Isotopes of iridium
There are two natural isotopes of iridium (Ir), and 34 radioisotopes, the most stable radioisotope being 192Ir with a half-life of 73.83 days, and many nuclear isomers, the most stable of which is 192m2Ir with a half-life of 241 years, all other isomers have half-lives under a year, most under a day.
Standard atomic mass: 192.217(3) u
Iridium-192
Iridium-192 (symbol 192Ir) is a radioactive isotope of iridium, with a half-life of 73.83 days.[1] It decays by emitting beta (β) particles and gamma (γ) radiation. About 96% of 192Ir decays occur via emission of β and γ radiation, leading to 192Pt. Some of the β particles are captured by other 192Ir nuclei, which are then converted to 192Os. Electron capture is responsible for the remaining 4% of 192Ir decays.[2]
Iridium-192 is also a strong gamma ray emitter. There are seven principal energy packets produced during its disintegration process ranging from just over 0.2 to about 0.6 MeV. Iridium-192 is commonly used as a gamma ray source in industrial radiography to locate flaws in metal components.[3] It is also used in radiotherapy as a radiation source, in particular in brachytherapy.
Iridium-192 has accounted for the majority of cases tracked by the US Nuclear Regulatory Commission in which radioactive materials have gone missing in quantities large enough to make a dirty bomb.[4]
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[5][n 1] |
daughter isotope(s)[n 2] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
164Ir | 77 | 87 | 163.99220(44)# | 1# ms | 2-# | ||||
164mIr | 270(110)# keV | 94(27) µs | 9+# | ||||||
165Ir | 77 | 88 | 164.98752(23)# | <1# µs | p | 164Os | 1/2+# | ||
α (rare) | 161Re | ||||||||
165mIr | 180(50)# keV | 300(60) µs | p (87%) | 164Os | 11/2- | ||||
α (13%) | 161Re | ||||||||
166Ir | 77 | 89 | 165.98582(22)# | 10.5(22) ms | α (93%) | 162Re | (2-) | ||
p (7%) | 165Os | ||||||||
166mIr | 172(6) keV | 15.1(9) ms | α (98.2%) | 162Re | (9+) | ||||
p (1.8%) | 165Os | ||||||||
167Ir | 77 | 90 | 166.981665(20) | 35.2(20) ms | α (48%) | 163Re | 1/2+ | ||
p (32%) | 166Os | ||||||||
β+ (20%) | 167Os | ||||||||
167mIr | 175.3(22) keV | 30.0(6) ms | α (80%) | 163Re | 11/2- | ||||
β+ (20%) | 167Os | ||||||||
p (.4%) | 166Os | ||||||||
168Ir | 77 | 91 | 167.97988(16)# | 161(21) ms | α | 164Re | high | ||
β+ (rare) | 168Os | ||||||||
168mIr | 50(100)# keV | 125(40) ms | α | 164Re | low | ||||
169Ir | 77 | 92 | 168.976295(28) | 780(360) ms [0.64(+46-24) s] |
α | 165Re | 1/2+# | ||
β+ (rare) | 169Os | ||||||||
169mIr | 154(24) keV | 308(22) ms | α (72%) | 165Re | 11/2-# | ||||
β+ (28%) | 169Os | ||||||||
