Mercury(II) nitrate
Mercury(II) nitrate | ||
---|---|---|
IUPAC name Mercury dinitrate | ||
Other names Mercuric nitrate | ||
Identifiers | ||
CAS number | 10045-94-0 , 7783-34-8 (monohydrate) | |
EC number | 233-152-3 | |
UN number | 1625 | |
RTECS number | OW8225000 | |
Properties | ||
Molecular formula | Hg(NO3)2 | |
Molar mass | 324.60 g/mol (anhydrous) | |
Appearance | colorless crystals or white powder | |
Odor | sharp | |
Density | 4.3 g/cm3 (monohydrate) | |
Melting point | 79 °C (monohydrate) | |
Solubility in water | soluble | |
Solubility | soluble in nitric acid, acetone, ammonia insoluble in alcohol | |
Hazards | ||
MSDS | ICSC 0980 | |
EU Index | 080-002-00-6 | |
EU classification | Very toxic (T+) Dangerous for the environment (N) | |
R-phrases | R26/27/28, R33, R50/53 | |
S-phrases | (S1/2), S13, S28, S45, S60, S61 | |
NFPA 704 |
0
3
1
OX
| |
Flash point | Non-flammable | |
Related compounds | ||
Other anions | Mercury(II) sulfate Mercury(II) chloride | |
Other cations | Zinc nitrate Cadmium nitrate | |
Related compounds | Mercury(I) nitrate | |
(verify) (what is: / ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | ||
Infobox references | ||
Mercury(II) nitrate is a toxic colorless or white soluble crystalline mercury(II) salt of nitric acid. It was also used to treat fur to make felt in a process called 'carroting'. The phrase 'mad as a hatter' is associated with psychological illness brought on by excessive exposure to mercury(II) nitrate. The practice continued in the United States until it was banned in December 1941 by The United States Public Health Service. Although this sounds to benefit health, the ban actually freed mercury(II)nitrate to be used as a detonator in the then ongoing war.[1]
Production
It is made by reacting hot concentrated nitric acid with mercury metal; dilute nitric acid would produce mercury(I) nitrate. It is an oxidizing agent.
See also
References
HNO3 | He | |||||||||||||||||
LiNO3 | Be(NO3)2 | B(NO3)3 | C | N | O | F | Ne | |||||||||||
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | |||||||||||
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti | V | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3 | Co(NO3)2, Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr | |
RbNO3 | Sr(NO3)2 | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb | Te | I | Xe | |
CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 | Tl(NO3)3 | Pb(NO3)2 | Bi(NO3)3 | Po | At | Rn | ||
Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Uut | Fl | Uup | Lv | Uus | Uuo | ||
↓ | ||||||||||||||||||
La | Ce | Pr | Nd | Pm | Sm | Eu | Gd(NO3)3 | Tb | Dy | Ho | Er | Tm | Yb | Lu | ||||
Ac | Th | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |
External links
- ATSDR - Toxic Substances Portal - Mercury (11/14/2013)
- ATSDR - Public Health Statement: Mercury (11/14/2013)
- ATSDR - ALERT! Patterns of Metallic Mercury Exposure, 6/26/97 (link not traceable 11/14/2013)
- ATSDR - Medical Management Guidelines for Mercury (11/14/2013)
- ATSDR - Toxicological Profile: Mercury (11/14/2013)
- Safety data (MSDS) (link not traceable 11/14/2013)
- Mercuric Nitrate (ICSC)
- Mercury
- Mercury Information Packages
- How to Make Good Mercury Electrical Connections, Popular Science monthly, February 1919, Unnumbered page, Scanned by Google Books: http://books.google.com/books?id=7igDAAAAMBAJ&pg=PT14
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