Ammonium uranyl carbonate

Ammonium uranyl carbonate

Names
IUPAC name uranium(VI)dioxide di-ammonium carbonate
Other names uranyl ammonium carbonate
Properties
Chemical formula	UO2CO3·2(NH4)2CO3
Molar mass	522.199 g/mol
Melting point	Decomposes between 165 °C and 185 °C
Solubility in water	Insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Ammonium uranyl carbonate (UO₂CO₃·2(NH₄)₂CO₃) is known in the uranium processing industry as AUC and is also called uranyl ammonium carbonate. This compound is important as a component in the conversion process of uranium hexafluoride (UF₆) to uranium dioxide (UO₂). The ammonium uranyl carbonate is combined with steam and hydrogen at 500–600 °C to yield UO₂. In another process aqueous uranyl nitrate, known as uranyl nitrate liquor (UNL) is treated with ammonium bicarbonate to form ammonium uranyl carbonate as a solid precipitate. This is separated from the solution, dried with methanol and then calcinated with hydrogen directly to UO₂ to obtain a sinterable grade powder. The ex-AUC uranium dioxide powder is free-flowing, relatively coarse (10 µ) and porous with specific surface area in the range of 5 m²/g and suitable for direct pelletisation, avoiding the granulation step. Conversion to UO₂ is often performed as the first stage of nuclear fuel fabrication.

The AUC process is followed in South Korea and Argentina. In the AUC route, calcination, reduction and stabilization are simultaneously carried out in a vertical fluidized bed reactor. In most countries, sinterable grade UO₂ powder for nuclear fuel is obtained by the ammonium diuranate (ADU) process, which requires several more steps.

Ammonium uranyl carbonate is also one of the many forms called yellowcake; in this case it is the product obtained by the heap leach process.

References