Silver carbonate

Silver carbonate
Other names none
Identifiers
CAS number	534-16-7 Y
PubChem	92796
ChemSpider	83768 Y
EC number	208-590-3
MeSH	silver+carbonate
Jmol-3D images	{{#if:[Ag]OC(=O)O[Ag]|Image 1
SMILES [Ag]OC(=O)O[Ag]
InChI InChI=1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Y Key: KQTXIZHBFFWWFW-UHFFFAOYSA-L Y InChI=1/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Key: KQTXIZHBFFWWFW-NUQVWONBAD
Properties
Molecular formula	Ag 2CO 3
Molar mass	275.7453 g mol-1
Appearance	Pale yellow crystals
Density	6.077 g cm-3
Melting point	210 °C; 410 °F; 483 K (decomposes)
Solubility in water	0.0032 g/100 mL
Thermochemistry
Std enthalpy of formation ΔfHo298	-506 kJ/mol
Specific heat capacity, C	112.5 J/mol K
Hazards
MSDS	External MSDS from Salt Lake Metals
NFPA 704	0 1 0
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Silver carbonate is the chemical compound with the formula Ag₂CO₃. Silver carbonate is yellow but typical samples are grayish due to the presence of elemental silver. It is poorly soluble in water, like most transition metal carbonates. Silver carbonate is used as a reagent in organic synthesis such as the Koenigs-Knorr reaction. In the Fétizon oxidation, silver carbonate on celite acts as an oxidising agent to form lactones from diols. It is also employed to convert alkyl bromides into alcohols.^[1]

Preparation

Silver carbonate can be easily prepared by combining aqueous solutions of sodium carbonate and silver nitrate.

References