Eudialyte group
Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups.[1] Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.[2]
List of the eudialyte-group minerals
- Alluaivite - Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl.2H2O
- Andrianovite - Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi(Si3O9)2(Si9O27)2O(O,H2O,OH)5
- Aqualite - (H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9Cl
- Carbokentbrooksite - (Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3).H2O
- Dualite - Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn(Si51O144)(OH,H2O,Cl)9
- Eudialyte - Na15Ca6(Fe,Mn)3Zr3(Si3O9)2SiO(Si9O27)2(O,OH,H2O)3(OH,Cl)2
- Feklichevite - Na11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5
- Ferrokentbrooksite - Na15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3(Cl,F,OH)2
- Georgbarsanovite - Na12(Mn,Sr,REE)3Ca6Fe3Zr3NbSi25O76Cl2.H2O
- Golyshevite - (Na10Ca3)Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2(OH)3(CO3).H2O
- Ikranite - (Na,H3O)15(Ca,Mn)6Fe3+2Zr3-4SiO(Si3O9)2(Si9O27)2.2-3H2O
- Johnsenite-(Ce) - Na12(Ce,La,Sr,Ca)3Ca6Mn3Zr3WSiO(Si3O9)2(Si9O27)2(CO3)(OH,Cl)2.H2O
- Kentbrooksite - (Na,REE)15(Ca,REE)6(Mn,Fe)3Zr3(Si3O9)2SiO(Si9O27)2(O,OH,H2O)3F2.2H2O
- Khomyakovite - Na12Sr3Ca6Fe3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2
- Labyrinthite - (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3
- Manganokhomyakovite - Na12Sr3Ca6Mn3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2
- Mogovidite - Na9(Ca,Na)5Ca6Zr3Fe2(SiNb)(Si3O9)2(Si9O27)2(CO3)(OH,H2O)3Cl0.3
- Oneillite - Na15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2
- Raslakite - Na15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5SiO(Si3O9)2(Si9O27)2(OH,H2O)3(Cl,OH)
- Rastsvetaevite - Na27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2
- Taseqite - Na12Sr3Ca6Fe3Zr3NbSiO(Si3O9)2(Si9O27)2(O,OH,H2O)3Cl2
- Voronkovite - Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl.H2O
- Zirsilite-(Ce) - (Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3).H2O
Further reading
- Ageeva, O. A.; Borutzky, B. Ye; Chukanov, N. V.; Sokolova, M. N. (2002). "Alluaivite and genetic aspect of the forming of enriched in Ti eudialytes in Khibiny massif". Zapiski Vserossijskogo mineralogičeskogo obŝestva 131 (1): 99–106. INIST:13846139.
- Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.; Rozenberg, K. A. (2009). "Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O, H2O,OH)5, a new potassium-rich mineral species of the eudialyte group from the Khibiny alkaline Pluton, Kola Peninsula, Russia". Geology of Ore Deposits 50 (8): 705–12. Bibcode:2008GeoOD..50..705K. doi:10.1134/S1075701508080060.
- Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K. (2007). "Aqualite, a new mineral species of the eudialyte group from the Inagli alkaline pluton, Sakha-Yakutia, Russia, and the problem of oxonium in hydrated eudialytes". Geology of Ore Deposits 49 (8): 739–51. Bibcode:2007GeoOD..49..739K. doi:10.1134/S1075701507080089.
- Khomyakov, A. P.; Dusmatov, V. D.; G.; Gula, A.; Ivaldi, G.; Nechelyustov, G. N. (2003). "Zapiski Vserossijskogo mineralogičeskogo obŝestva" 132 (5). pp. 40–51. INIST:15861098.
- Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K. (2007). "Dualite, Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3MnSi51O144(OH,H2O,Cl)9, a new zircono-titanosilicate with a modular eudialyte-like structure from Lovozero alkaline massif, Kola Peninsula, Russia". Zapiski Vserossijskogo mineralogičeskogo obŝestva 136 (4): 31–42. INIST:20451408.
- Rozenberg, K. A.; Rastsvetaeva, R. K.; Chukanov, N. V.; Verin, I. A. (2005). "Crystal structure of a niobium-deficient carbonate analogue of feklichevite". Doklady Chemistry 400 (4–6): 25–9. doi:10.1007/s10631-005-0014-5.
