Bromoiodomethane
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| Names | |
|---|---|
| Preferred IUPAC name
Bromoiodomethane | |
| Systematic IUPAC name
Bromo(iodo)methane[1] | |
Other names
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| Identifiers | |
557-68-6  | |
| ChemSpider | 61690 |
| |
| Jmol-3D images | Image |
| PubChem | 68407 |
| |
| Properties | |
| Molecular formula |
CH2BrI |
| Molar mass | 220.84 g·mol−1 |
| Appearance | Colourless liquid |
| Density | 2.93 g mL−1 |
| Melting point | 1 °C; 34 °F; 274 K |
| Boiling point | 138 °C (280 °F; 411 K) |
| Refractive index (nD) |
1.6382 |
| Hazards | |
| GHS pictograms |   |
| GHS signal word | DANGER |
| H315, H318, H335 | |
| P261, P280, P305+351+338 | |
| EU classification |  Xi |
| R-phrases | R37/38, R41 |
| S-phrases | S26, S36/39 |
| Related compounds | |
| Related alkanes |
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| Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
verify (what is: / ?) | |
| Infobox references | |
Bromoiodomethane is a liquid mixed halomethane very soluble in chloroform.
Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).
References
- Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. (March 2002). "Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation". J. Phys. Chem. A 106 (25): 5999–6005(7). doi:10.1021/jp014306j. Retrieved 2007-06-29.
- Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. (December 2005). "Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane". ChemPhysChem 7 (4): 955–963(9). doi:10.1002/cphc.200500654. PMID 16596616. Retrieved 2007-06-29.
- Zheng, X.; Phillips, D. L. (August 2000). "Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct". J. Chem. Phys. 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
- Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. (January 2005). "A theoretical study of bond selective photochemistry in CH2BrI". J. Chem. Phys. 122 (4): 044310. Bibcode:2005JChPh.122d4310L. doi:10.1063/1.1835955. PMID 15740251. Retrieved 2007-06-29.
- ↑ "bromoiodomethane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 27 March 2005. Identification. Retrieved 15 June 2012.
External links
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