Potassium hexachloroplatinate
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Potassium hexachloroplatinate | ||
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Identifiers | ||
CAS number | 16921-30-5 | |
PubChem | 61856 | |
RTECS number | TP1650000 | |
Jmol-3D images | {{#if:Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]|Image 1 | |
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Properties | ||
Molecular formula | K2PtCl6 | |
Molar mass | 485.99 g/mol | |
Appearance | orange to yellow solid | |
Density | 3.344 g/cm3 | |
Melting point | 250 °C (decomp.) | |
Hazards | ||
MSDS | Oxford MSDS | |
EU classification | Toxic (T) | |
Flash point | 250 °C; 482 °F; 523 K | |
Related compounds | ||
Other anions | Potassium tetrachloroplatinate | |
(verify) (what is: / ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | ||
Infobox references | ||
Potassium hexachloroplatinate, an inorganic compound, is an example of a comparatively insoluble potassium salt.
The precipitation of this compound from solutions of hexachloroplatinic acid was formerly used for the determination of potassium by gravimetry.[1]
Potassium hexachloroplatinate may be reduced by hydrazine dihydrochloride to give the corresponding tetrachloroplatinate salt.[2]
References
- ↑ G. F. Smith, J. L. Gring (1933). "The Separation and Determination of the Alkali Metals Using Perchloric Acid. V. Perchloric Acid and Chloroplatinic Acid in the Determination of Small Amounts of Potassium in the Presence of Large Amounts of Sodium". J. Am. Chem. Soc. 55 (10): 3957–3961. doi:10.1021/ja01337a007.
- ↑ Keller, R. N.; Moeller, T. (1963). "Potassium Tetrachloroplatinate(II)". Inorg. Synth. Inorganic Syntheses 7: 247–250. doi:10.1002/9780470132333.ch79. ISBN 978-0-470-13233-3.
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