Trinitramide
Trinitramide | |
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IUPAC name N,N-Dinitronitramide | |
Other names Trinitroamine | |
Identifiers | |
CAS number | 113282-38-5 |
ChemSpider | 24751851 |
Jmol-3D images | {{#if:O=N(=O)N(N(=O)=O)N(=O)=ON([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-]|Image 1 Image 2 |
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Properties | |
Molecular formula | N4O6 |
Molar mass | 152.02 g mol−1 |
(verify) (what is: / ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
Infobox references | |
Trinitramide is a compound of nitrogen and oxygen with the molecular formula N(NO2)3. The compound was detected and described in 2010 by researchers at the Royal Institute of Technology (KTH) in Sweden.[1]
Earlier, there had been speculation whether trinitramide could exist. Theoretical calculations by Montgomery and Michels in 1993 showed that the compound was likely to be stable.[2]
Trinitramide has a potential use as one of the most efficient and least polluting of rocket propellant oxidizers, as it is chlorine-free.[3] This is potentially an important development, because the Tsiolkovsky rocket equation implies that even small improvements in rocket delta-v can make large improvements in the size of practical rocket launch payloads. The density impulse (impulse per volume) of a trinitramide based propellant could be 20 to 30 per cent better than most existing formulations,[4] however the specific impulse (impulse per mass) of formulations with liquid oxygen is higher.[5]
References
- ↑ Angewandte Chemie International Edition, Early View, Dec. 23, 2010
- ↑ J. A. Montgomery Jr. and H. H. Michels (July 1993). "Structure and stability of trinitramide". Journal of Physical Chemistry 97 (26): 6774–6775. doi:10.1021/j100128a005.
- ↑ Discovery of New Molecule Could Lead to More Efficient Rocket Fuel, Science Daily, 2010-12-22, accessed 2011-01-03.
- ↑ http://www.rsc.org/chemistryworld/News/2011/January/07011103.asp
- ↑ http://onlinelibrary.wiley.com/store/10.1002/anie.201007047/asset/supinfo/anie_201007047_sm_miscellaneous_information.pdf?v=1&s=2b7789919ea7a0858400749fd4a8859942236a1e