170Ir | 77 | 93 | 169.97497(11)# | 910(150) ms [0.87(+18-12) s] |
β+ (64%) | 170Os | low# | ||
α (36%) | 166Re | ||||||||
170mIr | 270(70)# keV | 440(60) ms | high# | ||||||
171Ir | 77 | 94 | 170.97163(4) | 3.6(10) s [3.2(+13-7) s] |
α (58%) | 167Re | 1/2+# | ||
β+ (42%) | 171Os | ||||||||
171mIr | 180(30)# keV | 1.40(10) s | (11/2-) | ||||||
172Ir | 77 | 95 | 171.97046(11)# | 4.4(3) s | β+ (98%) | 172Os | (3+) | ||
α (2%) | 168Re | ||||||||
172mIr | 280(100)# keV | 2.0(1) s | β+ (77%) | 172Os | (7+) | ||||
α (23%) | 168Re | ||||||||
173Ir | 77 | 96 | 172.967502(15) | 9.0(8) s | β+ (93%) | 173Os | (3/2+,5/2+) | ||
α (7%) | 169Re | ||||||||
173mIr | 253(27) keV | 2.20(5) s | β+ (88%) | 173Os | (11/2-) | ||||
α (12%) | 169Re | ||||||||
174Ir | 77 | 97 | 173.966861(30) | 7.9(6) s | β+ (99.5%) | 174Os | (3+) | ||
α (.5%) | 170Re | ||||||||
174mIr | 193(11) keV | 4.9(3) s | β+ (99.53%) | 174Os | (7+) | ||||
α (.47%) | 170Re | ||||||||
175Ir | 77 | 98 | 174.964113(21) | 9(2) s | β+ (99.15%) | 175Os | (5/2-) | ||
α (.85%) | 171Re | ||||||||
176Ir | 77 | 99 | 175.963649(22) | 8.3(6) s | β+ (97.9%) | 176Os | |||
α (2.1%) | 172Re | ||||||||
177Ir | 77 | 100 | 176.961302(21) | 30(2) s | β+ (99.94%) | 177Os | 5/2- | ||
α (.06%) | 173Re | ||||||||
178Ir | 77 | 101 | 177.961082(21) | 12(2) s | β+ | 178Os | |||
179Ir | 77 | 102 | 178.959122(12) | 79(1) s | β+ | 179Os | (5/2)- | ||
180Ir | 77 | 103 | 179.959229(23) | 1.5(1) min | β+ | 180Os | (4,5)(+#) | ||
181Ir | 77 | 104 | 180.957625(28) | 4.90(15) min | β+ | 181Os | (5/2)- | ||
182Ir | 77 | 105 | 181.958076(23) | 15(1) min | β+ | 182Os | (3+) | ||
183Ir | 77 | 106 | 182.956846(27) | 57(4) min | β+ ( 99.95%) | 183Os | 5/2- | ||
α (.05%) | 179Re | ||||||||
184Ir | 77 | 107 | 183.95748(3) | 3.09(3) h | β+ | 184Os | 5- | ||
184m1Ir | 225.65(11) keV | 470(30) µs | 3+ | ||||||
184m2Ir | 328.40(24) keV | 350(90) ns | (7)+ | ||||||
185Ir | 77 | 108 | 184.95670(3) | 14.4(1) h | β+ | 185Os | 5/2- | ||
186Ir | 77 | 109 | 185.957946(18) | 16.64(3) h | β+ | 186Os | 5+ | ||
186mIr | 0.8(4) keV | 1.92(5) h | β+ | 186Os | 2- | ||||
IT (rare) | 186Ir | ||||||||
187Ir | 77 | 110 | 186.957363(7) | 10.5(3) h | β+ | 187Os | 3/2+ | ||
187m1Ir | 186.15(4) keV | 30.3(6) ms | IT | 187Ir | 9/2- | ||||
187m2Ir | 433.81(9) keV | 152(12) ns | 11/2- | ||||||
188Ir | 77 | 111 | 187.958853(8) | 41.5(5) h | β+ | 188Os | 1- | ||
188mIr | 970(30) keV | 4.2(2) ms | IT | 188Ir | 7+# | ||||
β+ (rare) | 188Os | ||||||||
189Ir | 77 | 112 | 188.958719(14) | 13.2(1) d | EC | 189Os | 3/2+ | ||
189m1Ir | 372.18(4) keV | 13.3(3) ms | IT | 189Ir | 11/2- | ||||
189m2Ir | 2333.3(4) keV | 3.7(2) ms | (25/2)+ | ||||||
