Copaene

Copaene
Names
(−)-α-Copaene
(−)-β-Copaene
IUPAC name α: (1R,2S,6S,7S,8S)-8-isopropyl-1,3-dimethyltricyclo[4.4.0.0^2,7]dec-3-ene
Identifiers
CAS Registry Number	3856-25-5 (α)^Y 317819-78-6 (β)^N
ChemSpider	10231594 (α)^Y
InChI InChI=1S/C15H24/c1-9(2)11-7-8-15(4)12-6-5-10(3)14(15)13(11)12/h5,9,11-14H,6-8H2,1-4H3/t11-,12-,13-,14+,15+/m0/s1 (α)^Y Key: VLXDPFLIRFYIME-BTFPBAQTSA-N^Y InChI=1/C15H24/c1-9(2)11-7-8-15(4)12-6-5-10(3)14(15)13(11)12/h5,9,11-14H,6-8H2,1-4H3/t11-,12-,13-,14+,15+/m0/s1 (α) Key: VLXDPFLIRFYIME-BTFPBAQTBX
Jmol-3D images	Image (α)
SMILES CC(C)[C@@H]1CC[C@@]3(C)[C@@H]2C(/C)=C\C[C@H]3[C@H]12 (α)
UNII	0V56HXQ8N5 (α)^N FDX76373XC (β)^N
Properties
Molecular formula	C₁₅H₂₄
Molar mass	204.35 g·mol⁻¹
Density	0.939 g/mL
Boiling point	124 °C (255 °F; 397 K) (15 mmHg)
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
N verify (what is: Y/N?)
Infobox references

Copaene, or more precisely, α-copaene, is the common (or trivial) chemical name of an oily liquid hydrocarbon that is found in a number of essential oil-producing plants. The name is derived from that of the resin-producing tropical copaiba tree, Copaifera langsdorfii, from which the compound was first isolated in 1914. Its structure, including the chirality, was determined in 1963.^[1] The double-bond isomer with an exo-methylene group, β-copaene, was first reported in 1967.^[2]

Chemically, the copaenes are tricyclic sesquiterpenes. The molecules are chiral, and the α-copaene enantiomer most commonly found in higher plants exhibits a negative optical rotation of about −6°. The rare (+)-α-copaene is also found in small amounts in some plants. It is of economic significance because it is strongly attracting to an agricultural pest, the Mediterranean fruit fly Ceratitis capitata.^[3]

References

↑ V.H. Kapadia; Nagasampagi, B.A.; Naik, V.G.; Dev, Sukh et al. (1963). "Structure of mustakone and copaene". Tetrahedron Letters 28 (28): 1933. doi:10.1016/S0040-4039(01)90945-1.
↑ L. Westfelt; Westfelt, Lars; Sky, K.; Nilsson, Åke; Theorell, H.; Blinc, R.; Paušak, S.; Ehrenberg, L.; Dumanović, J. (1967). "Beta-Copaene and beta-Ylangene, Minor Sesquiterpenes of the Wood of Pinus silvestris L. And of Swedish Sulphate Turpentine". Acta Chemica Scandinavica 21: 152. doi:10.3891/acta.chem.scand.21-0152.
↑ R. Nishida; Shelly, Todd E.; Whittier, Timothy S.; Kaneshiro, Kenneth Y. et al. (2000). Journal of Chemical Ecology 26: 87. doi:10.1023/A:1005489411397. Missing or empty |title= (help)