Chemical warfare

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Chemical warfare (CW) involves using the toxic properties of chemical substances as weapons. This type of warfare is distinct from nuclear warfare and biological warfare, which together make up NBC, the military acronym for nuclear, biological, and chemical (warfare or weapons), all of which are considered "weapons of mass destruction" (WMDs). None of these fall under the term conventional weapons which are primarily effective due to their destructive potential. With proper protective equipment, training, and decontamination measures, the primary effects of chemical weapons can be overcome. Many nations possess vast stockpiles of weaponized agents in preparation for wartime use. The threat and the perceived threat have become strategic tools in planning both measures and counter-measures.

Definition

Chemical warfare is different from the use of conventional weapons or nuclear weapons because the destructive effects of chemical weapons are not primarily due to any explosive force. The offensive use of living organisms (such as anthrax) is considered biological warfare rather than chemical warfare; however, the use of nonliving toxic products produced by living organisms (e.g. toxins such as botulinum toxin, ricin, and saxitoxin) is considered chemical warfare under the provisions of the Chemical Weapons Convention (CWC). Under this Convention, any toxic chemical, regardless of its origin, is considered a chemical weapon unless it is used for purposes that are not prohibited (an important legal definition known as the General Purpose Criterion).^[1]

About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th century. The entire class known as Lethal Unitary Chemical Agents and Munitions have been scheduled for elimination by the CWC.^[2]

Under the Convention, chemicals that are toxic enough to be used as chemical weapons, or that may be used to manufacture such chemicals, are divided into three groups according to their purpose and treatment:

• Schedule 1 – Have few, if any, legitimate uses. These may only be produced or used for research, medical, pharmaceutical or protective purposes (i.e. testing of chemical weapons sensors and protective clothing). Examples include nerve agents, ricin, lewisite and mustard gas. Any production over 100 g must be reported to the OPCW and a country can have a stockpile of no more than one tonne of these chemicals.
• Schedule 2 – Have no large-scale industrial uses, but may have legitimate small-scale uses. Examples include dimethyl methylphosphonate, a precursor to sarin also used as a flame retardant, and thiodiglycol, a precursor chemical used in the manufacture of mustard gas but also widely used as a solvent in inks.
• Schedule 3 – Have legitimate large-scale industrial uses. Examples include phosgene and chloropicrin. Both have been used as chemical weapons but phosgene is an important precursor in the manufacture of plastics and chloropicrin is used as a fumigant. The OPCW must be notified of, and may inspect, any plant producing more than 30 tonnes per year.

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Ancient times

Chemical weapons have been used for millennia in the form of poisoned spears and arrows, but evidence can be found for the existence of more advanced forms of chemical weapons in ancient and classical times.

Ancient Greek myths about Hercules poisoning his arrows with the venom of the Hydra monster are the earliest references to toxic weapons in western literature. Homer's epics, the Iliad and the Odyssey, allude to poisoned arrows used by both sides in the legendary Trojan War (Bronze Age Greece).^[3]

Some of the earliest surviving references to toxic warfare appear in the Indian epics Ramayana and Mahabharata.^[4] The "Laws of Manu," a Hindu treatise on statecraft (c. 400 BC) forbids the use of poison and fire arrows, but advises poisoning food and water. Kautilya's "Arthashastra", a statecraft manual of the same era, contains hundreds of recipes for creating poison weapons, toxic smokes, and other chemical weapons. Ancient Greek historians recount that Alexander the Great encountered poison arrows and fire incendiaries in India at the Indus basin in the 4th century BC.^[3]

Arsenical smokes were known to the Chinese as far back as c. 1000 BC^[5] and Sun Tzu's "Art of War" (c. 200 BC) advises the use of fire weapons. In the second century BC, writings of the Mohist sect in China describe the use of bellows to pump smoke from burning balls of mustard and other toxic vegetables into tunnels being dug by a besieging army. Other Chinese writings dating around the same period contain hundreds of recipes for the production of poisonous or irritating smokes for use in war along with numerous accounts of their use. These accounts describe an arsenic-containing "soul-hunting fog", and the use of finely divided lime dispersed into the air to suppress a peasant revolt in 178 AD.

The earliest recorded use of gas warfare in the West dates back to the fifth century BC, during the Peloponnesian War between Athens and Sparta. Spartan forces besieging an Athenian city placed a lighted mixture of wood, pitch, and sulfur under the walls hoping that the noxious smoke would incapacitate the Athenians, so that they would not be able to resist the assault that followed. Sparta was not alone in its use of unconventional tactics in ancient Greece; Solon of Athens is said to have used hellebore roots to poison the water in an aqueduct leading from the River Pleistos around 590 BC during the siege of Kirrha.^[3]

There is archaeological evidence that the Sasanians deployed chemical weapons against the Roman army in the third century AD. Research carried out on the collapsed tunnels at Dura-Europos in Syria suggests that the Iranians used bitumen and sulfur crystals to get it burning. When ignited, the materials gave off dense clouds of choking gases which killed 20 Roman soldiers in a matter of two minutes.^[6]

In the late 15th century, Spanish conquistadors encountered a rudimentary type of chemical warfare on the island of Hispaniola. The Taíno threw gourds filled with ashes and ground hot peppers at the Spaniards to create a blinding smoke screen before launching their attack.^[7]

Early modern era

Historian and philosopher David Hume, in his history of England, recounts how in the reign of Henry III (r.1216 - 1272) the English Navy destroyed an invading French fleet, by blinding the enemy fleet with "quicklime," the old name for calcium oxide. D’Albiney employed a stratagem against them, which is said to have contributed to the victory: Having gained the wind of the French, he came down upon them with violence; and throwing in their faces a great quantity of quicklime, which he purposely carried on board, he so blinded them, that they were disabled from defending themselves.^[8]

Leonardo da Vinci proposed the use of a powder of sulfide, arsenic and verdigris in the 15th century:

throw poison in the form of powder upon galleys. Chalk, fine sulfide of arsenic, and powdered verdegris may be thrown among enemy ships by means of small mangonels, and all those who, as they breathe, inhale the powder into their lungs will become asphyxiated.

It is unknown whether this powder was ever actually used.

In the 17th century during sieges, armies attempted to start fires by launching incendiary shells filled with sulfur, tallow, rosin, turpentine, saltpeter, and/or antimony. Even when fires were not started, the resulting smoke and fumes provided a considerable distraction. Although their primary function was never abandoned, a variety of fills for shells were developed to maximize the effects of the smoke.

In 1672, during his siege of the city of Groningen, Christoph Bernhard von Galen, the Bishop of Münster, employed several different explosive and incendiary devices, some of which had a fill that included Deadly Nightshade, intended to produce toxic fumes. Just three years later, August 27, 1675, the French and the Holy Roman Empire concluded the Strasbourg Agreement, which included an article banning the use of "perfidious and odious" toxic devices.

Industrial era

The modern notion of chemical warfare emerged from the mid-19th century, with the development of modern chemistry and associated industries. The first proposal for the use of chemical warfare was made by Lyon Playfair, Secretary of the Science and Art Department, in 1854 during the Crimean War. He proposed a cacodyl cyanide artillery shell for use against enemy ships as way to solve the stalemate during the siege of Sevastopol. The proposal was backed by Admiral Thomas Cochrane of the Royal Navy. It was considered by the Prime Minister, Lord Palmerston, but the British Ordnance Department rejected the proposal as "as bad a mode of warfare as poisoning the wells of the enemy." Playfair’s response was used to justify chemical warfare into the next century: ^[9]

There was no sense in this objection. It is considered a legitimate mode of warfare to fill shells with molten metal which scatters among the enemy, and produced the most frightful modes of death. Why a poisonous vapor which would kill men without suffering is to be considered illegitimate warfare is incomprehensible. War is destruction, and the more destructive it can be made with the least suffering the sooner will be ended that barbarous method of protecting national rights. No doubt in time chemistry will be used to lessen the suffering of combatants, and even of criminals condemned to death.

Later, during the American Civil War, New York school teacher John Doughty proposed the offensive use of chlorine gas, delivered by filling a 10-inch (254 millimeter) artillery shell with two to three quarts (two to three liters) of liquid chlorine, which could produce many cubic feet (a few cubic meters) of chlorine gas. Doughty’s plan was apparently never acted on, as it was probably^[10] presented to Brigadier General James Wolfe Ripley, Chief of Ordnance, who was described as being congenitally immune to new ideas.

A general concern over the use of poison gas manifested itself in 1899 at the Hague Conference with a proposal prohibiting shells filled with asphyxiating gas. The proposal was passed, despite a single dissenting vote from the United States. The American representative, Navy Captain Alfred Thayer Mahan, justified voting against the measure on the grounds that "the inventiveness of Americans should not be restricted in the development of new weapons."

World War I

The Hague Declaration of 1899 and the Hague Convention of 1907 forbade the use of "poison or poisoned weapons" in warfare, yet more than 124,000 tons of gas were produced by the end of World War I. The French were the first to use chemical weapons during the First World War, using the tear gases ethyl bromoacetate and chloroacetone.

One of Germany's earliest uses of chemical weapons occurred on October 27, 1914 when shells containing the irritant dianisidine chlorosulfonate were fired at British troops near Neuve-Chapelle, France.^[5] Germany used another irritant, xylyl bromide, in artillery shells that were fired in January 1915 at the Russians near Bolimów, in present-day Poland.^[11] The first full-scale deployment of deadly chemical warfare agents during World War I was at the Second Battle of Ypres, on April 22, 1915, when the Germans attacked French, Canadian and Algerian troops with chlorine gas. Deaths were light, though casualties relatively heavy.

