Strontium iodide

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Strontium iodide
Identifiers
CAS number 10476-86-5 (anhydrous) YesY
PubChem 25304
EC number 233-972-1
RTECS number WK9275000
Jmol-3D images {{#if:[Sr+2].[I-].[I-]|Image 1
Properties
Molecular formula SrI2 (anhydrous)
SrI2·6H2O (hexahydrate)
Molar mass 341.43 g/mol (anhydrous)
Appearance Colorless to white crystalline plates
Density 4.55 g/cm³ (anhydrous)[1]
4.40 g/cm³ (hexahydrate)[1]
Melting point 507-645°C [2]
Boiling point 1773 °C (decomp)
Solubility in water 177.0 g/100 mL (20°C)[3]
Solubility in ethanol 3.1 g/100 ml (4°C) [3]
Structure
Crystal structure Orthorhombic, oP24
Space group Pbca, No. 61
Hazards
R-phrases R14 R34
S-phrases S22 S26 S27 S36/37/39S45 [4]
Main hazards Corrosive
NFPA 704
0
1
0
Related compounds
Other anions strontium fluoride
strontium chloride
strontium bromide
Other cations beryllium iodide
magnesium iodide
calcium iodide
barium iodide
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Strontium iodide (SrI2) is a salt of strontium and iodine. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide .[5]

Reactions

Strontium iodide can be prepared by reacting strontium carbonate with hydroiodic acid:

SrCO3 + 2 HI → SrI2 + H2O + CO2

Strontium iodide yellows when exposed to air. Pure Strontium is rather soft and malleable, and a freshly exposed surface has a pinkish or peachy color. It is used as a thermal conductor, an electrical conductor, a building material, and a constituent of various metal alloys. At high temperatures (when in the presence of air) strontium iodide completely decomposes to form strontium oxide and free iodine.[6]

References

  1. 1.0 1.1 Yaws, C.L. (2008). Thermophysical properties of chemicals and hydrocarbons. William Andrew. ISBN 978-0-8155-1596-8. 
  2. Turner, Jr., Francis M., ed. (1920), The Condensed Chemical Dictionary, New York: The Chemical Catalog Company, p. 449, retrieved 2007-12-10 
  3. 3.0 3.1
    177 g/100 mL (20 °C) Seidell, Atherton (1907), Solubilities of Inorganic and Organic Substances, New York: D. Van Nostrand, p. 318, retrieved 2007-12-10 
  4. 400696 Strontium iodide anhydrous, beads, −10 mesh, 99.99+ %
  5. Shoemaker, John V. (1908), A Practical Treatise on Materia Medica and Therapeutics (7th ed.), Philadelphia: F. A. Davis, p. 854, retrieved 2007-12-10 
  6. Bartley, Elias H. (1898), Text-book of Medical and Pharmaceutical Chemistry (5th ed.), Philadelphia: P. Blakiston, pp. 267–268, retrieved 2007-12-10 
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