- Rozenberg, K. A.; Rastsvetaeva, R. K.; Chukanov, N. V.; Verin, I. A. (2005). "Crystal structure of golyshevite". Crystallography Reports 50 (4): 539–43. Bibcode:2005CryRp..50..539R. doi:10.1134/1.1996727.
- Johnsen, O.; Grice, J. D.; Gault, R. A. (2003). "Ferrokentbrooksite, A New Member of the Eudialyte Group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist 41 (1): 55–60. doi:10.2113/gscanmin.41.1.55.
- Piilonen, Paula C.; Locock, Andrew J.; Rowe, Ralph; Ercit, T. Scott (2007). "New Mineral Names" (PDF). American Mineralogist 92 (4): 703–7. doi:10.2138/am.2007.488.
- Chukanov, N. V.; Pekov, I. V.; Zadov, A. E.; Korovushkin, V. V.; Ekimenkova, I. A.; Rastsvetaeva, R. K. (2003). "Ikranite (Na,H3O)15(Ca,Mn,REE)6Fe3+2Zr3(□,Zr)(□,Si)Si24O66(O,OH)6Cl·nH2О and raslakite Na15Ca3Fe3(Na,Zr)3Zr3(Si,Nb)(Si25O73)(OH,H2O)3(Cl,OH) - the new eudialyte-group minerals from Lovozero massif, Kola Peninsula". Zapiski Vserossijskogo mineralogičeskogo obŝestva 132 (5): 22–33. INIST:15861096.
- Grice, Joel D.; Gault, Robert A. (2006). "Johnsenite-(Ce) : A new member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist 44 (1): 105–15. doi:10.2113/gscanmin.44.1.105. INIST:17777968.
- Jambor, John L.; Kovalenker, Vladimir A.; Roberts, Andrew C. (2000). "New Mineral Names" (PDF). American Mineralogist 85: 873–7.
- Khomyakov, A. P.; Nechelyustov, G. N.; Rastvetaeva, R. K. (2006). "Labyrinthite (Na,K,Sr)35Ca12Fe3Zr6TiSi51·O144(O,OH,H2O)9Cl3, a new mineral with the modular eudialyte-like structure from Khibiny alkaline massif, Kola Peninsula Russia". Zapiski Vserossijskogo mineralogičeskogo obŝestva 135 (2): 38–49. INIST:18813948.
- Ercit, T. Scott; Piilonen, Paula C.; Rowe, Ralph (2007). "New Mineral Names" (PDF). American Mineralogist 92 (8–9): 1539–42. doi:10.2138/am.2007.499.
- Johnsen, Ole; Grice, Joel D.; Gault, Robert A. (1999). "Oneillite: a new Ca-deficient and REE-rich member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist 37: 1295–301.
- Khomyakov, A. P.; Nechelyustov, G. N.; Arakcheeva, A. V. (2006). "Rastsvetaevite Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]34(О,ОН,Н2О) 6Сl2, a new mineral with a modular eudialyte-like structure and crystal-chemical systematics of the eudialyte group". Zapiski Vserossijskogo mineralogičeskogo obŝestva 135 (1): 49–65. INIST:18813995.
- Petersen, O. V.; Johnsen, O.; Gault, R. A.; Niedermayr, G.; Grice, J. D. (2004). "Taseqite, a new member of the eudialyte group from the Ilímaussaq alkaline complex, South Greenland". Neues Jahrbuch für Mineralogie - Monatshefte 2004 (2): 83–96. doi:10.1127/0028-3649/2004/2004-0083. INIST:15422915.
References
- ↑ Johnsen, O.; Ferraris, G.; Gault, R. A.; Grice, J. D.; Kampf, A. R.; Pekov, I. V. (2003). "The Nomenclature of Eudialyte-Group Minerals". The Canadian Mineralogist 41 (3): 785. doi:10.2113/gscanmin.41.3.785.
- ↑ Zubkova, Natalia V.; Pushcharovsky, Dmitrii Yu. (2008). "Mixed-Framework Microporous Natural Zirconosilicates : Minerals as Advanced Materials I". p. 45. doi:10.1007/978-3-540-77123-4_6. ISBN 978-3-540-77122-7.