A total 50,965 tons of pulmonary, lachrymatory, and vesicant agents were deployed by both sides of the conflict, including chlorine, phosgene, and mustard gas. Official figures declare about 1.3 million casualties directly caused by chemical warfare agents during the course of the war. Of these, an estimated 100,000-260,000 casualties were civilians. Nearby civilian towns were at risk from winds blowing the poison gases through. Civilians rarely had a warning system put into place to alert their neighbors of the danger. In addition to poor warning systems, civilians often did not have access to effective gas masks.^[12][13]

To this day, unexploded World War I-era chemical ammunition is still uncovered when the ground is dug in former battle or depot areas and continues to pose a threat to the civilian population in Belgium and France and less commonly in other countries.

After the war, most of the unused German chemical warfare agents were dumped into the Baltic Sea, a common disposal method among all the participants in several bodies of water. Over time, the salt water causes the shell casings to corrode, and mustard gas occasionally leaks from these containers and washes onto shore as a wax-like solid resembling ambergris.

Interwar years

In 1919, the Royal Air Force dropped arsenic gas on Bolshevik troops during the British intervention in the Russian Civil War.^[14]

After World War I chemical agents were occasionally used to subdue populations and suppress rebellion.

In 1920, the Arab and Kurdish people of Mesopotamia revolted against the British occupation, which cost the British dearly. As the Mesopotamian resistance gained strength, the British resorted to increasingly repressive measures. Much speculation was made about aerial bombardment of major cities with gas in Mesopotamia, with Winston Churchill, then-Secretary of State at the British War Office, arguing in favor of gas.^[15][16]

The Bolsheviks also employed poison gas in 1921 during the Tambov Rebellion. An order signed by military commanders Tukhachevsky and Vladimir Antonov-Ovseyenko stipulated: "The forests where the bandits are hiding are to be cleared by the use of poison gas. This must be carefully calculated, so that the layer of gas penetrates the forests and kills everyone hiding there."^[17]

During the Rif War in Spanish Morocco in 1921–1927, combined Spanish and French forces dropped mustard gas bombs in an attempt to put down the Berber rebellion. (See also: Chemical weapons in the Rif War)

In 1925, 16 of the world's major nations signed the Geneva Protocol, thereby pledging never to use gas in warfare again. Notably, while the United States delegation under Presidential authority signed the Protocol, it languished in the U.S. Senate until 1975, when it was finally ratified.

Beginning in the final week of 1935 and continuing into 1936, Fascist Italy used mustard gas during its invasion of Ethiopia in the Second Italo-Abyssinian War. Ignoring the Geneva Protocol, which it signed seven years earlier, the Italian military dropped mustard gas in bombs, sprayed it from airplanes, and spread it in powdered form on the ground. The Italians inflicted a reported 150,000 chemical casualties on the Ethiopians, mostly from mustard gas.

Nerve agents

Shortly after the end of World War I, Germany's General Staff enthusiastically pursued a recapture of their preeminent position in chemical warfare. In 1923, Hans von Seeckt pointed the way, by suggesting that German poison gas research move in the direction of delivery by aircraft in support of mobile warfare. Also in 1923, at the behest of the German army, poison gas expert Dr. Hugo Stoltzenberg negotiated with the USSR to build a huge chemical weapons plant at Trotsk, on the Volga river.

Collaboration between Germany and the USSR in poison gas continued on and off through the 1920s. In 1924, German officers debated the use of poison gas versus non-lethal chemical weapons against civilians.

Chemical warfare was revolutionized by Nazi Germany's discovery of the nerve agents tabun (in 1937) and sarin (in 1939) by Gerhard Schrader, a chemist of IG Farben.

IG Farben was Germany's premier poison gas manufacturer during World War II, so the weaponization of these agents cannot be considered accidental.^[18] Both were turned over to the German Army Weapons Office prior to the outbreak of the war.

The nerve agent soman was later discovered by Nobel Prize laureate Richard Kuhn and his collaborator Konrad Henkel at the Kaiser Wilhelm Institute for Medical Research in Heidelberg in spring 1944.^[19][20] The Germans developed and manufactured large quantities of several agents, but chemical warfare was not extensively used by either side. Chemical troops were set up (in Germany since 1934) and delivery technology was actively developed.

World War II

Imperial Japanese Army

Despite the 1899 Hague Declaration IV, 2 - Declaration on the Use of Projectiles the Object of Which is the Diffusion of Asphyxiating or Deleterious Gases,^[22] Article 23 (a) of the 1907 Hague Convention IV - The Laws and Customs of War on Land,^[23] and a resolution adopted against Japan by the League of Nations on May 14, 1938, the Imperial Japanese Army frequently used chemical weapons. Because of fear of retaliation, however, those weapons were never used against Westerners, but against other Asians judged "inferior" by imperial propaganda. According to historians Yoshiaki Yoshimi and Kentaro Awaya, gas weapons, such as tear gas, were used only sporadically in 1937 but in early 1938, the Imperial Japanese Army began full-scale use of sneeze and nausea gas (red), and from mid-1939, used mustard gas (yellow) against both Kuomintang and Communist Chinese troops.^[24]

According to historians Yoshiaki Yoshimi and Seiya Matsuno, the chemical weapons were authorized by specific orders given by Emperor Hirohito himself, transmitted by the chief of staff of the army. For example, the Emperor authorized the use of toxic gas on 375 separate occasions during the Battle of Wuhan from August to October 1938.^[25] They were also profusely used during the invasion of Changde. Those orders were transmitted either by prince Kotohito Kan'in or general Hajime Sugiyama.^[26] The Imperial Japanese Army had used mustard gas and the US-developed (CWS-1918) blister agent lewisite against Chinese troops and guerrillas. Experiments involving chemical weapons were conducted on live prisoners (Unit 731 and Unit 516).

The Japanese also carried chemical weapons as they swept through Southeast Asia towards Australia. Some of these items were captured and analyzed by the Allies. Historian Geoff Plunkett has recorded how Australia covertly imported 1,000,000 chemical weapons from the United Kingdom from 1942 onwards and stored them in many storage depots around the country, including three tunnels in the Blue Mountains to the west of Sydney. They were to be used as a retaliatory measure if the Japanese first used chemical weapons.^[27] Buried chemical weapons have been recovered at Marrangaroo and Columboola.^[27][28]

Nazi Germany

Recovered documents suggest that German intelligence incorrectly thought that the Allies also knew of the nerve agent compounds, interpreting their lack of mention in the Allies' scientific journals as evidence that information about them was being suppressed. Germany ultimately decided not to use the new nerve agents, fearing a potentially devastating Allied retaliatory nerve agent deployment.^[29]

Stanley P. Lovell, Deputy Director for Research and Development of the Office of Strategic Services, reports in his book Of Spies and Stratagems that the Allies knew the Germans had quantities of Gas Blau available for use in the defense of the Atlantic Wall. The use of nerve gas on the Normandy beachhead would have seriously impeded the Allies and possibly caused the invasion to fail altogether. He submitted the question "Why was nerve gas not used in Normandy?" to be asked of Hermann Göring during his interrogation. Göring answered that the reason gas was not used had to do with horses. The Wehrmacht was dependent upon horse-drawn transport to move supplies to their combat units, and had never been able to devise a gas mask horses could tolerate; the versions they developed would not pass enough pure air to allow the horses to pull a cart. Thus, gas was of no use to the German Army under most conditions.^[30]

One reported incident indicates the German army eventually used poison gas on survivors of the Battle of Kerch on the Eastern Crimean peninsula. After the battle in mid-May 1942, roughly 3000 soldiers and civilians not evacuated by sea were besieged in a series of caves and tunnels in the nearby Adzhimuskai quarry. After holding out for approximately three months, "poison gas was released into the tunnels, killing all but a few score of the Soviet defenders."^[31]

In February 1943, German troops stationed in Kuban received a telegram.^[32]

...Russians should be eventually cleared out of the mountain range with gas.

The troops also received two wagons of toxin antidotes.^[32]

Western allies

The Western allies did not use chemical weapons during the Second World War. The British planned to use mustard gas and phosgene to help repel a German invasion in 1940-1941,^[33][34] and had there been an invasion may have also deployed it against German cities.^[35] General Brooke, in command of British anti-invasion preparations during World War II said that he "...had every intention of using sprayed mustard gas on the beaches" in an annotation in his diary.^[36] The British manufactured mustard, chlorine, lewisite, phosgene and Paris Green and stored them at airfields and depots for use on the beaches.^[35]

The mustard gas stockpile was enlarged in 1942-1943 for possible use by Bomber Command against German cities, and in 1944 for possible retaliatory use if German forces used chemical weapons against the D-Day landings.^[33]

Winston Churchill issued a memorandum advocating a chemical strike on German cities using poison gas and possibly anthrax. Although the idea was rejected, it has provoked debate.^[37] In July 1944, fearing that rocket attacks on London would get even worse, and saying he would only use chemical weapons if it were "life or death for us" or would "shorten the war by a year",^[38] Churchill wrote a secret memorandum asking his military chiefs to "think very seriously over this question of using poison gas." He said "it is absurd to consider morality on this topic when everybody used it in the last war without a word of complaint..."

