Barium ferrate
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| Names | |||
|---|---|---|---|
| IUPAC name
Barium ferrate(VI) | |||
| Other names
Barium ferrate(2-) | |||
| Identifiers | |||
13773-23-4  | |||
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| Properties | |||
| BaFeO4 | |||
| Molar mass | 257.17 g·mol−1 | ||
| Appearance | Dark red, opaque crystals | ||
| insoluble | |||
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
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| Infobox references | |||
Barium ferrate is the chemical compound of formula BaFeO4. This compound contains iron in the +6 oxidation state.[1] It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.[2]
Preparation and chemistry
Anhydrous barium ferrate can be prepared by precipitation from a solution containing potassium ferrate and barium chloride.[3] Barium ferrate is an oxidising agent and has been proposed as an oxidising reagent for use in organic syntheses.[4]
References
- ↑ J. G. R. Briggs (2005). Longman A-level course in chemistry (4th ed.). Pearson Education South Asia. p. 536. ISBN 981-4105-08-2.
- ↑ Wells, A.F. (1986). Structural inorganic chemistry (5th ed.). Oxford [Oxfordshire]: Clarendon Press. ISBN 0-19-855370-6.
- ↑ Gump, J. R.; Wagner, W. F.; Schreyer, J. M. (1 December 1954). "Preparation and Analysis of Barium Ferrate(VI)". Analytical Chemistry 26 (12): 1957–1957. doi:10.1021/ac60096a027.
- ↑ Firouzabadi, H.; Mohajer, D.; Entezari-moghaddam, M. "Barium Ferrate Monohydrate BaFeO4·H2O, A Versatile Reagent for the Oxidation of Organic Compounds under Aprotic Condiiton". Synthetic Communications 16 (6): 723–731. doi:10.1080/00397918608057745.
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