Di-tert-butylzinc

Di-*tert*-butylzinc
Names


IUPAC name Bis(dimethylethyl)zinc
Other names Di-tert-butylzinc
Identifiers
CAS Number	16636-96-7^Y
ChemSpider	10750751^N
Jmol interactive 3D	Image
InChI InChI=1S/2C4H9.Zn/c21-4(2)3;/h21-3H3;^N Key: KYHHMFUFEIHUHB-UHFFFAOYSA-N^N InChI=1/2C4H9.Zn/c21-4(2)3;/h21-3H3;/rC8H18Zn/c1-7(2,3)9-8(4,5)6/h1-6H3 Key: KYHHMFUFEIHUHB-UUODNYSZAB
SMILES CC(C)(C)[Zn]C(C)(C)C
Properties
Chemical formula	C₈H₁₈Zn
Molar mass	179.61 g·mol⁻¹
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is ^YN ?)
Infobox references

Di-tert-butylzinc is a compound with the formula ZnC₈H₁₈. This compound is used as a meta activating reagent in the syntheses of N,N-dimethyl-3-iodoaniline from N,N-dimethylaniline.^[1]

References

↑ Armstrong, David R.; Clegg, William; Dale, Sophie H.; Hevia, Eva; Hogg, Lorna M.; Honeyman, Gordon W.; Mulvey, Robert E. (2006). "Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation". Angewandte Chemie International Edition 45 (23): 3775. doi:10.1002/anie.200600720.

Zinc compounds

Zinc(I)

Organozinc(I) compounds	Zn₂(C₅(CH₃)₅)₂

Zinc(II)

Organozinc(II) compounds	Zn(CH₃)₂ Zn(C₂H₅)₂ Zn(CH(CH₃)₂)₂ Zn(C(CH₃)₃)₂ Zn(C₆H₅)₂ ZnCIH₂I

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