The Joint Planning Staff, however, advised against the use of gas because it would inevitably provoke Germany to retaliate with gas. They argued that this would be to the Allies' disadvantage in France both for military reasons and because it might "seriously impair our relations with the civilian population when it became generally known that chemical warfare was first employed by us."^[39]

Accidental release

On the night of December 2, 1943, German Ju 88 bombers attacked the port of Bari in Southern Italy, sinking several American ships—among them the SS John Harvey, which was carrying mustard gas intended for use in retaliation by the Allies if German forces initiated gas warfare. The presence of the gas was highly classified, and authorities ashore had no knowledge of it, which increased the number of fatalities since physicians, who had no idea that they were dealing with the effects of mustard gas, prescribed treatment improper for those suffering from exposure and immersion.

The whole affair was kept secret at the time and for many years after the war. According to the U.S. military account, "Sixty-nine deaths were attributed in whole or in part to the mustard gas, most of them American merchant seamen"^[40] out of 628 mustard gas military casualties.^[41]

The large number of civilian casualties among the Italian population was not recorded. Part of the confusion and controversy derives from the fact that the German attack was highly destructive and lethal in itself, also apart from the accidental additional effects of the gas (the attack was nicknamed "The Little Pearl Harbor"), and attribution of the causes of death between the gas and other causes is far from easy.^[42][43] Rick Atkinson, in his book The Day of Battle, describes the intelligence that prompted Allied leaders to deploy mustard gas to Italy. This included Italian intelligence that Adolf Hitler had threatened to use gas against Italy if the state changed sides, and prisoner of war interrogations suggesting that preparations were being made to use a "new, egregiously potent gas" if the war turned decisively against Germany. Atkinson concludes, "No commander in 1943 could be cavalier about a manifest threat by Germany to use gas."

Post-war

After World War II, the Allies recovered German artillery shells containing the three German nerve agents of the day (tabun, sarin, and soman), prompting further research into nerve agents by all of the former Allies.

Although the threat of global thermonuclear war was foremost in the minds of most during the Cold War, both the Soviet and Western governments put enormous resources into developing chemical and biological weapons.

Britain

In the late 1940s and early 1950s, British postwar chemical weapons research was based at the Porton Down facility. Research was aimed at providing Britain with the means to arm itself with a modern nerve agent based capability and to develop specific means of defence against these agents.

Ranajit Ghosh, a chemist at the Plant Protection Laboratories of Imperial Chemical Industries was investigating a class of organophosphate compounds (organophosphate esters of substituted aminoethanethiols),^[44] for use as a pesticide. In 1954, ICI put one of them on the market under the trade name Amiton. It was subsequently withdrawn, as it was too toxic for safe use.

The toxicity did not go unnoticed, and samples of it were sent to the research facility at Porton Down for evaluation. After the evaluation was complete, several members of this class of compounds were developed into a new group of much more lethal nerve agents, the V agents. The best-known of these is probably VX, assigned the UK Rainbow Code Purple Possum, with the Russian V-Agent coming a close second (Amiton is largely forgotten as VG).^[45]

On the defensive side, there were years of difficult work to develop the means of prophylaxis, therapy, rapid detection and identification, decontamination and more effective protection of the body against nerve agents, capable of exerting effects through the skin, the eyes and respiratory tract.

Tests were carried out on servicemen to determine the effects of nerve agents on human subjects, with one recorded death due to a nerve gas experiment. There have been persistent allegations of unethical human experimentation at Porton Down, such as those relating to the death of Leading Aircraftman Ronald Maddison, aged 20, in 1953. Maddison was taking part in sarin nerve agent toxicity tests. Sarin was dripped onto his arm and he died shortly afterwards.^[46]

In the 1950s the Chemical Defence Experimental Establishment became involved with the development of CS, a riot control agent, and took an increasing role in trauma and wound ballistics work. Both these facets of Porton Down's work had become more important because of the situation in Northern Ireland.^[47]

In the early 1950s, nerve agents such as sarin were produced in small quantities—about 20 tons were made from 1954 until 1956. CDE Nancekuke was an important factory for stockpiling chemical weapons. Small amounts of VX were produced there, mainly for laboratory test purposes, but also to validate plant designs and optimise chemical processes for potential mass production. However, full-scale mass production of VX agent never took place, with the 1956 decision to end the UK's offensive chemical weapons programme.^[48] In the late 1950s, the chemical weapons production plant at Nancekuke was mothballed, but was maintained through the 1960s and 1970s in a state whereby production of chemical weapons could easily re-commence if required.^[49]

United States

In 1952, the U.S. Army patented a process for the "Preparation of Toxic Ricin", publishing a method of producing this powerful toxin. In 1958 the British government traded their VX technology with the United States in exchange for information on thermonuclear weapons. By 1961 the U.S. was producing large amounts of VX and performing its own nerve agent research. This research produced at least three more agents; the four agents (VE, VG, VM, VX) are collectively known as the "V-Series" class of nerve agents.

Between 1951 and 1969, Dugway Proving Ground was the site of testing for various chemical and biological agents, including an open-air aerodynamic dissemination test in 1968 that accidentally killed, on neighboring farms, approximately 6,400 sheep by an unspecified nerve agent.^[50]

From 1962 to 1973, the Department of Defense planned 134 tests under Project 112, a chemical and biological weapons "vulnerability-testing program." In 2002, the Pentagon admitted for the first time that some of tests used real chemical and biological weapons, not just harmless simulants.^[51]

Specifically under Project SHAD, 37 secret tests were conducted in California, Alaska, Florida, Hawaii, Maryland and Utah. Land tests in Alaska and Hawaii used artillery shells filled with sarin and VX, while Navy trials off the coasts of Florida, California and Hawaii tested the ability of ships and crew to perform under biological and chemical warfare, without the crew's knowledge. The code name for the sea tests was Project Shipboard Hazard and Defense—"SHAD" for short.^[51]

In October 2002, the Senate Armed Forces Subcommittee on Personnel held hearings as the controversial news broke that chemical agents had been tested on thousands of American military personnel. The hearings were chaired by Senator Max Cleland, former VA administrator and Vietnam War veteran.

United States chemical respiratory protection standardization

In December 2001, the United States Department of Health and Human Services, Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH), and National Personal Protective Technology Laboratory (NPPTL), along with the U.S. Army Research, Development and Engineering Command (RDECOM), Edgewood Chemical and Biological Center (ECBC), and the U.S. Department of Commerce National Institute for Standards and Technology (NIST) published the first of six technical performance standards and test procedures designed to evaluate and certify respirators intended for use by civilian emergency responders to a chemical, biological, radiological, or nuclear weapon release, detonation, or terrorism incident.

To date NIOSH/NPPTL has published six new respirator performance standards based on a tiered approach that relies on traditional industrial respirator certification policy, next-generation emergency response respirator performance requirements, and special live chemical warfare agent testing requirements of the classes of respirators identified to offer respiratory protection against chemical, biological, radiological, and nuclear (CBRN) agent inhalation hazards. These CBRN respirators are commonly known as open-circuit self-contained breathing apparatus (CBRN SCBA), air-purifying respirator (CBRN APR), air-purifying escape respirator (CBRN APER), self-contained escape respirator (CBRN SCER) and loose- or tight-fitting powered air-purifying respirators (CBRN PAPR). Current NIOSH-approved/certified CBRN respirator concept standards and test procedures can be found at the webpage.^[52]

Soviet Union

There were numerous reports of chemical weapons being used during the Soviet war in Afghanistan, sometimes against civilians.^[53][54]

Due to the secrecy of the Soviet Union's government, very little information was available about the direction and progress of the Soviet chemical weapons until relatively recently. After the fall of the Soviet Union, Russian chemist Vil Mirzayanov published articles revealing illegal chemical weapons experimentation in Russia.

In 1993, Mirzayanov was imprisoned and fired from his job at the State Research Institute of Organic Chemistry and Technology, where he had worked for 26 years. In March 1994, after a major campaign by U.S. scientists on his behalf, Mirzayanov was released.^[55]

Among the information related by Vil Mirzayanov was the direction of Soviet research into the development of even more toxic nerve agents, which saw most of its success during the mid-1980s. Several highly toxic agents were developed during this period; the only unclassified information regarding these agents is that they are known in the open literature only as "Foliant" agents (named after the program under which they were developed) and by various code designations, such as A-230 and A-232.^[56]

According to Mirzayanov, the Soviets also developed weapons that were safer to handle, leading to the development of the binary weapons, in which precursors for the nerve agents are mixed in a munition to produce the agent just prior to its use. Because the precursors are generally significantly less hazardous than the agents themselves, this technique makes handling and transporting the munitions a great deal simpler.

Additionally, precursors to the agents are usually much easier to stabilize than the agents themselves, so this technique also made it possible to increase the shelf life of the agents a great deal. During the 1980s and 1990s, binary versions of several Soviet agents were developed and are designated as "Novichok" agents (after the Russian word for "newcomer").^[57] Together with Lev Fedorov, he told the secret Novichok story exposed in the newspaper The Moscow News.^[58]

Use in post-WWII conflicts

Stalag 13 prison camp

The earliest successful use of chemical agents in a non-combat setting was in 1946. Motivated by a desire to obtain revenge on Germans for the Holocaust, three members of a Jewish group calling themselves Dahm Y'Israel Nokeam ("Avenging Israel's Blood") hid in a bakery in the Stalag 13 prison camp near Nuremberg, Germany, where several thousand SS troops were being detained. The three applied an arsenic-containing mixture to loaves of bread, sickening more than 2,000 Nazi troops, of whom more than 200 required hospitalization.

