Cornwallite
| Cornwallite | |
|---|---|
|
Cornwallite in a vug from Pastrana, Murcia, Spain (size: 4.3 x 3.7 x 2.2 cm) | |
| General | |
| Category | Arsenate mineral |
| Formula (repeating unit) | Cu5(AsO4)2(OH)4 |
| Strunz classification | 8.BD.05 |
| Dana classification | 41.4.2.2 |
| Crystal symmetry |
Monoclinic prismatic H-M symbol: 2/m Space group: P21/a |
| Unit cell | a = 17.33 Å, b = 5.82 Å, c = 4.60 Å; β = 92.22°; Z=2 |
| Identification | |
| Color | Verdigis green, blackish-green, emerald-green |
| Crystal habit | Microcrystalline radial fibrous, botryoidal to globular crusts |
| Crystal system | Monoclinic |
| Cleavage | Distinct in one direction |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 4.5 |
| Luster | Sub-vitreous, resinous, waxy |
| Streak | Apple green |
| Diaphaneity | Translucent to opaque |
| Specific gravity | 4.17 |
| Optical properties | Biaxial (+/-) |
| Refractive index | nα = 1.810 - 1.820 nβ = 1.815 - 1.860 nγ = 1.850 - 1.880 |
| Birefringence | δ = 0.040 - 0.060 |
| 2V angle | Measured: 30° to 50° |
| References | [1][2][3] |
Cornwallite is an uncommon copper arsenate mineral with formula Cu5(AsO4)2(OH)4. It forms a series with the phosphate pseudomalachite and is a dimorph of the triclinic cornubite. It is a green monoclinic mineral which forms as radial to fibrous encrustations.
Discovery and occurrence
It was first described in 1846 for an occurrence in Wheal Gorland, St Day United Mines of the St Day District, Cornwall, England.[2] It occurs as a secondary mineral in the oxidized zone of copper sulfide deposits. Associated minerals include olivenite, cornubite, arthurite, clinoclase, chalcophyllite, strashimirite, lavendulan, tyrolite, spangolite, austinite, conichalcite, brochantite, azurite and malachite.[1]