Diphosphene

Diphosphene
Identifiers
41916-72-7 YesY
ChemSpider 125761 YesY
Jmol interactive 3D Image
PubChem 142559
Properties
P
2
H
2
Molar mass 63.96340 g·mol−1
Related compounds
Other anions
diazene
Other cations
diphosphenes
Related Binary azenes
triazene
tetrazene
Related compounds
ammonia
diazane
triazane
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Infobox references

Diphosphene is a compound having the formula (PH)2. It exists as two geometric isomers, E and Z.[1] Diphosphene is also the parent member of the entire class of diphosphene compounds with the formula (PR)2, where R is an organyl group.[2]

References

  1. Lu, T.; Simmonett, A. C.; Evangelista, F. A.; Yamaguchi, Y.; Schaefer, H. F. (2009). "Diphosphene and Diphosphinylidene". The Journal of Physical Chemistry A 113 (47): 13227–13236. doi:10.1021/jp904028a.
  2. Yoshifuji, M.; Shibayama, K.; Inamoto, N.; Hirotsu, K.; Higuchi, T. (1983). "Reaction of the diphosphene ArP=PAr (Ar = 2,4,6-But3C6H2) with sulphur: isolation and X-ray structure of the diphosphene monosulphide". Journal of the Chemical Society, Chemical Communications 1983 (16): 862–863. doi:10.1039/C39830000862.
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