North Yemen

The first attack of the North Yemen Civil War took place on June 8, 1963 against Kawma, a village of about 100 inhabitants in northern Yemen, killing about seven people and damaging the eyes and lungs of 25 others. This incident is considered to have been experimental, and the bombs were described as "home-made, amateurish and relatively ineffective". The Egyptian authorities suggested that the reported incidents were probably caused by napalm, not gas.

There were no reports of gas during 1964, and only a few were reported in 1965. The reports grew more frequent in late 1966. On December 11, 1966, fifteen gas bombs killed two people and injured thirty-five. On January 5, 1967, the biggest gas attack came against the village of Kitaf, causing 270 casualties, including 140 fatalities. The target may have been Prince Hassan bin Yahya, who had installed his headquarters nearby. The Egyptian government denied using poison gas, and alleged that Britain and the US were using the reports as psychological warfare against Egypt. On February 12, 1967, it said it would welcome a UN investigation. On March 1, U Thant, the then Secretary-General of the United Nations, said he was "powerless" to deal with the matter.

On May 10, 1967 the twin villages of Gahar and Gadafa in Wadi Hirran, where Prince Mohamed bin Mohsin was in command, were gas bombed, killing at least seventy-five. The Red Cross was alerted and on June 2, 1967, it issued a statement in Geneva expressing concern. The Institute of Forensic Medicine at the University of Berne made a statement, based on a Red Cross report, that the gas was likely to have been halogenous derivatives—phosgene, mustard gas, lewisite, chloride or cyanogen bromide.

The gas attacks stopped for three weeks after the Six-Day War of June, but resumed in July, against all parts of royalist Yemen. Casualty estimates vary, and an assumption, considered conservative, is that the mustard-and-phosgene-filled aerial bombs caused approximately 1,500 fatalities and 1,500 injuries.

Vietnamese border raids in Thailand

There is some evidence suggesting that Vietnamese troops used phosgene gas against Cambodian resistance forces in Thailand during the 1984-1985 dry-season offensive on the Thai-Cambodian border.^[59][60][61]

Iran–Iraq War

Chemical weapons employed by Saddam Hussein killed and injured numerous Iranians and Iraqi Kurds. According to Iraqi documents, assistance in developing chemical weapons was obtained from firms in many countries, including the United States, West Germany, the Netherlands, the United Kingdom, and France.^[62]

About 100,000 Iranian soldiers were victims of Iraq's chemical attacks. Many were hit by mustard gas. The official estimate does not include the civilian population contaminated in bordering towns or the children and relatives of veterans, many of whom have developed blood, lung and skin complications, according to the Organization for Veterans. Nerve gas agents killed about 20,000 Iranian soldiers immediately, according to official reports. Of the 80,000 survivors, some 5,000 seek medical treatment regularly and about 1,000 are still hospitalized with severe, chronic conditions.^[63][64][65]

Halabja

Shortly before the war ended in 1988, the Iraqi Kurdish village of Halabja was exposed to multiple chemical agents, killing about 5,000 of the town's 50,000 residents.^[66]

During the Gulf War in 1991, Coalition forces began a ground war in Iraq. Despite the fact that they did possess chemical weapons, Iraq did not use any chemical agents against coalition forces. The commander of the Allied Forces, General Norman Schwarzkopf, suggested this may have been due to Iraqi fear of retaliation with nuclear weapons.

Angola

During the Cuban intervention in Angola, United Nations toxicologists certified that residue from both VX and sarin nerve agents had been discovered in plants, water, and soil where Cuban units were conducting operations against National Union for the Total Independence of Angola (UNITA) insurgents.^[67] In 1985, UNITA made the first of several claims that their forces were the target of chemical weapons, specifically organophosphates. The following year guerrillas reported being bombarded with an unidentified greenish-yellow agent on three separate occasions. Depending on the length and intensity of exposure, victims suffered blindness or death. The toxin was also observed to have killed plant life.^[68] Shortly afterwards, UNITA also sighted strikes carried out with a brown agent which it claimed resembled mustard gas.^[69] As early as 1984 a research team dispatched by the University of Ghent had examined patients in UNITA field hospitals showing signs of exposure to nerve agents, although it found no evidence of mustard gas.^[70]

The UN first accused Cuba of deploying chemical weapons against Angolan civilians and partisans in 1988.^[67] Wouter Basson later disclosed that South African military intelligence had long verified the use of unidentified chemical weapons on Angolan soil; this was to provide the impetus for their own biological warfare programme, Project Coast.^[67] During the Battle of Cuito Cuanavale, South African troops then fighting in Angola were issued with gas masks and ordered to rehearse chemical weapons drills. Although the status of its own chemical weapons program remained uncertain, South Africa also deceptively bombarded Cuban and Angolan units with coloured smoke in an attempt to induce hysteria or mass panic.^[69] According to Defence Minister Magnus Malan, this would force the Cubans to share the inconvenience of having to take preventative measures such as donning NBC suits, which would cut combat effectiveness in half. The tactic was effective: beginning in early 1988 Cuban units posted to Angola were issued with full protective gear in anticipation of a South African chemical strike.^[69]

On 29 October 1988, personnel attached to Angola's 59 Brigade, accompanied by six Soviet military advisors, reported being struck with chemical weapons on the banks of the Mianei River.^[71] The attack occurred shortly after one in the afternoon. Four Angolan soldiers lost consciousness while the others complained of violent headaches and nausea. That November the Angolan representative to the UN accused South Africa of employing poison gas near Cuito Cuanavale for the first time.^[71]

Falklands War

Technically, the reported employment of tear gas by Argentine forces during the 1982 invasion of the Falkland Islands constitutes chemical warfare.^[72] However, the tear gas grenades were employed as nonlethal weapons to avoid British casualties. The barrack buildings the weapons were used on proved to be deserted in any case. The British claim that more lethal, but legally justifiable as they are not considered chemical weapons under the Chemical Weapons Convention, white phosphorus grenades were used.^[73]

Syrian Civil War

Terrorism

For many terrorist organizations, chemical weapons might be considered an ideal choice for a mode of attack, if they are available: they are cheap, relatively accessible, and easy to transport. A skilled chemist can readily synthesize most chemical agents if the precursors are available.

In July 1974, a group calling themselves the Aliens of America successfully firebombed the houses of a judge, two police commissioners, and one of the commissioner’s cars, burned down two apartment buildings, and bombed the Pan Am Terminal at Los Angeles International Airport, killing three people and injuring eight. The organization, which turned out to be a single resident alien named Muharem Kurbegovic, claimed to have developed and possessed a supply of sarin, as well as four unique nerve agents named AA1, AA2, AA3, and AA4S. Although no agents were found at the time Kurbegovic was arrested in August 1974, he had reportedly acquired "all but one" of the ingredients required to produce a nerve agent. A search of his apartment turned up a variety of materials, including precursors for phosgene and a drum containing 25 pounds of sodium cyanide.^[74]

The first successful use of chemical agents by terrorists against a general civilian population was on June 27, 1994, when Aum Shinrikyo, an apocalyptic group based in Japan that believed it necessary to destroy the planet, released sarin gas in Matsumoto, Japan, killing eight and harming 200. The following year, Aum Shinrikyo released sarin into the Tokyo subway system killing 12 and injuring over 5,000.

On 29 December 1999, four days after Russian forces began an assault of Grozny, Chechen terrorists exploded two chlorine tanks in the town. Because of the wind conditions, no Russian soldiers were injured.^[75]

In 2001, after carrying out the attacks in New York City on September 11, the organization Al-Qaeda announced that they were attempting to acquire radiological, biological and chemical weapons. This threat was lent a great deal of credibility when a large archive of videotapes was obtained by the cable television network CNN in August 2002 showing, among other things, the killing of three dogs by an apparent nerve agent.^[76]

On October 26, 2002, Russian special forces used a chemical agent (presumably KOLOKOL-1, an aerosolized fentanyl derivative), as a precursor to an assault on Chechen terrorists, ending the Moscow theater hostage crisis. All 42 of the terrorists and 120 out of 850 hostages were killed during the raid. Of the hostages who died, all but one or two died from the effects of the agent.

In early 2007, multiple terrorist bombings had been reported in Iraq using chlorine gas. These attacks wounded or sickened more than 350 people. Reportedly the bombers were affiliated with Al-Qaeda in Iraq,^[77] and they have used bombs of various sizes up to chlorine tanker trucks.^[78] United Nations Secretary-General Ban Ki-moon condemned the attacks as "clearly intended to cause panic and instability in the country."^[79]

Chemical weapons treaties

The Protocol for the Prohibition of the Use in War of Asphyxiating, Poisonous or other Gases, and the Bacteriological Methods of Warfare, or the Geneva Protocol, is an international treaty which prohibits the use of chemical and biological weapons in warfare. Signed into international Law at Geneva on June 17, 1925 and entered into force on February 8, 1928, this treaty states that chemical and biological weapons are "justly condemned by the general opinion of the civilised world."^[80]

Chemical Weapons Convention

The most recent arms control agreement in International Law, the Convention of the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, or the Chemical Weapons Convention, outlaws the production, stockpiling, and use of chemical weapons. It is administered by the Organisation for the Prohibition of Chemical Weapons (OPCW), an intergovernmental organisation based in The Hague.^[81]

Technology

Chemical warfare technology timeline

	Agents	Dissemination	Protection	Detection
1914	Chlorine Chloropicrin Phosgene Mustard gas	Wind dispersal	Gas masks, urinated-on gauze	Smell
1918	Lewisite	Chemical shells	Gas mask Rosin oil clothing	smell of geraniums
1920s		Projectiles w/ central bursters	CC-2 clothing
1930s	G-series nerve agents	Aircraft bombs		Blister agent detectors Color change paper
1940s		Missile warheads Spray tanks	Protective ointment (mustard) Collective protection Gas mask w/ Whetlerite
1950s
1960s	V-series nerve agents	Aerodynamic	Gas mask w/ water supply	Nerve gas alarm
1970s
1980s		Binary munitions	Improved gas masks (protection, fit, comfort)	Laser detection
1990s	Novichok nerve agents

Although crude chemical warfare has been employed in many parts of the world for thousands of years,^[82] "modern" chemical warfare began during World War I - see Chemical weapons in World War I.

