Metal–air electrochemical cell
From Wikipedia, the free encyclopedia
A metal–air electrochemical cell is an electrochemical cell that uses an anode made from pure metal and an external cathode of ambient air, typically with an aqueous electrolyte.[1][2]
Types
The Li–air battery discharge reaction between Li and oxygen Li2O, according to 4Li + O2 → 2Li2O, has an open-circuit voltage of 2.91 V and a theoretical specific energy of 5210 Wh/kg. Since oxygen is not stored in the battery, the theoretical specific energy excluding oxygen is 11140 Wh/kg (40.1 MJ/kg). Compare this to the figure of 44 MJ/kg for gasoline (see petrol energy content).
Metal–air battery | Calculated open-circuit voltage, V | Theoretical specific energy, Wh/kg (including oxygen) |
Theoretical specific energy, Wh/kg (excluding oxygen) |
---|---|---|---|
Aluminium–air | 1.2 | 4300[3] | 8140[4] |
Beryllium–air | |||
Calcium-air | 3.12 | 2990 | 4180 |
Iron–air | |||
Lithium–air | 2.91 | 5210 | 11140 |
Magnesium–air | 2.93 | 2789 | 6462 |
Sodium–air | 2.3[5][6] | 1677 | 2260 |
Titanium–air | |||
Zinc-air | 1.65 | 1090 | 1350 |
References
- ↑ Metal Air Batteries, Half a Fuel Cell?
- ↑ "METAL-AIR BATTERIES Lithium, Aluminum, Zinc, and Carbon" (PDF). Retrieved 2013-04-04.
- ↑ "Electrically Rechargeable Metal-Air Batteries (ERMAB)". Retrieved 25 March 2012.
- ↑ "Batteries for Oxygen Concentrators".
- ↑ "Electrochemical properties of room temperature sodium–air batteries with non-aqueous electrolyte".
- ↑ "BASF investigating sodium-air batteries as alternative to Li-air; patent application filed with USPTO".
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