Strain energy

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For strain energy of structures, see Energy principles in structural mechanics. For strain energy of solids, see Strain energy density function.

In physics, strain energy is the energy stored by a system undergoing deformation. When the load is removed, strain energy is gradually released as the system returns to its original shape.

It is denoted by U. When stress is proportional to strain, U can be written as :
$U={\frac 12}V\sigma \epsilon ={\frac 12}VE\epsilon ^{2}$
where σ is stress, ε is strain, V is volume, and E is Young's modulus.

Molecular Strain Energy

In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction or a change of chemical conformation in a way that:

angle strain,
torsional strain,
ring strain and/or steric strain,
Allylic strain, and
pentane interference

are reduced.^[1] The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy. The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work.

For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) for each additional CH₂ unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubanes, fenestranes and cyclophanes.

References

↑ March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Michael B. Smith & Jerry March, Wiley-Interscience, 5th edition, 2001, ISBN 0-471-58589-0

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