Initially, only well-known commercially available chemicals and their variants were used. These included chlorine and phosgene gas. The methods used to disperse these agents during battle were relatively unrefined and inefficient. Even so, casualties could be heavy, due to the mainly static troop positions which were characteristic features of trench warfare.

Germany, the first side to employ chemical warfare on the battlefield,^[83] simply opened canisters of chlorine upwind of the opposing side and let the prevailing winds do the dissemination. Soon after, the French modified artillery munitions to contain phosgene – a much more effective method that became the principal means of delivery.^[84]

Since the development of modern chemical warfare in World War I, nations have pursued research and development on chemical weapons that falls into four major categories: new and more deadly agents; more efficient methods of delivering agents to the target (dissemination); more reliable means of defense against chemical weapons; and more sensitive and accurate means of detecting chemical agents.

Chemical warfare agents

A chemical used in warfare is called a chemical warfare agent (CWA). About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th and 21st centuries. These agents may be in liquid, gas or solid form. Liquid agents that evaporate quickly are said to be volatile or have a high vapor pressure. Many chemical agents are made volatile so they can be dispersed over a large region quickly.

The earliest target of chemical warfare agent research was not toxicity, but development of agents that can affect a target through the skin and clothing, rendering protective gas masks useless. In July 1917, the Germans employed mustard gas. Mustard gas easily penetrates leather and fabric to inflict painful burns on the skin.

Chemical warfare agents are divided into lethal and incapacitating categories. A substance is classified as incapacitating if less than 1/100 of the lethal dose causes incapacitation, e.g., through nausea or visual problems. The distinction between lethal and incapacitating substances is not fixed, but relies on a statistical average called the LD₅₀.

Persistency

Chemical warfare agents can be classified according to their persistency, a measure of the length of time that a chemical agent remains effective after dissemination. Chemical agents are classified as persistent or nonpersistent.

Agents classified as nonpersistent lose effectiveness after only a few minutes or hours or even only a few seconds. Purely gaseous agents such as chlorine are nonpersistent, as are highly volatile agents such as sarin. Tactically, nonpersistent agents are very useful against targets that are to be taken over and controlled very quickly.

Apart from the agent used, the delivery mode is very important. To achieve a nonpersistent deployment, the agent is dispersed into very small droplets comparable with the mist produced by an aerosol can. In this form not only the gaseous part of the agent (around 50%) but also the fine aerosol can be inhaled or absorbed through pores in the skin.

Modern doctrine requires very high concentrations almost instantly in order to be effective (one breath should contain a lethal dose of the agent). To achieve this, the primary weapons used would be rocket artillery or bombs and large ballistic missiles with cluster warheads. The contamination in the target area is only low or not existent and after four hours sarin or similar agents are not detectable anymore.

By contrast, persistent agents tend to remain in the environment for as long as several weeks, complicating decontamination. Defense against persistent agents requires shielding for extended periods of time. Non-volatile liquid agents, such as blister agents and the oily VX nerve agent, do not easily evaporate into a gas, and therefore present primarily a contact hazard.

The droplet size used for persistent delivery goes up to 1 mm increasing the falling speed and therefore about 80% of the deployed agent reaches the ground, resulting in heavy contamination. Deployment of persistent agents is intended to constrain enemy operations by denying access to contaminated areas.

Possible targets include enemy flank positions (averting possible counterattacks), artillery regiments, commando posts or supply lines. Because it is not necessary to deliver large quantities of the agent in a short period of time, a wide variety of weapons systems can be used.

A special form of persistent agents are thickened agents. These comprise a common agent mixed with thickeners to provide gelatinous, sticky agents. Primary targets for this kind of use include airfields, due to the increased persistency and difficulty of decontaminating affected areas.

Classes

Chemical weapons are inert agents that come in four categories: choking, blister, blood and nerve.^[85] The agents are organized into several categories according to the manner in which they affect the human body. The names and number of categories varies slightly from source to source, but in general, types of chemical warfare agents are as follows:

Classes of chemical weapon agents

Class of agent	Agent Names	Mode of Action	Signs and Symptoms	Rate of action	Persistency
Nerve	Cyclosarin (GF) Sarin (GB) Soman (GD) Tabun (GA) VX VR Some insecticides Novichok agents	Inactivates enzyme acetylcholinesterase, preventing the breakdown of the neurotransmitter acetylcholine in the victim's synapses and causing both muscarinic and nicotinic effects	Miosis (pinpoint pupils) Blurred/dim vision Headache Nausea, vomiting, diarrhea Copious secretions/sweating Muscle twitching/fasciculations Dyspnea Seizures Loss of consciousness	Vapors: seconds to minutes; Skin: 2 to 18 hours	VX is persistent and a contact hazard; other agents are non-persistent and present mostly inhalation hazards.
Asphyxiant/Blood	Most Arsines Cyanogen chloride Hydrogen cyanide	Arsine: Causes intravascular hemolysis that may lead to renal failure. Cyanogen chloride/hydrogen cyanide: Cyanide directly prevents cells from using oxygen. The cells then use anaerobic respiration, creating excess lactic acid and metabolic acidosis.	Possible cherry-red skin Possible cyanosis Confusion Nausea Patients may gasp for air Seizures prior to death Metabolic acidosis	Immediate onset	Non-persistent and an inhalation hazard.
Vesicant/Blister	Sulfur mustard (HD, H) Nitrogen mustard (HN-1, HN-2, HN-3) Lewisite (L) Phosgene oxime (CX)	Agents are acid-forming compounds that damages skin and respiratory system, resulting burns and respiratory problems.	Severe skin, eye and mucosal pain and irritation Skin erythema with large fluid blisters that heal slowly and may become infected Tearing, conjunctivitis, corneal damage Mild respiratory distress to marked airway damage	Mustards: Vapors: 4 to 6 hours, eyes and lungs affected more rapidly; Skin: 2 to 48 hours Lewisite: Immediate	Persistent and a contact hazard.
Choking/Pulmonary	Chlorine Hydrogen chloride Nitrogen oxides Phosgene	Similar mechanism to blister agents in that the compounds are acids or acid-forming, but action is more pronounced in respiratory system, flooding it and resulting in suffocation; survivors often suffer chronic breathing problems.	Airway irritation Eye and skin irritation Dyspnea, cough Sore throat Chest tightness Wheezing Bronchospasm	Immediate to 3 hours	Non-persistent and an inhalation hazard.
Lachrymatory agent	Tear gas Pepper spray	Causes severe stinging of the eyes and temporary blindness.	Powerful eye irritation	Immediate	Non-persistent and an inhalation hazard.
Incapacitating	Agent 15 (BZ)	Causes atropine-like inhibition of acetylcholine in subject. Causes peripheral nervous system effects that are the opposite of those seen in nerve agent poisoning.	May appear as mass drug intoxication with erratic behaviors, shared realistic and distinct hallucinations, disrobing and confusion Hyperthermia Ataxia (lack of coordination) Mydriasis (dilated pupils) Dry mouth and skin	Inhaled: 30 minutes to 20 hours; Skin: Up to 36 hours after skin exposure to BZ. Duration is typically 72 to 96 hours.	Extremely persistent in soil and water and on most surfaces; contact hazard.
Cytotoxic proteins	Non-living biological proteins, such as: Ricin Abrin	Inhibit protein synthesis	Latent period of 4-8 hours, followed by flu-like signs and symptoms Progress within 18-24 hours to: Inhalation: nausea, cough, dyspnea, pulmonary edema Ingestion: Gastrointestinal hemorrhage with emesis and bloody diarrhea; eventual liver and kidney failure.	4-24 hours; see symptoms. Exposure by inhalation or injection causes more pronounced signs and symptoms than exposure by ingestion	Slight; agents degrade quickly in environment

There are other chemicals used militarily that are not scheduled by the Chemical Weapons Convention, and thus are not controlled under the CWC treaties. These include:

• Defoliants and herbicides that destroy vegetation, but are not immediately toxic or poisonous to human beings. Their use is classified as herbicidal warfare. Some batches of Agent Orange, for instance, used by the British during the Malayan Emergency and the United States during the Vietnam War, contained dioxins as manufacturing impurities. Dioxins, rather than Agent Orange itself, have long-term cancer effects and for causing genetic damage leading to serious birth deformities.
• Incendiary or explosive chemicals (such as napalm, extensively used by the United States during the Korean War and the Vietnam War, or dynamite) because their destructive effects are primarily due to fire or explosive force, and not direct chemical action. Their use is classified as conventional warfare.
• Viruses, bacteria, or other organisms. Their use is classified as biological warfare. Toxins produced by living organisms are considered chemical weapons, although the boundary is blurry. Toxins are covered by the Biological Weapons Convention.

