Isotopes of cadmium

Naturally occurring cadmium (Cd) is composed of 8 isotopes. For two of them, natural radioactivity was observed, and three others are predicted to be radioactive but their decays were never observed, due to extremely long half-life times. The two natural radioactive isotopes are ¹¹³Cd (beta decay, half-life is 7.7 × 10¹⁵ years) and ¹¹⁶Cd (two-neutrino double beta decay, half-life is 2.9 × 10¹⁹ years). The other three are ¹⁰⁶Cd, ¹⁰⁸Cd (double electron capture), and ¹¹⁴Cd (double beta decay); only lower limits on their half-life times have been set. At least three isotopes - ¹¹⁰Cd, ¹¹¹Cd, and ¹¹²Cd - are absolutely stable (except, theoretically, to spontaneous fission). Among the isotopes absent in the natural cadmium, the most long-lived are ¹⁰⁹Cd with a half-life of 462.6 days, and ¹¹⁵Cd with a half-life of 53.46 hours. All of the remaining radioactive isotopes have half-lives that are less than 2.5 hours and the majority of these have half-lives that are less than 5 minutes. This element also has 8 known meta states with the most stable being ^113mCd (t_½ 14.1 years), ^115mCd (t_½ 44.6 days) and ^117mCd (t_½ 3.36 hours).

The known isotopes of cadmium range in atomic mass from 94.950 u (⁹⁵Cd) to 131.946 u (¹³²Cd). The primary decay mode before the second most abundant stable isotope, ¹¹²Cd, is electron capture and the primary modes after are beta emission and electron capture. The primary decay product before ¹¹²Cd is element 47 (silver) and the primary product after is element 49 (indium).
Standard atomic mass: 112.411(8) u

Cadmium-113m

Cadmium-113m is a cadmium radioisotope and nuclear isomer with a halflife of 14.1 years. In a normal thermal reactor, it has a very low fission product yield, plus its large neutron capture cross section means that most of even the small amount produced is destroyed in the course of the nuclear fuel's burnup; thus, this isotope is not a significant contributor to nuclear waste.

Fast fission or fission of some heavier actinides will produce ^113mCd at higher yields.

Table

1. ↑ Bold for isotopes with half-lives longer than the age of the universe (nearly stable)
2. ↑ Abbreviations:
   EC: Electron capture
   IT: Isomeric transition
3. ↑ Bold for stable isotopes, bold italics for nearly-stable isotopes (half-life longer than the age of the universe)
4. ↑ Believed to decay by β⁺β⁺ to ¹⁰⁶Pd with a half-life over 4.1×10²⁰ years
5. ↑ Believed to decay by β⁺β⁺ to ¹⁰⁸Pd with a half-life over 4.1×10¹⁷ years
6. ↑ 6.0 6.1 6.2 Theoretically capable of spontaneous fission
7. ↑ 7.0 7.1 7.2 7.3 7.4 7.5 7.6 Fission product
8. ↑ 8.0 8.1 Primordial radionuclide
9. ↑ Believed to undergo β^-β^- decay to ¹¹⁴Sn with a half-life over 6.4×10¹⁸ years

Notes

• The precision of the isotope abundances and atomic mass is limited through variations. The given ranges should be applicable to any normal terrestrial material.
• Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
• Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
• Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
• Hyperdeformation is predicted to be found in ¹⁰⁷Cd.

References

• Isotope masses from:
  • G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. 
• Isotopic compositions and standard atomic masses from:
  • J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683. 
  • M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary. 
• Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
  • G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. 
  • National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005. 
  • N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9. 

1. ↑ http://www.nucleonica.net/unc.aspx