190Ir | 77 | 113 | 189.9605460(18) | 11.78(10) d | β+ | 190Os | 4- | ||
190m1Ir | 26.1(1) keV | 1.120(3) h | IT | 190Ir | (1-) | ||||
190m2Ir | 36.154(25) keV | >2 µs | (4)+ | ||||||
190m3Ir | 376.4(1) keV | 3.087(12) h | (11)- | ||||||
191Ir | 77 | 114 | 190.9605940(18) | Observationally Stable[n 3] | 3/2+ | 0.373(2) | |||
191m1Ir | 171.24(5) keV | 4.94(3) s | IT | 191Ir | 11/2- | ||||
191m2Ir | 2120(40) keV | 5.5(7) s | |||||||
192Ir | 77 | 115 | 191.9626050(18) | 73.827(13) d | β− (95.24%) | 192Pt | 4+ | ||
EC (4.76%) | 192Os | ||||||||
192m1Ir | 56.720(5) keV | 1.45(5) min | 1- | ||||||
192m2Ir | 168.14(12) keV | 241(9) a | (11-) | ||||||
193Ir | 77 | 116 | 192.9629264(18) | Observationally Stable[n 4] | 3/2+ | 0.627(2) | |||
193mIr | 80.240(6) keV | 10.53(4) d | IT | 193Ir | 11/2- | ||||
194Ir | 77 | 117 | 193.9650784(18) | 19.28(13) h | β− | 194Pt | 1- | ||
194m1Ir | 147.078(5) keV | 31.85(24) ms | IT | 194Ir | (4+) | ||||
194m2Ir | 370(70) keV | 171(11) d | (10,11)(-#) | ||||||
195Ir | 77 | 118 | 194.9659796(18) | 2.5(2) h | β− | 195Pt | 3/2+ | ||
195mIr | 100(5) keV | 3.8(2) h | β− (95%) | 195Pt | 11/2- | ||||
IT (5%) | 195Ir | ||||||||
196Ir | 77 | 119 | 195.96840(4) | 52(1) s | β− | 196Pt | (0-) | ||
196mIr | 210(40) keV | 1.40(2) h | β− (99.7%) | 196Pt | (10,11-) | ||||
IT | 196Ir | ||||||||
197Ir | 77 | 120 | 196.969653(22) | 5.8(5) min | β− | 197Pt | 3/2+ | ||
197mIr | 115(5) keV | 8.9(3) min | β− (99.75%) | 197Pt | 11/2- | ||||
IT (.25%) | 197Ir | ||||||||
198Ir | 77 | 121 | 197.97228(21)# | 8(1) s | β− | 198Pt | |||
199Ir | 77 | 122 | 198.97380(4) | 20# s | β− | 199Pt | 3/2+# |
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes, bold italics for nearly-stable isotopes (half-life longer than the age of the universe)
- ↑ Believed to undergo α decay to 187Re
- ↑ Believed to undergo α decay to 189Re
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
References
- ↑ "Radioisotope Brief: Iridium-192 (Ir-192)". Retrieved 20 March 2012.
- ↑ Braggerly, L.L. (1956). The radioactive decay of Iridium-192 (Pd.D. Thesis). Pasadena, CA: California Institute of Technology. pp. 1, 2, 7.
- ↑ Charles Hellier (2003). Handbook of Nondestructive Evaluation. McGraw-Hill. p. 6.20. ISBN 0-07-028121-1.
- ↑ Steve Coll (March 12, 2007). "The Unthinkable". The New Yorker. Retrieved 2007-03-09.
- ↑ Added info from http://www.nucleonica.net/unc.aspx
- Isotope masses from:
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
External links
- NLM Hazardous Substances Databank – Iridium, Radioactive (referring to iridium-192)
Isotopes of osmium | Isotopes of iridium | Isotopes of platinum |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
|