Designations

Most chemical weapons are assigned a one- to three-letter "NATO weapon designation" in addition to, or in place of, a common name. Binary munitions, in which precursors for chemical warfare agents are automatically mixed in shell to produce the agent just prior to its use, are indicated by a "-2" following the agent's designation (for example, GB-2 and VX-2).

Some examples are given below:

Blood agents:	Vesicants:
Cyanogen chloride: CK Hydrogen cyanide: AC	Lewisite: L Sulfur mustard: H, HD, HS, HT
Pulmonary agents:	Incapacitating agents:
Phosgene: CG	Quinuclidinyl benzilate: BZ
Lachrymatory agents:	Nerve agents:
Pepper spray: OC Tear gas: CN, CS, CR	Sarin: GB VE, VG, VM, VX

Delivery

The most important factor in the effectiveness of chemical weapons is the efficiency of its delivery, or dissemination, to a target. The most common techniques include munitions (such as bombs, projectiles, warheads) that allow dissemination at a distance and spray tanks which disseminate from low-flying aircraft. Developments in the techniques of filling and storage of munitions have also been important.

Although there have been many advances in chemical weapon delivery since World War I, it is still difficult to achieve effective dispersion. The dissemination is highly dependent on atmospheric conditions because many chemical agents act in gaseous form. Thus, weather observations and forecasting are essential to optimize weapon delivery and reduce the risk of injuring friendly forces.

Dispersion

Dispersion is placing the chemical agent upon or adjacent to a target immediately before dissemination, so that the material is most efficiently used. Dispersion is the simplest technique of delivering an agent to its target. The most common techniques are munitions, bombs, projectiles, spray tanks and warheads.

World War I saw the earliest implementation of this technique. The actual first chemical ammunition was the French 26 mm cartouche suffocante rifle grenade, fired from a flare carbine. It contained 35g of the tear-producer ethyl bromoacetate, and was used in autumn 1914 – with little effect on the Germans.

The Germans on the other hand tried to increase the effect of 10.5 cm shrapnel shells by adding an irritant – dianisidine chlorosulfonate. Its use went unnoticed by the British when it was used against them at Neuve Chapelle in October 1914. Hans Tappen, a chemist in the Heavy Artillery Department of the War Ministry, suggested to his brother, the Chief of the Operations Branch at German General Headquarters, the use of the tear-gases benzyl bromide or xylyl bromide.

Shells were tested successfully at the Wahn artillery range near Cologne on 9 January 1915, and an order was placed for 15 cm howitzer shells, designated ‘T-shells’ after Tappen. A shortage of shells limited the first use against the Russians at Bolimów on 31 January 1915; the liquid failed to vaporize in the cold weather, and again the experiment went unnoticed by the Allies.

The first effective use were when the German forces at the Second Battle of Ypres simply opened cylinders of chlorine and allowed the wind to carry the gas across enemy lines. While simple, this technique had numerous disadvantages. Moving large numbers of heavy gas cylinders to the front-line positions from where the gas would be released was a lengthy and difficult logistical task.

Stockpiles of cylinders had to be stored at the front line, posing a great risk if hit by artillery shells. Gas delivery depended greatly on wind speed and direction. If the wind was fickle, as at Loos, the gas could blow back, causing friendly casualties.

Gas clouds gave plenty of warning, allowing the enemy time to protect themselves, though many soldiers found the sight of a creeping gas cloud unnerving. This made the gas doubly effective, as, in addition to damaging the enemy physically, it also had a psychological effect on the intended victims.

Another disadvantage was that gas clouds had limited penetration, capable only of affecting the front-line trenches before dissipating. Although it produced limited results in World War I, this technique shows how simple chemical weapon dissemination can be.

Shortly after this "open canister" dissemination, French forces developed a technique for delivery of phosgene in a non-explosive artillery shell. This technique overcame many of the risks of dealing with gas in cylinders. First, gas shells were independent of the wind and increased the effective range of gas, making any target within reach of guns vulnerable. Second, gas shells could be delivered without warning, especially the clear, nearly odorless phosgene– there are numerous accounts of gas shells, landing with a "plop" rather than exploding, being initially dismissed as dud high explosive or shrapnel shells, giving the gas time to work before the soldiers were alerted and took precautions.

The major drawback of artillery delivery was the difficulty of achieving a killing concentration. Each shell had a small gas payload and an area would have to be subjected to saturation bombardment to produce a cloud to match cylinder delivery. A British solution to the problem was the Livens Projector. This was effectively a large-bore mortar, dug into the ground that used the gas cylinders themselves as projectiles - firing a 14 kg cylinder up to 1500 m. This combined the gas volume of cylinders with the range of artillery.

Over the years, there were some refinements in this technique. In the 1950s and early 1960s, chemical artillery rockets and cluster bombs contained a multitude of submunitions, so that a large number of small clouds of the chemical agent would form directly on the target.

Thermal dissemination

Thermal dissemination is the use of explosives or pyrotechnics to deliver chemical agents. This technique, developed in the 1920s, was a major improvement over earlier dispersal techniques, in that it allowed significant quantities of an agent to be disseminated over a considerable distance. Thermal dissemination remains the principal method of disseminating chemical agents today.

Most thermal dissemination devices consist of a bomb or projectile shell that contains a chemical agent and a central "burster" charge; when the burster detonates, the agent is expelled laterally.

Thermal dissemination devices, though common, are not particularly efficient. First, a percentage of the agent is lost by incineration in the initial blast and by being forced onto the ground. Second, the sizes of the particles vary greatly because explosive dissemination produces a mixture of liquid droplets of variable and difficult to control sizes.

The efficacy of thermal detonation is greatly limited by the flammability of some agents. For flammable aerosols, the cloud is sometimes totally or partially ignited by the disseminating explosion in a phenomenon called flashing. Explosively disseminated VX will ignite roughly one third of the time. Despite a great deal of study, flashing is still not fully understood, and a solution to the problem would be a major technological advance.

Despite the limitations of central bursters, most nations use this method in the early stages of chemical weapon development, in part because standard munitions can be adapted to carry the agents.

Aerodynamic dissemination

Aerodynamic dissemination is the non-explosive delivery of a chemical agent from an aircraft, allowing aerodynamic stress to disseminate the agent. This technique is the most recent major development in chemical agent dissemination, originating in the mid-1960s.

This technique eliminates many of the limitations of thermal dissemination by eliminating the flashing effect and theoretically allowing precise control of particle size. In actuality, the altitude of dissemination, wind direction and velocity, and the direction and velocity of the aircraft greatly influence particle size. There are other drawbacks as well; ideal deployment requires precise knowledge of aerodynamics and fluid dynamics, and because the agent must usually be dispersed within the boundary layer (less than 200–300 ft above the ground), it puts pilots at risk.

Significant research is still being applied toward this technique. For example, by modifying the properties of the liquid, its breakup when subjected to aerodynamic stress can be controlled and an idealized particle distribution achieved, even at supersonic speed. Additionally, advances in fluid dynamics, computer modeling, and weather forecasting allow an ideal direction, speed, and altitude to be calculated, such that warfare agent of a predetermined particle size can predictably and reliably hit a target.

Protection against chemical warfare

Ideal protection begins with nonproliferation treaties such as the Chemical Weapons Convention, and detecting, very early, the signatures of someone building a chemical weapons capability. These include a wide range of intelligence disciplines, such as economic analysis of exports of dual-use chemicals and equipment, human intelligence (HUMINT) such as diplomatic, refugee, and agent reports; photography from satellites, aircraft and drones (IMINT); examination of captured equipment (TECHINT); communications intercepts (COMINT); and detection of chemical manufacturing and chemical agents themselves (MASINT).

If all the preventive measures fail and there is a clear and present danger, then there is a need for detection of chemical attacks,^[86] collective protection,^[87][88][89] and decontamination. Since industrial accidents can cause dangerous chemical releases (e.g., the Bhopal disaster), these activities are things that civilian, as well as military, organizations must be prepared to carry out. In civilian situations in developed countries, these are duties of HAZMAT organizations, which most commonly are part of fire departments.

Detection has been referred to above, as a technical MASINT discipline; specific military procedures, which are usually the model for civilian procedures, depend on the equipment, expertise, and personnel available. When chemical agents are detected, an alarm needs to sound, with specific warnings over emergency broadcasts and the like. There may be a warning to expect an attack.

If, for example, the captain of a US Navy ship believes there is a serious threat of chemical, biological, or radiological attack, the crew may be ordered to set Circle William, which means closing all openings to outside air, running breathing air through filters, and possibly starting a system that continually washes down the exterior surfaces. Civilian authorities dealing with an attack or a toxic chemical accident will invoke the Incident Command System, or local equivalent, to coordinate defensive measures.^[89]

Individual protection starts with a gas mask and, depending on the nature of the threat, through various levels of protective clothing up to a complete chemical-resistant suit with a self-contained air supply. The US military defines various levels of MOPP (mission-oriented protective posture) from mask to full chemical resistant suits; Hazmat suits are the civilian equivalent, but go farther to include a fully independent air supply, rather than the filters of a gas mask.

