Nahcolite

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Nahcolite

Nahcolite from California (size: 9.5 x 8 x 4 cm)
General
Category Carbonate mineral
Formula
(repeating unit)
NaHCO3
Strunz classification 05.AA.15
Dana classification 13.01.01.01
Crystal symmetry Monoclinic prismatic
H-M symbol: (2/m)
Space group: P 21/n
Unit cell a = 7.47 Å, b = 9.68 Å, c = 3.48 Å; β = 93.38°; Z=4
Identification
Colour White to colourless, may be grey to brown
Crystal habit Elongated crystals, fibrous masses, friable porous aggregates
Crystal system Monoclinic prismatic
Twinning Common on [101]
Cleavage {101} perfect, {111} good, {100} distinct
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 2.5
Luster Vitreous - resinous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.21
Optical properties Biaxial (-)
Refractive index nα = 1.377 nβ = 1.503 nγ = 1.583
Birefringence δ = 0.206
Ultraviolet fluorescence Short UV=blue-white cream-yellow, Long UV=cream-yellow
Solubility Soluble in water
References [1][2][3]

Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (NaHCO3) also called thermokalite. It crystallizes in the monoclinic system.[3]

Nahcolite was first described in 1928 for an occurrence in a lava tunnel at Mount Vesuvius, Italy.[1] The name is in reference to its chemical formula. It occurs as a hot spring and saline lake precipitate or efflorescence; in differentiated alkalic massifs; in fluid inclusions as a daughter mineral phase and in evaporite deposits.[1][3] Its name refers to the elements which compose it: Na, H, C, and O.[4]

It occurs in association with trona, thermonatrite, thenardite, halite, gaylussite, burkeite, northupite and borax.[2] It has been reported in a Roman conduit at Stufe de Nerone, Campi Flegrei, near Naples; in the U. S. from Searles Lake, San Bernardino County, California; in the Green River Formation, Colorado and Utah; in the Tincalayu deposit, Salar del Hombre Muerto, Salta Province, Argentina; on Mt. Alluaiv, Lovozero Massif and Khibiny Massif, Kola Peninsula, Russia; and around Mount Erebus, Victoria Land, Antarctica.[2]

References

  1. 1.0 1.1 1.2 Nahcolite on Mindat.org
  2. 2.0 2.1 2.2 Nahcolite in the Handbook of Mineralogy
  3. 3.0 3.1 3.2 Nahcolite data on Webmineral
  4. Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Abraham Rosenzweig: Dana's new mineralogy, John Wiley & Sons, 1997
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