Isotopes of osmium
Osmium (Os) has seven naturally occurring isotopes, 6 of which are stable: 184Os, 187Os, 188Os, 189Os, 190Os, and (most abundant) 192Os. The other natural isotope, 186Os, has an extremely long half-life (2×1015 years) and for practical purposes can be considered to be stable as well. 187Os is the daughter of 187Re (half-life 4.56×1010 years) and is most often measured in an 187Os/188Os ratio. This ratio, as well as the 187Re/188Os ratio, have been used extensively in dating terrestrial as well as meteoric rocks. It has also been used to measure the intensity of continental weathering over geologic time and to fix minimum ages for stabilization of the mantle roots of continental cratons. However, the most notable application of Os in dating has been in conjunction with iridium, to analyze the layer of shocked quartz along the Cretaceous–Paleogene boundary that marks the extinction of the dinosaurs 66 million years ago.
There are also 29 artificial radioisotopes,[1] the longest-lived of which is 194Os with a half-life of 6 years, all others have half-lives under 94 days. There are also 9 known nuclear isomers, the longest-lived of which is 191mOs with a half-life of 13.10 hours.
Standard atomic mass: 190.23(3) u
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life[n 1] | decay mode(s)[2][n 2] |
daughter isotope(s)[n 3] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
162Os | 76 | 86 | 161.98443(54)# | 1.87(18) ms | α | 158W | 0+ | ||
163Os | 76 | 87 | 162.98269(43)# | 5.5(6) ms | α | 159W | 7/2-# | ||
β+, p (rare) | 162W | ||||||||
β+ (rare) | 163Re | ||||||||
164Os | 76 | 88 | 163.97804(22) | 21(1) ms | α (98%) | 160W | 0+ | ||
β+ (2%) | 164Re | ||||||||
165Os | 76 | 89 | 164.97676(22)# | 71(3) ms | α (60%) | 161W | (7/2-) | ||
β+ (40%) | 165Re | ||||||||
166Os | 76 | 90 | 165.972691(20) | 216(9) ms | α (72%) | 162W | 0+ | ||
β+ (28%) | 166Re | ||||||||
167Os | 76 | 91 | 166.97155(8) | 810(60) ms | α (67%) | 163W | 3/2-# | ||
β+ (33%) | 167Re | ||||||||
168Os | 76 | 92 | 167.967804(13) | 2.06(6) s | β+ (51%) | 168Re | 0+ | ||
α (49%) | 164W | ||||||||
169Os | 76 | 93 | 168.967019(27) | 3.40(9) s | β+ (89%) | 169Re | 3/2-# | ||
α (11%) | 165W | ||||||||
170Os | 76 | 94 | 169.963577(12) | 7.46(23) s | β+ (91.4%) | 170Re | 0+ | ||
α (8.6%) | 176W | ||||||||
171Os | 76 | 95 | 170.963185(20) | 8.3(2) s | β+ (98.3%) | 171Re | (5/2-) | ||
α (1.7%) | 167W | ||||||||
172Os | 76 | 96 | 171.960023(16) | 19.2(5) s | β+ (98.9%) | 172Re | 0+ | ||
α (1.1%) | 168W | ||||||||
173Os | 76 | 97 | 172.959808(16) | 22.4(9) s | β+ (99.6%) | 173Re | (5/2-) | ||
α (.4%) | 169W | ||||||||
174Os | 76 | 98 | 173.957062(12) | 44(4) s | β+ (99.97%) | 174Re | 0+ | ||
α (.024%) | 170W | ||||||||
175Os | 76 | 99 | 174.956946(15) | 1.4(1) min | β+ | 175Re | (5/2-) | ||
176Os | 76 | 100 | 175.95481(3) | 3.6(5) min | β+ | 176Re | 0+ | ||
177Os | 76 | 101 | 176.954965(17) | 3.0(2) min | β+ | 177Re | 1/2- | ||
178Os | 76 | 102 | 177.953251(18) | 5.0(4) min | β+ | 178Re | 0+ | ||
179Os | 76 | 103 | 178.953816(19) | 6.5(3) min | β+ | 179Re | (1/2-) | ||
180Os | 76 | 104 | 179.952379(22) | 21.5(4) min | β+ | 180Re | 0+ | ||
181Os | 76 | 105 | 180.95324(3) | 105(3) min | β+ | 181Re | 1/2- | ||