Collective protection allows continued functioning of groups of people in buildings or shelters, the latter which may be fixed, mobile, or improvised. With ordinary buildings, this may be as basic as plastic sheeting and tape, although if the protection needs to be continued for any appreciable length of time, there will need to be an air supply, typically an enhanced gas mask.^[88][89]

Decontamination

Decontamination varies with the particular chemical agent used. Some nonpersistent agents, including most pulmonary agents (chlorine, phosgene, and so on), blood gases, and nonpersistent nerve gases (e.g., GB), will dissipate from open areas, although powerful exhaust fans may be needed to clear out buildings where they have accumulated.

In some cases, it might be necessary to neutralize them chemically, as with ammonia as a neutralizer for hydrogen cyanide or chlorine. Riot control agents such as CS will dissipate in an open area, but things contaminated with CS powder need to be aired out, washed by people wearing protective gear, or safely discarded.

Mass decontamination is a less common requirement for people than equipment, since people may be immediately affected and treatment is the action required. It is a requirement when people have been contaminated with persistent agents. Treatment and decontamination may need to be simultaneous, with the medical personnel protecting themselves so they can function.^[90]

There may need to be immediate intervention to prevent death, such as injection of atropine for nerve agents. Decontamination is especially important for people contaminated with persistent agents; many of the fatalities after the explosion of a WWII US ammunition ship carrying mustard gas, in the harbor of Bari, Italy, after a German bombing on 2 December 1943, came when rescue workers, not knowing of the contamination, bundled cold, wet seamen in tight-fitting blankets.

For decontaminating equipment and buildings exposed to persistent agents, such as blister agents, VX or other agents made persistent by mixing with a thickener, special equipment and materials might be needed. Some type of neutralizing agent will be needed; e.g. in the form of a spraying device with neutralizing agents such as Chlorine, Fichlor, strong alkaline solutions or enzymes. In other cases, a specific chemical decontaminant will be required.^[89]

Sociopolitical climate

The study of chemicals and their military uses was widespread in China and India. The use of toxic materials has historically been viewed with mixed emotions and moral qualms in the West. The practical and ethical problems surrounding poison warfare appeared in ancient Greek myths about Hercules' invention of poison arrows and Odysseus's use of toxic projectiles. There are many instances of the use of chemical weapons in battles documented in Greek and Roman historical texts; the earliest example was the deliberate poisoning of Kirrha's water supply with hellebore in the First Sacred War, Greece, about 590 BC.^[91]

One of the earliest reactions to the use of chemical agents was from Rome. Struggling to defend themselves from the Roman legions, Germanic tribes poisoned the wells of their enemies, with Roman jurists having been recorded as declaring "armis bella non venenis geri", meaning "war is fought with weapons, not with poisons." Yet the Romans themselves resorted to poisoning wells of besieged cities in Anatolia in the 2nd century BCE.^[3]

Before 1915 the use of poisonous chemicals in battle was typically the result of local initiative, and not the result of an active government chemical weapons program. There are many reports of the isolated use of chemical agents in individual battles or sieges, but there was no true tradition of their use outside of incendiaries and smoke. Despite this tendency, there have been several attempts to initiate large-scale implementation of poison gas in several wars, but with the notable exception of World War I, the responsible authorities generally rejected the proposals for ethical reasons.

For example, in 1854 Lyon Playfair (later 1st Baron Playfair, GCB, PC, FRS (1 May 1818 – 29 May 1898), a British chemist, proposed using a cacodyl cyanide-filled artillery shell against enemy ships during the Crimean War. The British Ordnance Department rejected the proposal as "as bad a mode of warfare as poisoning the wells of the enemy."

Efforts to eradicate chemical weapons

Nation	CW Possession	Signed CWC	Ratified CWC
Albania	Known	January 14, 1993[92]	May 11, 1994[92]
Burma (Myanmar)	Possible	January 14, 1993[93]	July 8, 2015[94]
China	Probable	January 13, 1993	April 4, 1997
Egypt	Probable	No	No
India	Known	January 14, 1993	September 3, 1996
Iran	Known	January 13, 1993	November 3, 1997
Israel	Probable	January 13, 1993[93]	No
Japan	Probable	January 13, 1993	September 15, 1995
Libya	Known	No	January 6, 2004 (acceded)
North Korea	Known	No	No
Pakistan	Probable	January 13, 1993	October 28, 1997
Russia	Known	January 13, 1993	November 5, 1997
Serbia and Montenegro	Probable	No	April 20, 2000 (acceded)
Sudan	Possible	No	May 24, 1999 (acceded)
Syria	Known	No	September 14, 2013 (acceded)
Taiwan	Possible	n/a	n/a
United States	Known	January 13, 1993	April 25, 1997
Vietnam	Probable	January 13, 1993	September 30, 1998

• August 27, 1874: The Brussels Declaration Concerning the Laws and Customs of War is signed, specifically forbidding the "employment of poison or poisoned weapons", although the treaty was not adopted by any nation whatsoever and it never went into effect.
• September 4, 1900: The First Hague Convention, which includes a declaration banning the "use of projectiles the object of which is the diffusion of asphyxiating or deleterious gases," enters into force.
• January 26, 1910: The Second Hague Convention enters into force, prohibiting the use of "poison or poisoned weapons" in warfare.
• February 6, 1922: After World War I, the Washington Arms Conference Treaty prohibited the use of asphyxiating, poisonous or other gases. It was signed by the United States, Britain, Japan, France, and Italy, but France objected to other provisions in the treaty and it never went into effect.
• February 8, 1928: The Geneva Protocol enters into force, prohibiting the use of "asphyxiating, poisonous or other gases, and of all analogous liquids, materials or devices" and "bacteriological methods of warfare".

Chemical weapon proliferation

Despite numerous efforts to reduce or eliminate them, some nations continue to research and/or stockpile chemical warfare agents. To the right is a summary of the nations that have either declared weapon stockpiles or are suspected of secretly stockpiling or possessing CW research programs. Notable examples include United States and Russia.

In 1997, future US Vice President Dick Cheney opposed the signing ratification of a treaty banning the use chemical weapons, a recently unearthed letter shows. In a letter dated April 8, 1997, then Halliburton-CEO Cheney told Sen. Jesse Helms, the chairman of the Senate Foreign Relations Committee, that it would be a mistake for America to join the Convention. "Those nations most likely to comply with the Chemical Weapons Convention are not likely to ever constitute a military threat to the United States. The governments we should be concerned about are likely to cheat on the CWC, even if they do participate," reads the letter,^[95] published by the Federation of American Scientists.

The CWC was ratified by the Senate that same month. Since then, Albania, Libya, Russia, the United States, and India have declared over 71,000 metric tons of chemical weapon stockpiles, and destroyed about a third of them. Under the terms of the agreement, the United States and Russia agreed to eliminate the rest of their supplies of chemical weapons by 2012. Not having met its goal, the U.S. government estimates remaining stocks will be destroyed by 2017.

Chemical weapons destruction

India

In June 1997, India declared that it had a stockpile of 1044 tonnes of sulphur mustard in its possession. India's declaration of its stockpile came after its entry into the Chemical Weapons Convention, that created the Organisation for the Prohibition of Chemical Weapons, and on January 14, 1993 India became one of the original signatories to the Chemical Weapons Convention. By 2005, from among six nations that had declared their possession of chemical weapons, India was the only country to meet its deadline for chemical weapons destruction and for inspection of its facilities by the Organisation for the Prohibition of Chemical Weapons.^[96][97] By 2006, India had destroyed more than 75 percent of its chemical weapons and material stockpile and was granted an extension to complete a 100 percent destruction of its stocks by April 2009. On May 14, 2009 India informed the United Nations that it has completely destroyed its stockpile of chemical weapons.^[98]

Iraq

The Director-General of the Organisation for the Prohibition of Chemical Weapons, Ambassador Rogelio Pfirter, welcomed Iraq's decision to join the OPCW as a significant step to strengthening global and regional efforts to prevent the spread and use of chemical weapons. The OPCW announced "The government of Iraq has deposited its instrument of accession to the Chemical Weapons Convention with the Secretary General of the United Nations and within 30 days, on 12 February 2009, will become the 186th State Party to the Convention". Iraq has also declared stockpiles of chemical weapons, and because of their recent accession is the only State Party exempted from the destruction time-line.^[99]

Japan

During the Second Sino-Japanese War (1937–1945) Japan stored chemical weapons on the territory of mainland China. The weapon stock mostly containing mustard gas-lewisite mixture.^[100] The weapons are classified as abandoned chemical weapons under the Chemical Weapons Convention and from September 2010 Japan has started their destruction in Nanjing using mobile destruction facilities in order to do so.^[101]

Russia

Russia signed into the Chemical Weapons Convention on January 13, 1993 and ratified it on November 5, 1995. Declaring an arsenal of 39,967 tons of chemical weapons in 1997, by far the largest arsenal, consisting of blister agents: Lewisite, Sulfur mustard, Lewisite-mustard mix, and nerve agents: Sarin, Soman, and VX. Russia met its treaty obligations by destroying 1 percent of its chemical agents by the 2002 deadline set out by the Chemical Weapons Convention, but requested an extension on the deadlines of 2004 and 2007 due to technical, financial, and environmental challenges of chemical disposal. Since, Russia has received help from other countries such as Canada which donated C$100,000, plus a further C$100,000 already donated, to the Russian Chemical Weapons Destruction Program. This money will be used to complete work at Shchuch'ye and support the construction of a chemical weapons destruction facility at Kizner (Russia), where the destruction of nearly 5,700 tonnes of nerve agent, stored in approximately 2 million artillery shells and munitions, will be undertaken. Canadian funds are also being used for the operation of a Green Cross Public Outreach Office, to keep the civilian population informed on the progress made in chemical weapons destruction activities.^[102]

