Nickel–hydrogen battery

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A nickel–hydrogen battery (NiH₂ or Ni–H₂) is a rechargeable electrochemical power source based on nickel and hydrogen.^[1] It differs from a nickel–metal hydride (NIMH) battery by the use of hydrogen in gaseous form, stored in a pressurized cell at up to 1200 psi (82.7 bar) pressure.^[2]

NiH₂ cells using 26% potassium hydroxide (KOH) as an electrolyte have shown a service life of 15 years or more at 80% depth of discharge (DOD)^[3] The energy density is 75 Wh/kg, 60 Wh/dm³^[4] specific power 220 W/kg.^[5] The open-circuit voltage is 1.55 V, the average voltage during discharge is 1.25 V.^[6]

While the energy density is only around one third as that of a lithium battery, the specific property of the nickel–hydrogen battery is its long life: the cells handle more than 20,000 charge cycles^[7] with 85% energy efficiency and 100% faradaic efficiency.

NiH₂ rechargeable batteries possess good electrical properties which make them attractive for the energy storage of electrical energy in satellites^[8] and space probes. For example, the ISS,^[9] Mercury Messenger,^[10] Mars Odyssey^[11] and the Mars Global Surveyor^[12] are equipped with nickel–hydrogen batteries. The Hubble Space Telescope, when its original batteries were changed in May 2009 more than 19 years after launch, led with the highest number of charge and discharge cycles of any NiH₂^[13] battery in low earth orbit.^[14]

History

The development of the nickel hydrogen battery started in 1970 at Comsat^[15] and was used for the first time in 1977 aboard the U.S. Navy's Navigation technology satellite-2 (NTS-2).^[16] Currently, the major manufacturers of nickel-hydrogen batteries are Eagle-Pitcher Technologies and Johnson Controls, Inc.

Characteristics

The nickel-hydrogen battery combines the positive nickel electrode of a nickel-cadmium battery, and the negative electrode includes the catalyst and gas diffusion elements of a fuel cell. During discharge, hydrogen contained in the pressure vessel is oxidized into water while the nickel oxyhydroxide electrode is reduced to nickel hydroxide. Water is consumed at the nickel electrode and produced at the hydrogen electrode, so the concentration of the potassium hydroxide electrolyte does not change. As the battery discharges, the hydrogen pressure drops, providing a reliable state of charge indicator. In one communication satellite battery, the pressure at full charge was over 500 pounds/square inch (3.4 MPa), dropping to only about 15 PSI (0.1 MPa) at full discharge.

If the cell is over-charged, the oxygen produced at the nickel electrode reacts with the hydrogen present in the cell and forms water; as a consequence the cells can withstand overcharging as long as the heat generated can be dissipated.

The cells have the disadvantage of relatively high self-discharge rate, i.e chemical reduction of Ni(III) into Ni(II) in the cathode:

NiOOH + 0.5 H2 = Ni(OH)2.

which is proportional to the pressure of hydrogen in the cell; in some designs, 50% of the capacity can be lost after only a few days' storage. Self-discharge is less at lower temperature. ^[17]

Compared with other rechargeable batteries, a nickel-hydrogen battery provides good specific energy of 55-60 watthours/kg, and very long cycle life (40,000 cycles at 40% DOD) and operating life (> 15 years) in satellite applications. The cells can tolerate overcharging and accidental polarity reversal, and the hydrogen pressure in the cell provides a good indication of the state of charge. However, the gaseous nature of hydrogen means that the volume efficiency is relatively low (60-100 Wh/L for an IPV (individual pressure vessel) cell), and the high pressure required makes for high-cost pressure vessels.^[17]

The positive electrode is made up of a dry sintered^[18] porous nickel plaque, which contains nickel hydroxide. The negative hydrogen electrode utilises a teflon-bonded platinum black catalyst at a rather high loading of 7 mg/cm2, the separator is knit zirconia cloth(ZYK-15 Zircar) ^[19]^[20] Asbestos was used in the past.

The Hubble replacement batteries are produced with a wet slurry process where a binder agent and powdered metallic materials are molded and heated to boil off the liquid.^[21]

Designs

Individual pressure vessel (IPV) design consists of a single unit of NiH₂ cells in a pressure vessel.^[22]
Common pressure vessel (CPV) design consist of two NiH₂ cell stacks in series in a common pressure vessel. The CPV provides a slightly higher specific energy than the IPV.
Single pressure vessel (SPV) design combines up to 22 cells in series in a single pressure vessel.
Bipolar design is based on thick electrodes, positive-to-negative back-to-back stacked in a SPV.^[23]
Dependent pressure vessel (DPV) cell design offers higher specific energy and reduced cost.^[24]
Common/dependent pressure vessel (C/DPV) is a hybrid of the common pressure vessel (CPV) and the dependent pressure vessel (DPV) with a high volumetric efficiency.^[25]

Schematics

References

External links

v t e Galvanic cells

Types	Voltaic pile Battery Flow battery Trough battery Concentration cell Fuel cell

Primary cell (non-rechargable)	Alkaline Aluminium–air Bunsen Chromic acid Clark Daniell Dry Edison-Lalande Grove Leclanché Lithium Mercury Nickel oxyhydroxide Silicon–air Silver oxide Weston Zamboni Zinc–air Zinc–carbon

Secondary cell (rechargeable)	Automotive Lead–acid gel / VRLA Lithium–air Lithium–ion Lithium polymer Lithium iron phosphate Lithium–sulfur Lithium titanate Nanowire Nickel–cadmium Nickel–hydrogen Nickel–iron Nickel–lithium Nickel–metal hydride Nickel–zinc Polysulfide bromide Potassium-ion Rechargeable alkaline Sodium-ion Sodium–sulfur Vanadium redox Zinc–bromine Zinc–cerium

Cell parts	Anode Binder Catalyst Cathode Electrolyte Half-cell Ions Salt bridge Semipermeable membrane

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