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)[1]
TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)[1]
N.D.[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references
Calcium silicate passive fire protection board being clad around steel structure in order to achieve a fire-resistance rating.

Calcium silicate (often referred to by its shortened trade name Cal-Sil or Calsil) is the chemical compound Ca2SiO4, also known as calcium orthosilicate and sometimes formulated 2CaO.SiO2. It is one of a group of compounds obtained by reacting calcium oxide and silica in various ratios[4] e.g. 3CaO•SiO2, Ca3SiO5; 2CaO•SiO2, Ca2SiO4; 3CaO•2SiO2, Ca3Si2O7 and CaO•SiO2, CaSiO3. Calcium silicate is a white free-flowing powder derived from limestone and diatomaceous earth. It has a low bulk density and high physical water absorption. It is used in roads, insulation, bricks, roof tiles, table salt[5] and occurs in cements, where it is known as belite (or in cement chemist notation C2S).

It is used as an anti-caking agent in food preparation and an antacid. It is approved by the United Nations' FAO and WHO bodies as a safe food additive in a large variety of products.[6]

High temperature insulation

Calcium silicate is commonly used as a safe alternative to asbestos for high temperature insulation materials. Industrial grade piping and equipment insulation is often fabricated from calcium silicate. Its fabrication is a routine part of the curriculum for insulation apprentices. Calcium silicate competes in these realms against rockwool as well as proprietary insulation solids, such as perlite mixture and vermiculite bonded with sodium silicate. Although it is popularly considered an asbestos substitute, early uses of calcium silicate for insulation still made use of asbestos fibers.

Passive fire protection

Circuit integrity fireproofing of cable trays in Lingen/Ems, Germany using calcium silicate board system qualified to DIN 4102. Other methods for exterior protection of electrical circuits include boards made of sodium silicate bonded and pressed vermiculite and flexible wraps made of ceramic fibre and rockwool.

One of the most successful materials in fireproofing in Europe is calcium silicate. Where North Americans use spray fireproofing plasters, Europeans are more likely to use cladding made of calcium silicate. High performance calcium silicate boards retain their excellent dimensional stability even in damp and humid conditions and can be installed at an early stage in the construction program, before wet trades are completed and the building is weather-tight. For sub-standard products, silicone treated sheets are available to fabricators to mitigate potential harm from high humidity or general presence of water. Fabricators and installers of calcium silicate in passive fire protection often also install firestops.

While the best possible Reaction to Fire Classifications are A1 (construction applications) and A1Fl (flooring applications) respectively, both of which mean "non-combustible" according to EN 13501-1: 2007, as classified by a notified laboratory in Europe, some calcium silicate boards only come with Fire Classification of A2 (limited combustibility) or even lower classifications (or no classification), if they are tested at all.

Acid mine drainage remediation

Calcium silicate, also known as slag, is produced when molten iron is made from iron ore, silicon dioxide and calcium carbonate in a blast furnace. When this material is processed into a highly refined, re-purposed calcium silicate aggregate, it is used in the remediation of acid mine drainage (AMD) on active and passive mine sites.[7] Calcium silicate neutralizes active acidity in AMD systems by removing free hydrogen ions from the bulk solution, thereby increasing pH. As its silicate anion captures H+ ions (raising the pH), it forms monosilicic acid (H4SiO4), a neutral solute. Monosilicic acid remains in the bulk solution to play other important roles in correcting the adverse effects of acidic conditions. As opposed to limestone (a popular remediation material),[8] calcium silicate effectively precipitates heavy metals and does not armor over, prolonging its effectiveness in AMD systems.[7][9]

As a product of sealants

When sodium silicate is applied as a sealant to cured concrete or the shells of fresh eggs, it chemically reacts with calcium hydroxide or carbonate to form calcium silicate hydrate, sealing pores with a relatively impermeable material.

See also

References

  1. 1 2 3 4 5 "NIOSH Pocket Guide to Chemical Hazards #0094". National Institute for Occupational Safety and Health (NIOSH).
  2. 1 2 Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A21. ISBN 0-618-94690-X.
  3. ↑ http://www.bnzmaterials.com/msds/msds218.html
  4. ↑ H F W Taylor, Cement Chemistry, Academic Press, 1990, ISBN 0-12-683900-X, p 33-34
  5. ↑ http://www.mortonsalt.com/faqs/food_salt_faq.html#q6
  6. ↑ "Food Additive Details: Calcium silicate". Retrieved July 28, 2013. Codex General Standard for Food Additives (GSFA) Online Database, FAO/WHO Food Standards Codex alimentarius, published by the Food and Agricultural Organization of the United Nations / World Health Organization, 2013.
  7. 1 2 Ziemkiewicz, Paul. "The Use of Steel Slag in Acid Mine Drainage Treatment and Control". Retrieved 25 April 2011.
  8. ↑ Skousen, Jeff. "Chemicals". Overview of Acid Mine Drainage Treatment with Chemicals. West Virginia University Extension Service. Retrieved 29 March 2011.
  9. ↑ Hammarstrom, Jane M.; Philip L. Sibrell; Harvey E. Belkin. "Characterization of limestone reacted with acid-mine drainage" (PDF). Applied Geochemistry (18): 1710–1714. Retrieved 30 March 2011.
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