Plumbocene
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| Plumbocene | ||
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| Identifiers | ||
| CAS number | 1294-74-2 | |
| Properties | ||
| Molecular formula | C10H10Pb | |
| Molar mass | 337.39 g mol−1 | |
| Boiling point | 150 °C at 10−7 mmHg[1] | |
 (verify) (what is: / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | ||
| Infobox references | ||
Plumbocene is an organometallic compound of lead. It is a member of the class of metallocenes. It is soluble in benzene, acetone, ether, and petroleum ether, and insoluble in water. Plumbocene is stable in cold water.[1]
Plumbocene is not commercially available. It may be synthesized by the reaction of sodium cyclopentadienide with a lead(II) source such as lead(II) nitrate[1] or lead(II) iodide.[2]
The decamethyl analog, Cp*2Pb, and the half-sandwich complexes, Cp*PbBF4 and Cp*PbCl, are known as well.[3]
References
- ↑ 1.0 1.1 1.2 Fischer, E. O.; Grubert, H. (1956). "Über Aromatenkomplexe von Metallen. IV. Di-cyclopentadienyl-blei". Zeitschrift für anorganische und allgemeine Chemie 286 (5–6): 237. doi:10.1002/zaac.19562860507.
- ↑ Izod, Keith; McFarlane, William; Wills, Corinne; Clegg, William; Harrington, Ross W. (2008). "Agostic-Type…Pb Interactions Stabilize a Dialkylplumbylene. Structure of and Bonding in [{nPr2P(BH3)}(Me3Si)C(CH2)]2Pb". Organometallics 27: 4386. doi:10.1021/om800598b.
- ↑ Jutzi, Peter; Dickbreder, Reiner; Nöth, Heinrich (1989). "Blei(II)-Verbindungen mit π-gebundenen Pentamethylcyclopentadienylliganden – Synthesen, Strukturen und Bindungsverhältnisse". Chemische Berichte 122 (5): 865. doi:10.1002/cber.19891220512.
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