(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
The correct title of this article is [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride. The substitution or omission of any < > [ ] { } is because of technical restrictions.
ferrocene_palladium(II)_dichloride.svg.png) | |
| Identifiers | |
|---|---|
72287-26-4  95464-05-4 complex with DCM | |
| ChemSpider | 24602493 |
| |
| Properties | |
| Molecular formula |
C34H28Cl2FeP2Pd |
| Molar mass | 731.70 g·mol−1 |
| Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
verify (what is: / ?) | |
| Infobox references | |
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is an palladium complex containing the iron-containing dppf ligand. Commercially available, this compound is popularly used for palladium-catalyzed coupling reactions.
Commercially available, this compound may be prepared from dppf and nitrile complexes of palladium dichloride:[1]
- dppf + PdCl2(RCN)2 → (dppf)PdCl2 + 2 RCN (RCN = acetonitrile or benzonitrile)
References
- ↑ Nataro, Chip; Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1’-Bis(diphenylphosphino)ferrocene". J. Chem. Ed. 86: 1412. doi:10.1021/ed086p1412.
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