As of July 2011, Russia has destroyed 48 percent (18,241 tonnes) of its stockpile at destruction facilities located in Gorny (Saratov Oblast) and Kambarka (Udmurt Republic) - where operations have finished - and Schuch'ye (Kurgan Oblast), Maradykovsky (Kirov Oblast), Leonidovka (Penza Oblast) whilst installations are under construction in Pochep (Bryansk Oblast) and Kizner (Udmurt Republic).^[103][104] As August 2013, 76 percent (30,500 tonnes) were destroyed,^[105] and Russia leaves the Cooperative Threat Reduction (CTR) Program, which partially funded chemical weapons destruction.^[106]

United States

On November 25, 1969, President Richard Nixon unilaterally renounced the use of chemical weapons and renounced all methods of biological warfare. He issued a decree halting the production and transport of all chemical weapons which remains in effect. From May 1964 to the early 1970s the USA participated in Operation CHASE, a United States Department of Defense program that aimed to dispose of chemical weapons by sinking ships laden with the weapons in the deep Atlantic. After the Marine Protection, Research, and Sanctuaries Act of 1972, Operation Chase was scrapped and safer disposal methods for chemical weapons were researched, with the U.S. destroying several thousand tons of mustard gas by incineration at the Rocky Mountain Arsenal, and nearly 4,200 tons of nerve agent by chemical neutralisation at Tooele Army Depot.^[107]

The U.S. ratified the Geneva Protocol which banned the use of chemical and biological weapons on January 22, 1975. In 1989 and 1990, the U.S. and the Soviet Union entered an agreement to both end their chemical weapons programs, including binary weapons. In April 1997, the United States ratified the Chemical Weapons Convention, this banned the possession of most types of chemical weapons. It also banned the development of chemical weapons, and required the destruction of existing stockpiles, precursor chemicals, production facilities, and their weapon delivery systems.

The U.S. began stockpile reductions in the 1980s with the removal of outdated munitions and destroying its entire stock of 3-Quinuclidinyl benzilate (BZ or Agent 15) at the beginning of 1988. In June 1990 the Johnston Atoll Chemical Agent Disposal System began destruction of chemical agents stored on the Johnston Atoll in the Pacific, seven years before the Chemical Weapons Treaty came into effect. In 1986 President Ronald Reagan made an agreement with the Chancellor, Helmut Kohl to remove the U.S. stockpile of chemical weapons from Germany. In 1990, as part of Operation Steel Box, two ships were loaded with over 100,000 shells containing Sarin and VX where taken from the U.S. Army weapons storage depots such as Miesau and then-classified FSTS (Forward Storage / Transportation Sites) and transported from Bremerhaven, Germany to Johnston Atoll in the Pacific, a 46-day nonstop journey.^[108]

In May 1991, President George H. W. Bush committed the United States to destroying all of its chemical weapons and renounced the right to chemical weapon retaliation. In 1993, the United States signed the Chemical Weapons Treaty, which required the destruction of all chemical weapon agents, dispersal systems, and production facilities by April 2012. The U.S. prohibition on the transport of chemical weapons has meant that destruction facilities had to be constructed at each of the U.S.'s nine storage facilities. The U.S. met the first three of the four deadlines set out in the treaty, destroying 45% of its stockpile of chemical weapons by 2007. Due to the destruction of chemical weapons, under the United States policy of Proportional Response, an attack upon the United States or its Allies would trigger a force-equivalent counter-attack. Since the United States only maintains nuclear Weapons of Mass Destruction, it is the stated policy that the United States will regard all WMD attacks (Biological, chemical, or nuclear) as a nuclear attack and will respond to such an attack with a nuclear strike.^[109]

As of 2012, stockpiles have been eliminated at 7 of the 9 chemical weapons depots and 89.75% of the 1997 stockpile has been destroyed by the treaty deadline of April 2012.^[110] Destruction will not begin at the two remaining depots until after the treaty deadline and will use neutralization, instead of incineration.

See also

• 1990 Chemical Weapons Accord
• Ali Hassan al-Majid
• Area denial weapon
• Biological warfare
• Chemical Weapons Convention
• Chemical weapon designation
• Chemical weapons and the United Kingdom
• Exotic pollution
• Lethal Unitary Chemical Agents and Munitions
• List of chemical warfare agents
• List of highly toxic gases
• Operation Red Hat
• Ronald Maddison
• Psychochemical weapon
• Saint Julien Memorial
• Sardasht (A town attacked with chemical weapons during the Iran–Iraq War.)
• Stink bomb
• United States Army Medical Research Institute of Chemical Defense
• Weapon of mass destruction
• Zyklon B

Notes

References

• CBWInfo.com (2001). A Brief History of Chemical and Biological Weapons: Ancient Times to the 19th Century. Retrieved Nov. 24, 2004.
• Chomsky, Noam (Mar. 4, 2001). Prospects for Peace in the Middle East, page 2. Lecture.
• Cordette, Jessica, MPH(c) (2003). Chemical Weapons of Mass Destruction. Retrieved Nov. 29, 2004.
• Croddy, Eric (2001), Chemical and Biological Warfare, Copernicus, ISBN 0-387-95076-1 
• Smart, Jeffery K., M.A. (1997). History of Biological and Chemical Warfare. Retrieved Nov. 24, 2004.
• United States Senate, 103d Congress, 2d Session. (May 25, 1994). The Riegle Report. Retrieved Nov. 6, 2004.
• Gerard J Fitzgerald. American Journal of Public Health. Washington: Apr 2008. Vol. 98, Iss. 4; p. 611
• Гречко, А.А. (1976). Годы Войны. Военное Издательство Министерства Оборонны СССР.Москва. 

Further reading

• Leo P. Brophy and George J. B. Fisher; The Chemical Warfare Service: Organizing for War Office of the Chief of Military History, 1959; L. P. Brophy, W. D. Miles and C. C. Cochrane, The Chemical Warfare Service: From Laboratory to Field (1959); and B. E. Kleber and D. Birdsell, The Chemical Warfare Service in Combat (1966). official US history;
• Gordon M. Burck and Charles C. Flowerree; International Handbook on Chemical Weapons Proliferation 1991
• L. F. Haber. The Poisonous Cloud: Chemical Warfare in the First World War Oxford University Press: 1986
• James W. Hammond Jr; Poison Gas: The Myths Versus Reality Greenwood Press, 1999
• Jiri Janata, Role of Analytical Chemistry in Defense Strategies Against Chemical and Biological Attack, Annual Review of Analytical Chemistry, 2009
• Ishmael Jones, The Human Factor: Inside the CIA's Dysfunctional Intelligence Culture, Encounter Books, New York 2008, revised 2010, ISBN 978-1-59403-382-7. WMD espionage.
• Benoit Morel and Kyle Olson; Shadows and Substance: The Chemical Weapons Convention Westview Press, 1993
• Adrienne Mayor, "Greek Fire, Poison Arrows & Scorpion Bombs: Biological and Chemical Warfare in the Ancient World" Overlook-Duckworth, 2003, rev ed with new Introduction 2008
• Geoff Plunkett, Chemical Warfare in Australia: Australia's Involvement In Chemical Warfare 1914 - Today, (2nd Edition), 2013.. Leech Cup Books. A volume in the Army Military History Series published in association with the Army History Unit.
• Jonathan B. Tucker. Chemical Warfare from World War I to Al-Qaeda (2006)

External links

Wikimedia Commons has media related to Chemical warfare.

• Chemical weapons and international humanitarian law
• ATSDR Case Studies in Environmental Medicine: Cholinesterase Inhibitors, Including Insecticides and Chemical Warfare Nerve Agents U.S. Department of Health and Human Services
• Russian Biological and Chemical Weapons, about the danger posed by non-state weapons transfers
• Gaddum Papers at the Royal Society
• Chemical Weapons stored in the United States
• The Organisation for the Prohibition of Chemical Weapons OPCW
• Chemical Warfare in Australia
• Classes of Chemical Agents U.S. National Library of Medicine
• Chemical warfare agent potency, logistics, human damage, dispersal, protection and types of agents (bomb-shelter.net)
• "'War of Nerves': A History of Chemical Weapons" (interview with Jonathan Tucker from National Public Radio Talk of the Nation program, May 8, 2006
• Chemical weapons in World War II
• "Our Army's Defense Against Poison Gas". Popular Science, February 1945, pp. 106–111.

Agents used in chemical warfare incapacitation riot control Blood Cyanogen chloride (CK) Hydrogen cyanide (AC) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite (L) Sulfur mustard (HD H HT HL HQ) Nitrogen mustard HN1 HN2 HN3 Nerve G-agents Tabun (GA) Sarin (GB) Soman (GD) Cyclosarin (GF) GV Methyl fluorophosphoryl homocholine iodide (MFPhCh) V-agents EA-3148 VE VG VM VP VR VX Novichok agents Nettle Phosgene oxime (CX) Pulmonary Chlorine Chloropicrin (PS) Phosgene (CG) Diphosgene (DP) Disulfur decafluoride Incapacitating Agent 15 (BZ) Dimethylheptylpyran (DMHP) EA-3167 Kolokol-1 LSD-25 PAVA spray Sleeping gas Riot control Pepper spray (OC) CS CN (mace) CR List of chemical warfare agents