Rubidium bromide

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Rubidium bromide
Identifiers
CAS number 7789-39-1 YesY
PubChem 4670918
ChemSpider 74217 YesY
Jmol-3D images {{#if:[Rb+].[Br-]|Image 1
Properties
Molecular formula RbBr
Molar mass 165.372 g/mol
Appearance white crystalline solid
Density 3.350 g/cm3
Melting point 693 °C; 1,279 °F; 966 K
Boiling point 1,340 °C; 2,440 °F; 1,610 K
Solubility in water 98 g/100 mL
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Rubidium fluoride
Rubidium chloride
Rubidium iodide
Other cations Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Rubidium bromide is the bromide of rubidium. It has a NaCl crystal structure, with a lattice constant of 685 picometres. [1]

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rb2CO3 + 2HBr → 2RbBr + H2O + CO2

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

References

  1. G. Chern, J. G. Skofronick, W. P. Brug ,S. A. Safron (1989). "Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering". Phys. Rev. B 39 (17): 12838–12844. doi:10.1103/PhysRevB.39.12838. 
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