181m1Os | 48.9(2) keV | 2.7(1) min | β+ | 181Re | (7/2)- | ||||
181m2Os | 156.5(7) keV | 316(18) ns | (9/2)+ | ||||||
182Os | 76 | 106 | 181.952110(23) | 22.10(25) h | EC | 182Re | 0+ | ||
183Os | 76 | 107 | 182.95313(5) | 13.0(5) h | β+ | 183Re | 9/2+ | ||
183mOs | 170.71(5) keV | 9.9(3) h | β+ (85%) | 183Re | 1/2- | ||||
IT (15%) | 183Os | ||||||||
184Os | 76 | 108 | 183.9524891(14) | Observationally Stable[n 4] | 0+ | 2(1)×10−4 | |||
185Os | 76 | 109 | 184.9540423(14) | 93.6(5) d | EC | 185Re | 1/2- | ||
185m1Os | 102.3(7) keV | 3.0(4) µs | (7/2-)# | ||||||
185m2Os | 275.7(8) keV | 0.78(5) µs | (11/2+) | ||||||
186Os[n 5] | 76 | 110 | 185.9538382(15) | 2.0(11)×1015 a | α | 182W | 0+ | 0.0159(3) | |
187Os[n 6] | 76 | 111 | 186.9557505(15) | Observationally Stable[n 7] | 1/2- | 0.0196(2) | |||
188Os[n 6] | 76 | 112 | 187.9558382(15) | Observationally Stable[n 8] | 0+ | 0.1324(8) | |||
189Os | 76 | 113 | 188.9581475(16) | Observationally Stable[n 9] | 3/2- | 0.1615(5) | |||
189mOs | 30.812(15) keV | 5.81(6) h | IT | 189Os | 9/2- | ||||
190Os | 76 | 114 | 189.9584470(16) | Observationally Stable[n 10] | 0+ | 0.2626(2) | |||
190mOs | 1705.4(2) keV | 9.9(1) min | IT | 190Os | (10)- | ||||
191Os | 76 | 115 | 190.9609297(16) | 15.4(1) d | β− | 191Ir | 9/2- | ||
191mOs | 74.382(3) keV | 13.10(5) h | IT | 191Os | 3/2- | ||||
192Os | 76 | 116 | 191.9614807(27) | Observationally Stable[n 11] | 0+ | 0.4078(19) | |||
192mOs | 2015.40(11) keV | 5.9(1) s | IT (87%) | 192Os | (10-) | ||||
β− (13%) | 192Ir | ||||||||
193Os | 76 | 117 | 192.9641516(27) | 30.11(1) h | β− | 193Ir | 3/2- | ||
194Os | 76 | 118 | 193.9651821(28) | 6.0(2) a | β− | 194Ir | 0+ | ||
195Os | 76 | 119 | 194.96813(54) | 6.5 min | β− | 195Ir | 3/2-# | ||
196Os | 76 | 120 | 195.96964(4) | 34.9(2) min | β− | 196Ir | 0+ | ||
197Os | 76 | 121 | 2.8(6) min |
- ↑ Bold for isotopes with half-lives longer than the age of the universe (nearly stable)
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes, bold italics for nearly stable isotopes (half-life longer than the age of the universe)
- ↑ Believed to undergo α decay to 180W or β+β+ decay to 184W with a half-life over 56×1012 years
- ↑ primordial radionuclide
- ↑ 6.0 6.1 Used in rhenium-osmium dating
- ↑ Believed to undergo α decay to 183W
- ↑ Believed to undergo α decay to 184W
- ↑ Believed to undergo α decay to 185W
- ↑ Believed to undergo α decay to 186W
- ↑ Believed to undergo α decay to 188W or β−β− decay to 192Pt with a half-life over 9.8×1012 years
Notes
- Evaluated isotopic composition is for most but not all commercial samples.
- The precision of the isotope abundances and atomic mass is limited through variations. The given ranges should be applicable to any normal terrestrial material.
- Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
References
- ↑ FLEGENHEIMER, J. (2014). The mystery of the disappearing isotope. Revista Virtual de Química, V. XX. Available at http://www.uff.br/RVQ/index.php/rvq/article/viewFile/660/450
- ↑ http://www.nucleonica.net/unc.aspx
- Isotope masses from:
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of rhenium | Isotopes of osmium | Isotopes of iridium |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
|