Labradorite

From Wikipedia, the free encyclopedia
Labradorite

Labradorite in a polished rock slab
General
Category Feldspar, tectosilicate
Formula
(repeating unit)
(Ca,Na)(Al,Si)4O8, where Ca/(Ca + Na) (% anorthite) is between 50%–70%
Crystal symmetry Triclinic pinacoidal 1
Unit cell a = 8.155 Å, b = 12.84 Å, c = 10.16 Å; α = 93.5°, β = 116.25°, γ = 89.133°; Z = 6
Identification
Color Gray, brown, greenish, blue, yellow, colorless
Crystal habit Crystals typically thin and tabular, rhombic in cross section, striated; massive
Crystal system Triclinic
Twinning Common by Albite, Pericline, Carlsbad, Baveno, or Manebach twin laws
Cleavage Perfect on {001}, less perfect on {010}, intersecting at near 90°; distinct on {110}
Fracture Uneven to conchoidal
Mohs scale hardness 6 – 6.5
Luster Vitreous to pearly on cleavages
Streak white
Diaphaneity Translucent to transparent
Specific gravity 2.68 to 2.72
Optical properties Biaxial (+)
Refractive index nα = 1.554 - 1.563 nβ = 1.559 - 1.568 nγ = 1.562 - 1.573
Birefringence δ = 0.008 - 0.010
2V angle Measured: 85°
Dispersion None
Other characteristics Labradorescence (iridescent)
References [1][2][3]

Labradorite ((Ca, Na)(Al, Si)4O8), a feldspar mineral, is an intermediate to calcic member of the plagioclase series. It is usually defined as having "%An" (anorthite) between 50 and 70. The specific gravity ranges from 2.68 to 2.72. The streak is white, like most silicates. The refractive index ranges from 1.559 to 1.573. Twinning is common. As with all plagioclase members the crystal system is triclinic and three directions of cleavage are present two of which form nearly right angle prisms. It occurs as clear, white to gray, blocky to lath shaped grains in common mafic igneous rocks such as basalt and gabbro, as well as in anorthosites.

Occurrence

The geological type area for labradorite is Paul's Island near the town of Nain in Labrador, Canada. It has also been reported in Norway and various other locations worldwide.[2]

Labradorite occurs in mafic igneous rocks and is the feldspar variety most common in basalt and gabbro. The uncommon anorthosite bodies are composed almost entirely of labradorite.[4] It also is found in metamorphic amphibolites and as a detrital component of some sediments. Common mineral associates in igneous rocks include olivine, pyroxenes, amphiboles and magnetite.[1]

Labradorescence

An effect similar to adularescence in labradorite

Labradorescence is a side-effect of the molecular change which occurs in large crystal masses of anorthosite, producing an iridescent play of colors similar to adularescence. This labradorescence, or schiller effect, is the result of light diffraction within the lamellar intergrowths fine, adjacent layers of the separate materials (lamellae) comprising the whole rock phase created when conditions do not allow for sufficient diffusion to the materials' equilibrium composition.

The cause of this optical phenomenon is phase exsolution, or phase (state) instability, occurring in the Bøggild miscibility gap (An48-An58); under the appropriate heat and pressure conditions the separate molecular components will coexist but not mix to a solution, producing the phenomenon. [5][6][7][8]

Gemstone varieties of labradorite exhibiting a high degree of labradorescence are called spectrolite.

Gallery

References

This article is issued from Wikipedia. The text is available under the Creative Commons Attribution/Share Alike; additional terms may apply for the media files.