Propylamine

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Propylamine
Identifiers
CAS number 107-10-8 YesY
PubChem 7852
ChemSpider 7564 YesY
EC number 203-462-3
UN number 1277
ChEBI CHEBI:39870 YesY
ChEMBL CHEMBL14409 YesY
RTECS number UH9100000
Beilstein Reference 1098243
Gmelin Reference 1529
Jmol-3D images Image 1
Properties
Molecular formula C3H9N
Molar mass 59.11 g mol−1
Appearance Colorless liquid
Odor fishy, ammoniacal
Density 719 mg mL–1
Melting point −83.00 °C; −117.40 °F; 190.15 K
Boiling point 47 to 51 °C; 116 to 124 °F; 320 to 324 K
Solubility in water Miscible
log P 0.547
Vapor pressure 33.01 kPa (at 20 °C)
kH 660 μmol Pa−1 kg−1
Acidity (pKa) 10.89
Refractive index (nD) 1.388
Thermochemistry
Std enthalpy of
formation ΔfHo298
−101.9–−101.1 kJ mol−1
Std enthalpy of
combustion
ΔcHo298
−2.368–−2.362 MJ mol−1
Standard molar
entropy
So298
227.44 J K−1 mol−1
Specific heat capacity, C 162.51 J K−1 mol−1
Hazards
GHS pictograms
GHS signal word DANGER
GHS hazard statements H225, H302, H311, H314, H331
GHS precautionary statements P210, P261, P280, P305+351+338, P310
EU classification F C
R-phrases R11, R20/21/22, R34
S-phrases S26, S36/37/39, S45
Flash point −30 °C; −22 °F; 243 K
Explosive limits 2–10.4%
LD50
  • 370 mg kg−1 (oral, rat)
  • 402.6 mg kg−1 (dermal, rabbit)
Related compounds
Related alkanamines
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Propylamine, also known as n-propylamine, is an amine with the chemical formula C2H5CH2NH2 (also written as C3H7NH2 and C3H9N).

Propylamine is a weak base with its Kb (base dissociation constant) equaling 4.7 × 10−4.

Preparation

Propyl amine hydrochloride can be prepared by reacting 1-propanol with ammonium chloride in water at high temperature and pressure using a lewis acid catalyst such as ferric chloride.

References

  1. "Propylamine - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 26 March 2005. Identification and Related Records. Retrieved 4 May 2012. 

External links

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