Cobalt(II) acetate
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Names | |
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IUPAC name
Cobalt(II) acetate | |
Identifiers | |
71-48-7 (anhydrous) ![]() 6147-53-1 (tetrahydrate) ![]() | |
ChemSpider | 6041 ![]() |
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Jmol-3D images | Image |
PubChem | 6277 |
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UNII | 3XC4P44U7E ![]() |
Properties | |
Co(C2H3O2)2 | |
Molar mass | 177.02124 g/mol (anhydrous) 249.08 g/mol (tetrahydrate) |
Appearance | Pink crystals (anhydrous) intense red crystals (tetrahydrate) |
Odor | vinegar (tetrahydrate) |
Density | 1.705 g/cm3 (tetrahydrate) |
Melting point | 140 °C (284 °F; 413 K) (tetrahydrate) |
Soluble | |
Solubility | soluble in alcohol, dilute acids, pentyl acetate (tetrahydrate) |
Refractive index (nD) |
1.542 (tetrahydrate) |
Hazards | |
MSDS | J.T. Baker MSDS |
NFPA 704 | |
LD50 (Median lethal dose) |
503 mg/kg (oral, rat) |
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
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Infobox references | |
Cobalt(II) acetate is the cobalt(II) salt of acetic acid. It is commonly found as the tetrahydrate Co(C2H3O2)2(H2O)4. It is used as an industrial catalyst.
Synthesis and structure
It may be formed by the reaction between cobalt oxide or hydroxide and acetic acid:
- CoO + 2 HC2H3O2 + 3 H2O → Co(C2H3O2)2(H2O)4
The tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central cobalt centre being coordinated by four water molecules and two acetate ligands.[1]
Reactions and uses
Cobalt acetate is a precursor to various oil drying agents, catalysts that allow paints and varnishes to harden.[2] Cobalt(II) acetate reacts with salenH2 to give salcomine, a transition metal dioxygen complex:[3]
- Co(OAc)2 + salenH2 → Co(salen) + 2 HOAc
Safety
Cobalt salts are poisonous.[4]
References
- ↑ Van Niekerk, J. N.; Schoening, F. R. L. (1953). "The crystal structures of nickel acetate, Ni(CH3COO)2·4H2O, and cobalt acetate, Co(CH3COO)2·4H2O". Acta Cryst. 6 (7): 609–612. doi:10.1107/S0365110X5300171X.
- ↑ John Dallas Donaldson, Detmar Beyersmann, "Cobalt and Cobalt Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. doi:10.1002/14356007.a07_281.pub2
- ↑ Appleton, T. G. (1977). "Oxygen Uptake by a Cobalt(II) Complex". J. Chem. Ed. 54 (7): 443. doi:10.1021/ed054p443.
- ↑ MallBaker MSDS