Tris(tert-butoxy)silanethiol
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Names | |||
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IUPAC name
Tris(tert-butoxy)silanethiol | |||
Other names
Tri(tert-butoxy)silanethiol | |||
Identifiers | |||
Abbreviations | TBST | ||
690-52-8 | |||
ChemSpider | 4414610 | ||
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Jmol-3D images | Image | ||
PubChem | 5246420 | ||
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Properties | |||
Molecular formula |
C12H28O3SSi | ||
Molar mass | 280.50 g·mol−1 | ||
Appearance | Colourless liquid | ||
Boiling point | 113 to 115 °C (235 to 239 °F; 386 to 388 K) at 35 mmHg | ||
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |||
Infobox references | |||
Tris(tert-butoxy)silanethiol is a silicon compound containing three tert-butoxy groups and a rare Si-S-H functional group. This colourless compound serves as an hydrogen donor in radical chain reactions. It is prepared by alcoholysis of silicon disulfide and purified by distillation:
- 3 (CH3)3COH + SiS2 → [(CH3)3CO]3SiSH + H2S