Interpnictogen

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Structure of monophosphorus mononitride (PN).

The pnictogens react with each other to form interpnictogen compounds.

Summary of known interpnictogens

N P As Sb Bi
N
N2
P
PN, P3N5
P4, P∞
As
AsN, (AsN)x
AsP3
As∞
Sb
SbN
SbP
SbAs
Sb∞
Bi
BiN
BixSby
Bi∞

Phosphorus pnictides

  • Monophosphorus mononitride (PN), an off-white to yellow-orange solid which decomposes at 800°C[1]
  • Triphosphorus pentanitride (P3N5), a white solid which decomposes at temperatures greater than 850°C

Arsenic pnictides

  • Arsenic nitride (AsN), which exists in the solid state as an oligomer, (AsN)x[2][3]
  • Arsenic phosphide (AsP3), which has a tetrahedral structure similar to that of white phosphorus, with an arsenic atom at one vertex of the tetrahedron and phosphorus atoms at the other three.[4]

Antimony pnictides

Bismuth pnictides

  • Bismuth nitride (BiN)[11]
  • Many "alloys" of bismuth and antimony in different concentrations with semimetallic bonding, BixSby[12]

See also

References

  1. ↑ Phosphorus Nitride - Description
  2. ↑ Oligomeric arsenic nitrides
  3. ↑ Arsenic Nitride gas (AsN) - Property Index
  4. ↑ Arsenic Phosphide AsP3 | AMERICAN ELEMENTS
  5. ↑ Antimony compounds: antimony nitride
  6. ↑ Antimony Nitride SbN | AMERICAN ELEMENTS
  7. ↑ Antimony phosphide
  8. ↑ Antimony Phosphide SbP | AMERICAN ELEMENTS
  9. ↑ ANTIMONY PHOSPHIDE (53120-23-3)
  10. ↑ Antimony arsenide | Chemical Dictionary Online
  11. ↑ Bismuth nitride (BiN)(8CI,9CI) | GuideChem
  12. ↑ Bismuth antimonide Bi(1-x)Sb(x) | SpringerMaterials The Landolt-Börnstein Database


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